Abstract: The time dependent progress of a chemical reaction over a flat horizontal plate is here considered. The problem is solved through the group similarity transformation method which reduces the number of independent by one and leads to a set of nonlinear ordinary differential equation. The problem shows a singularity at the chemical reaction order n=1 and is analytically solved through the perturbation method. The behavior of the process is then numerically investigated for n≠1 and different Schmidt numbers. Graphical results for the velocity and concentration of chemicals based on the analytical and numerical solutions are presented and discussed.
Abstract: In the first part of the research work, an electrolyzer (10.16 cm dia and 24.13 cm height) to produce hydrogen and oxygen was constructed for single slice O2/H2 fuel cell using cation exchange membrane. The electrolyzer performance was tested with 23% NaOH, 30% NaOH, 30% KOH and 35% KOH electrolyte solution with current input 4 amp and 2.84 V from the rectifier. Rates of volume of hydrogen produced were 0.159 cm3/sec, 0.155 cm3/sec, 0.169 cm3/sec and 0.163 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution. Rates of volume of oxygen produced were 0.212 cm3/sec, 0.201 cm3/sec, 0.227 cm3/sec and 0.219 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution (1.5 L). In spite of being tested the increased concentration of electrolyte solution, the gas rate does not change significantly. Therefore, inexpensive 23% NaOH electrolyte solution was chosen to use as the electrolyte in the electrolyzer. In the second part of the research work, graphite serpentine flow plates, fiberglass end plates, stainless steel screen electrodes, silicone rubbers were made to assemble the single slice O2/H2 polymer electrolyte membrane fuel cell (PEMFC).
Abstract: The assessment of surface waters in Enugu metropolis
for fecal coliform bacteria was undertaken. Enugu urban was divided
into three areas (A1, A2 and A3), and fecal coliform bacteria
analysed in the surface waters found in these areas for four years
(2005-2008). The plate count method was used for the analyses. Data
generated were subjected to statistical tests involving; Normality test,
Homogeneity of variance test, correlation test, and tolerance limit
test. The influence of seasonality and pollution trends were
investigated using time series plots. Results from the tolerance limit
test at 95% coverage with 95% confidence, and with respect to EU
maximum permissible concentration show that the three areas suffer
from fecal coliform pollution. To this end, remediation procedure
involving the use of saw-dust extracts from three woods namely;
Chlorophora-Excelsa (C-Excelsa),Khayan-Senegalensis,(CSenegalensis)
and Erythrophylum-Ivorensis (E-Ivorensis) in
controlling the coliforms was studied. Results show that mixture of
the acetone extracts of the woods show the most effective
antibacterial inhibitory activities (26.00mm zone of inhibition)
against E-coli. Methanol extract mixture of the three woods gave best
inhibitory activity (26.00mm zone of inhibition) against S-areus, and
25.00mm zones of inhibition against E-Aerogenes. The aqueous
extracts mixture gave acceptable zones of inhibitions against the
three bacteria organisms.
Abstract: The distributions of stresses and deflection in
rectangular isotropic and orthotropic plates with central
circular hole under transverse static loading have been studied
using finite element method. The aim of author is to analyze
the effect of D/A ratio (where D is hole diameter and A is plate
width) upon stress concentration factor (SCF) and deflection
in isotropic and orthotropic plates under transverse static
loading. The D/A ratio is varied from 0.01 to 0.9. The analysis
is done for plates of isotropic and two different orthotropic
materials. The results are obtained for three different boundary
conditions. The variations of SCF and deflection with respect
to D/A ratio are presented in graphical form and discussed.
The finite element formulation is carried out in the analysis
section of the ANSYS package.
Abstract: This paper presents a novel control strategy of a threephase
four-wire Unified Power Quality (UPQC) for an improvement
in power quality. The UPQC is realized by integration of series and
shunt active power filters (APFs) sharing a common dc bus capacitor.
The shunt APF is realized using a thee-phase, four leg voltage source
inverter (VSI) and the series APF is realized using a three-phase,
three leg VSI. A control technique based on unit vector template
technique (UTT) is used to get the reference signals for series APF,
while instantaneous sequence component theory (ISCT) is used for
the control of Shunt APF. The performance of the implemented
control algorithm is evaluated in terms of power-factor correction,
load balancing, neutral source current mitigation and mitigation of
voltage and current harmonics, voltage sag and swell in a three-phase
four-wire distribution system for different combination of linear and
non-linear loads. In this proposed control scheme of UPQC, the
current/voltage control is applied over the fundamental supply
currents/voltages instead of fast changing APFs currents/voltages,
there by reducing the computational delay and the required sensors.
MATLAB/Simulink based simulations are obtained, which support
the functionality of the UPQC. MATLAB/Simulink based
simulations are obtained, which support the functionality of the
UPQC.
Abstract: In the classical buckling analysis of rectangular plates
subjected to the concurrent action of shear and uniaxial forces, the
Euler shear buckling stress is generally evaluated separately, so that
no influence on the shear buckling coefficient, due to the in-plane
tensile or compressive forces, is taken into account.
In this paper the buckling problem of simply supported rectangular
plates, under the combined action of shear and uniaxial forces, is
discussed from the beginning, in order to obtain new project formulas
for the shear buckling coefficient that take into account the presence
of uniaxial forces.
Furthermore, as the classical expression of the shear buckling
coefficient for simply supported rectangular plates is considered only
a “rough" approximation, as the exact one is defined by a system of
intersecting curves, the convergence and the goodness of the classical
solution are analyzed, too.
Finally, as the problem of the Euler shear buckling stress
evaluation is a very important topic for a variety of structures, (e.g.
ship ones), two numerical applications are carried out, in order to
highlight the role of the uniaxial stresses on the plating scantling
procedures and the goodness of the proposed formulas.
Abstract: Refractive index control of benzocyclobutene (BCB 4024-40) is achieved by facilitating different conditions during the thermal curing of BCB film. Refractive index (RI) change of 1.49% is obtained with curing of BCB film using an oven, while the RI change is 0.1% when the BCB is cured using a hotplate. The two different curing methods exhibit a temperature dependent refractive index change of the BCB photosensitive polymer. By carefully controlling the curing conditions, multiple layers of BCB with different RI can be fabricated, which can then be applied in the fabrication of optical waveguides.
Abstract: In the paper, the results of sensitivity analysis of the influence of initial imperfections on the web stress state of a thinwalled girder are presented. The results of the study corroborate a very good and effective agreement of experiments with theory. Most input random quantities were found experimentally. The change of sensitivity coefficients in dependence on working load value is analysed. The stress was analysed by means of a geometrically and materially non-linear solution by applying the program ANSYS. This research study offers important background for theoretical studies of stability problems, post-critical effects and limit states of thin-walled steel structures.