Abstract: Extraction of lactic acid by emulsion liquid membrane technology (ELM) using n-trioctyl amine (TOA) in n-heptane as carrier within the organic membrane along with sodium carbonate as acceptor phase was optimized by using response surface methodology (RSM). A three level Box-Behnken design was employed for experimental design, analysis of the results and to depict the combined effect of five independent variables, vizlactic acid concentration in aqueous phase (cl), sodium carbonate concentration in stripping phase (cs), carrier concentration in membrane phase (ψ), treat ratio, and batch extraction time (τ)
with equal volume of organic and external aqueous phase on lactic acid extraction efficiency. The maximum lactic acid extraction efficiency (ηext) of 98.21%from aqueous phase in a batch reactor using ELM was found at the optimized values for test variables, cl, cs, ψ, and τ as 0.06 [M], 0.18 [M], 4.72 (%,v/v), 1.98 (v/v) and 13.36 min respectively.
Abstract: The rheological properties of light crude oil and its mixture with water were investigated experimentally. These rheological properties include steady flow behavior, yield stress, transient flow behavior, and viscoelastic behavior. A RheoStress RS600 rheometer was employed in all of the rheological examination tests. The light crude oil exhibits a Newtonian and for emulsion exhibits a non-Newtonian shear thinning behavior over the examined shear rate range of 0.1–120 s-1. In first time, a series of samples of crude oil from the Algerian Sahara has been tested and the results expressed in terms of τ=f(γ) have demonstrated their Newtonian character for the temperature included in [20°C, 70°C]. In second time and at T=20°C, the oil-water emulsions (30%, 50% and 70%) by volume of water), thermodynamically stable, have demonstrated a non-Newtonian rheological behavior that is to say, Herschel-Bulkley and Bingham types. For each type of crude oil-water emulsion, the rheological parameters are calculated by numerical treatment of results.
Abstract: A prototype model of an emulsion separator was
designed and manufactured. Generally, it is a cylinder filled with
different fractal modules. The emulsion was fed into the reactor by a
peristaltic pump through an inlet placed at the boundary between the
two phases. For hydrodynamic design and sizing of the reactor the
assumptions of the theory of filtration were used and methods to
describe the separation process were developed. Based on this
methodology and using numerical methods and software of Autodesk
the process is simulated in different operating modes. The basic
hydrodynamic characteristics - speed and performance for different
types of fractal systems and decisions to optimize the design of the
reactor were also defined.
Abstract: The influence of viscosity on droplet diameter for
water-in-crude oil (w/o) emulsion with two different ratios; 20-80 %
and 50-50 % w/o emulsion was examined in the Brookfield
Rotational Digital Rheometer. The emulsion was prepared with
sorbitan sesquiolate (Span 83) act as emulsifier at varied temperature
and stirring speed in rotation per minute (rpm). Results showed that
the viscosity of w/o emulsion was strongly augmented by increasing
volume of water and decreased the temperature. The changing of
viscosity also altered the droplet size distribution. Changing of
droplet diameter was depends on the viscosity and the behavior of
emulsion either Newtonian or non-Newtonian.
Abstract: This study demonstrates the use of Class F fly ash in
combination with lime or lime kiln dust in the full depth reclamation
(FDR) of asphalt pavements. FDR, in the context of this paper, is a
process of pulverizing a predetermined amount of flexible pavement
that is structurally deficient, blending it with chemical additives and
water, and compacting it in place to construct a new stabilized base
course. Test sections of two structurally deficient asphalt pavements
were reclaimed using Class F fly ash in combination with lime and
lime kiln dust. In addition, control sections were constructed using
cement, cement and emulsion, lime kiln dust and emulsion, and mill
and fill. The service performance and structural behavior of the FDR
pavement test sections were monitored to determine how the fly ash
sections compared to other more traditional pavement rehabilitation
techniques. Service performance and structural behavior were
determined with the use of sensors embedded in the road and Falling
Weight Deflectometer (FWD) tests. Monitoring results of the FWD
tests conducted up to 2 years after reclamation show that the cement,
fly ash+LKD, and fly ash+lime sections exhibited two year resilient
modulus values comparable to open graded cement stabilized
aggregates (more than 750 ksi). The cement treatment resulted in a
significant increase in resilient modulus within 3 weeks of
construction and beyond this curing time, the stiffness increase was
slow. On the other hand, the fly ash+LKD and fly ash+lime test
sections indicated slower shorter-term increase in stiffness. The fly
ash+LKD and fly ash+lime section average resilient modulus values
at two years after construction were in excess of 800 ksi. Additional
longer-term testing data will be available from ongoing pavement
performance and environmental condition data collection at the two
pavement sites.
Abstract: Experimental data are presented to show the influence of different types of chemical demulsifier on the stability and demulsification of emulsions. Three groups of demulsifier with different functional groups were used in this work namely amines, alcohol and polyhydric alcohol. The results obtained in this study have exposed the capability of chemical breaking agents in destabilization of water in crude oil emulsions. From the present study, found that molecular weight of the demulsifier were influent the capability of the emulsion to separate.
Abstract: The coalescer process is one of the methods for oily water treatment by increasing the oil droplet size in order to enhance the separating velocity and thus effective separation. However, the presence of surfactants in an oily emulsion can limit the obtained mechanisms due to the small oil size related with stabilized emulsion. In this regard, the purpose of this research is to improve the efficiency of the coalescer process for treating the stabilized emulsion. The effects of bed types, bed height, liquid flow rate and stage coalescer (step-bed) on the treatment efficiencies in term of COD values were studied. Note that the treatment efficiency obtained experimentally was estimated by using the COD values and oil droplet size distribution. The study has shown that the plastic media has more effective to attach with oil particles than the stainless one due to their hydrophobic properties. Furthermore, the suitable bed height (3.5 cm) and step bed (3.5 cm with 2 steps) were necessary in order to well obtain the coalescer performance. The application of step bed coalescer process in reactor has provided the higher treatment efficiencies in term of COD removal than those obtained with classical process. The proposed model for predicting the area under curve and thus treatment efficiency, based on the single collector efficiency (ηT) and the attachment efficiency (α), provides relatively a good coincidence between the experimental and predicted values of treatment efficiencies in this study.