Abstract: The commercial white tyres are usually used for forklifts in food and medicine industries. Conventionally, silica is used as reinforcement in the tyres. However, the adhesion between silica particles and rubber is remarkably poor. To improve the problem of adhesion and hence enhance wear resistance, modification of silica surface is one of the solutions. In this work, the natural rubber compound blending with polyisoprene-coated silica prepared by admicellar polymerization technique was studied to compare with the natural rubber compound of unmodified silica. The surface characterization of modified silica was also examined by SEM, FTIR, and TGA. The results show that polyisoprene-coated silica/natural rubber compound gave better overall mechanical properties, especially wear resistance with the improvement of the adhesion between silica and natural rubber matrix that can be seen in the SEM micrograph.
Abstract: The nanofiber sheet of Multiwall Cabon Nanotube
(MWCNTs)/Polyacylonitile (PAN) composites was fabricated from
electrospun nanofiber. Firstly the surface of MWCNTs was
chemically modified, comparing two different techniques consisting
of admicellar polymerization and functionalization to improve the
dispersion and prevent the aggregation in the PAN matrix. The
modified MWCNTs were characterized by the dispersion in
dimethylformamide (DMF) solvent, Laser particle size, and FTRaman.
Lastly, DSC, SEM and mechanical properties of the
nanofiber sheet were examined. The results show that the mechanical
properties of the nanofiber sheet prepared from admicellar
polymerization-modified MWCNTs were higher than those of the
others.