Abstract: Isobaric vapor-liquid equilibrium measurements are
reported for binary mixture of 2-Methyltetrahydrofuran and Cumene
at 97.3 kPa. The data were obtained using a vapor recirculating type
(modified Othmer's) equilibrium still. The mixture shows slight
negative deviation from ideality. The system does not form an
azeotrope. The experimental data obtained in this study are
thermodynamically consistent according to the Herington test. The
activity coefficients have been satisfactorily correlated by means of
the Margules, and NRTL equations. Excess Gibbs free energy has
been calculated from the experimental data. The values of activity
coefficients have also been obtained by the UNIFAC group
contribution method.
Abstract: A method to determine experimentally the melting
rate, rm, and the heat transfer coefficients, αv (W/(m3K)), at
convective melting in a fixed bed of particles under adiabatic regime
is established in this paper. The method lies in the determining of the
melting rate by measuring the fixed bed height in time. Experimental
values of rm, α and α v were determined using cylindrical particles of
ice (d = 6.8 mm, h = 5.5 mm) and, as a melting agent, aqueous NaCl
solution with a temperature of 283 K at different values of the liquid
flow rate (11.63·10-6, 28.83·10-6, 38.83·10-6 m3/s).
Our experimental results were compared with those existing in
literature being noticed a good agreement for Re values higher than
50.
Abstract: Isobaric vapor-liquid equilibrium measurements are
reported for the binary mixture of Methyl acetate and
Isopropylbenzene at 97.3 kPa. The measurements have been
performed using a vapor recirculating type (modified Othmer's)
equilibrium still. The mixture shows positive deviation from ideality
and does not form an azeotrope. The activity coefficients have been
calculated taking into consideration the vapor phase nonideality. The
data satisfy the thermodynamic consistency tests of Herington and
Black. The activity coefficients have been satisfactorily correlated by
means of the Margules, NRTL, and Black equations. A comparison
of the values of activity coefficients obtained by experimental data
with the UNIFAC model has been made.