Abstract: The proof of concept experiments were conducted to
determine the feasibility of using small amounts of Dissolved
Sulphur (DS) from the gaseous phase to precipitate platinum ions in
chloride media. Two sets of precipitation experiments were
performed in which the source of sulphur atoms was either a
thiosulphate solution (Na2S2O3) or a sulphur dioxide gas (SO2). In
liquid-liquid (L-L) system, complete precipitation of Pt was achieved
at small dosages of Na2S2O3 (0.01 – 1.0 M) in a time interval of 3-5
minutes. On the basis of this result, gas absorption tests were carried
out mainly to achieve sulphur solubility equivalent to 0.018 M. The
idea that huge amounts of precious metals could be recovered
selectively from their dilute solutions by utilizing the waste SO2
streams at low pressure seemed attractive from the economic and
environmental point of views. Therefore, mass transfer characteristics
of SO2 gas associated with reactive absorption across the gas-liquid
(G-L) interface were evaluated under different conditions of pressure
(0.5 – 2 bar), solution temperature ranges from 20 – 50 oC and acid
strength (1 – 4 M, HCl). This paper concludes with information about
selective precipitation of Pt in the presence of cations (Fe2+, Co2+,
and Cr3+) in a CSTR and recommendation to scale up laboratory data
to industrial pilot scale operations.