Abstract: The paper presents a one-dimensional transient
mathematical model of compressible thermal multi-component gas
mixture flows in pipes. The set of the mass, momentum and enthalpy
conservation equations for gas phase is solved. Thermo-physical
properties of multi-component gas mixture are calculated by solving
the Equation of State (EOS) model. The Soave-Redlich-Kwong
(SRK-EOS) model is chosen. Gas mixture viscosity is calculated on
the basis of the Lee-Gonzales-Eakin (LGE) correlation. Numerical
analysis on rapid decompression in conventional dry gases is
performed by using the proposed mathematical model. The model is
validated on measured values of the decompression wave speed in
dry natural gas mixtures. All predictions show excellent agreement
with the experimental data at high and low pressure. The presented
model predicts the decompression in dry natural gas mixtures much
better than GASDECOM and OLGA codes, which are the most
frequently-used codes in oil and gas pipeline transport service.
Abstract: Perturbed-Chain Statistical Association Fluid Theory (PC-SAFT) equation of state (EOS) is a modified SAFT EOS with three pure component specific parameters: segment number (m), diameter (σ) and energy (ε). These PC-SAFT parameters need to be determined for each component under the conditions of interest by fitting experimental data, such as vapor pressure, density or heat capacity. PC-SAFT parameters for propane, ethylene and hydrogen in supercritical region were successfully estimated by fitting experimental density data available in literature. The regressed PCSAFT parameters were compared with the literature values by means of estimating pure component density and calculating average absolute deviation between the estimated and experimental density values. PC-SAFT parameters available in literature especially for ethylene and hydrogen estimated density in supercritical region reasonably well. However, the regressed PC-SAFT parameters performed better in supercritical region than the PC-SAFT parameters from literature.