Abstract: The modified Claus process is the major technology
for the recovery of elemental sulfur from hydrogen sulfide. The
chemical reactions that can occur in the reaction furnace are
numerous and many byproducts such as carbon disulfide and carbon
carbonyl sulfide are produced. These compounds can often contribute
from 20 to 50% of the pollutants and therefore, should be hydrolyzed
in the catalytic converter. The inlet temperature of the first catalytic
reactor should be maintained over than 250 °C, to hydrolyze COS
and CS2. In this paper, the various configurations for the first
converter reheating of sulfur recovery unit are investigated. As a
result, the performance of each method is presented for a typical
clause unit. The results show that the hot gas method seems to be
better than the other methods.
Abstract: Majority of pepper farmers in Malaysia are using the
open-sun method for drying the pepper berries. This method is time
consuming and exposed the berries to rain and contamination. A
maintenance-friendly and properly enclosed dryer is therefore
desired. A dryer design with a solar collector and a chimney was
studied and adapted to suit the needs of small-scale pepper farmers in
Malaysia. The dryer will provide an environment with an optimum
operating temperature meant for drying pepper berries. The dryer
model was evaluated by using commercially available computational
fluid dynamic (CFD) software in order to understand the heat and
mass transfer inside the dryer. Natural convection was the only mode
of heat transportation considered in this study as in accordance to the
idea of having a simple and maintenance-friendly design. To
accommodate the effect of low buoyancy found in natural convection
driers, a biomass burner was integrated into the solar dryer design.
Abstract: The present work was conducted for Arsenic (III)
removal, which one of the most poisonous groundwater pollutants, by
synthetic nano size zerovalent iron (nZVI). Batch experiments were
performed to investigate the influence of As (III), nZVI
concentration, pH of solution and contact time on the efficiency of As
(III) removal. nZVI was synthesized by reduction of ferric chloride
by sodium borohydrid. SEM and XRD were used to determine
particle size and characterization of produced nanoparticles. Up to
99.9% removal efficiency for arsenic (III) was obtained by nZVI
dosage of 1 g/L at time equal to 10 min. and pH=7. It could be
concluded that the removal efficiency were enhanced with increasing
of ZVI dosage and reaction time, but decreased with increasing of
arsenic concentration and pH for nano sized ZVI. nZVI presented an
outstanding ability to remove As (III) due to not only a high surface
area and low particle size but also to high inherent activity.
Abstract: Based on Rayleigh beam theory, the sub-impacts of a
free-free beam struck horizontally by a round-nosed rigid mass is
simulated by the finite difference method and the impact-separation
conditions. In order to obtain the sub-impact force, a uniaxial
compression elastic-plastic contact model is employed to analyze the
local deformation field on contact zone. It is found that the horizontal
impact is a complicated process including the elastic plastic
sub-impacts in sequence. There are two sub-zones of sub-impact. In
addition, it found that the elastic energy of the free-free beam is more
suitable for the Poisson collision hypothesis to explain compression
and recovery processes.