Abstract: Hydrogen diffusion is the main problem for corrosion fatigue in corrosive environment. In order to analyze the phenomenon, it is needed to understand their behaviors specially the hydrogen behavior during the diffusion. So, Hydrogen embrittlement and prediction its behavior as a main corrosive part of the fractions, needed to solve combinations of different equations mathematically. The main point to obtain the equation, having knowledge about the source of causing diffusion and running the atoms into materials, called driving force. This is produced by either gradient of electrical or chemical potential. In this work, we consider the gradient of chemical potential to obtain the property equation. In diffusion of atoms, some of them may be trapped but, it could be ignorable in some conditions. According to the phenomenon of hydrogen embrittlement, the thermodynamic and chemical properties of hydrogen are considered to justify and relate them to fracture mechanics. It is very important to get a stress intensity factor by using fugacity as a property of hydrogen or other gases. Although, the diffusive behavior and embrittlement event are common and the same for other gases but, for making it more clear, we describe it for hydrogen. This considering on the definite gas and describing it helps us to understand better the importance of this relation.
Abstract: This paper presents the results of corrosion fatigue
crack growth behaviour of a Ni-Cr-Mn steel commonly used in
marine applications. The effect of mechanical variables such as
frequency and load ratio on fatigue crack growth rate at various
stages has been studied using compact tension (C(T)) specimens
along the rolling direction of steel plate under 3.5% saturated NaCl
aqueous environment. The significance of crack closure on corrosion
fatigue, and the validity of Elber-s empirical linear crack closure
model with the ASTM compliance offset method have been
examined.
Fatigue crack growth rate is higher and threshold stress intensities
are lower in aqueous environment compared to the lab air conditions.
It is also observed that the crack growth rate increases at lower
frequencies. The higher stress ratio promotes the crack growth. The
effect of oxidization and corrosion pit formation is very less as the
stress ratio is increased. It is observed that as stress ratios are
increased, the Elber-s crack closure model agrees well with the crack
closure estimated by the ASTM compliance offset method for tests
conducted at 5Hz frequency compared to tests conducted at 1Hz in
corrosive environment.