Abstract: Cu-mesoporous TiO2 is developed for removal acid
odor cooperated with ozone assistance and online- regeneration
system with/without UV irradiation (all weather) in study. The results
showed that Cu-mesoporous TiO2 present the desirable adsorption
efficiency of acid odor without UV irradiation, due to the larger
surface area, pore sizeand the additional absorption ability provided by
Cu. In the photocatalysis process, the material structure also benefits
Cu-mesoporous TiO2 to perform the more outstanding efficiency on
degrading acid odor. Cu also postponed the recombination of
electron-hole pairs excited from TiO2 to enhance photodegradation
ability. Cu-mesoporous TiO2 could gain the conspicuous increase on
photocatalysis ability from ozone assistance, but without any benefit
on adsorption. In addition, the online regeneration procedure could
process the used Cu-mesoporous TiO2 to reinstate the adsorption
ability and maintain the photodegradtion performance, depended on
scrubbing, desorping acid odor and reducing Cu to metal state.
Abstract: This paper aims to fabricated high quality anodic
aluminum oxide (AAO) film by anodization method. AAO pore size,
pore density, and film thickness can be controlled in 10~500 nm,
108~1011 pore．cm-2, and 1~100 μm. AAO volume and surface area can
be computed based on structural parameters such as thickness, pore
size, pore density, and sample size. Base on the thetorical calculation,
AAO has 100 μm thickness with 15 nm, 60 nm, and 500 nm pore
diameters AAO surface areas are 1225.2 cm2, 3204.4 cm2, and 549.7
cm2, respectively. The large unit surface area which is useful for
adsorption application. When AAO adsorbed pH indictor of
bromphenol blue presented a sensitive pH detection of solution
change. This testing method can further be used for the precise
measurement of biotechnology, convenience measurement of
industrial engineering.
Abstract: A new SUZ-4 zeolite membrane with
tetraethlyammonium hydroxide as the template was fabricated on
mullite tube via hydrothermal sol-gel synthesis in a rotating
autoclave reactor. The suitable synthesis condition was SiO2:Al2O3
ratio of 21.2 for 4 days at 155 °C crystallization under autogenous
pressure. The obtained SUZ-4 possessed a high BET surface area of
396.4 m2/g, total pore volume at 2.611 cm3/g, and narrow pore size
distribution with 97 nm mean diameter and 760 nm long of needle
crystal shape. The SUZ-4 layer obtained from seeding crystallization
was thicker than that of without seeds or in situ crystallization.
Abstract: Hydrate phase equilibria for the binary CO2+water and
CH4+water mixtures in silica gel pore of nominal diameters 6, 30, and
100 nm were measured and compared with the calculated results based
on van der Waals and Platteeuw model. At a specific temperature,
three-phase hydrate-water-vapor (HLV) equilibrium curves for pore
hydrates were shifted to the higher-pressure condition depending on
pore sizes when compared with those of bulk hydrates. Notably,
hydrate phase equilibria for the case of 100 nominal nm pore size were
nearly identical with those of bulk hydrates. The activities of water in
porous silica gels were modified to account for capillary effect, and
the calculation results were generally in good agreement with the
experimental data. The structural characteristics of gas hydrates in
silica gel pores were investigated through NMR spectroscopy.
Abstract: This paper present some preliminary work on the
preparation and physicochemical caracterization of nanocomposite
MFI-alumina structures based on alumina hollow fibres. The fibers
are manufactured by a wet spinning process. α-alumina particles were
dispersed in a solution of polysulfone in NMP. The resulting slurry is
pressed through the annular gap of a spinneret into a precipitation
bath. The resulting green fibres are sintered. The mechanical strength
of the alumina hollow fibres is determined by a three-point-bending
test while the pore size is characterized by bubble-point testing. The
bending strength is in the range of 110 MPa while the average pore
size is 450 nm for an internal diameter of 1 mm and external diameter
of 1.7 mm. To characterize the MFI membranes various techniques
were used for physicochemical characterization of MFI–ceramic
hollow fibres membranes: The nitrogen adsorption, X-ray
diffractometry, scanning electron microscopy combined with X
emission microanalysis. Scanning Electron Microscopy (SEM) and
Energy Dispersive Microanalysis by the X-ray were used to observe
the morphology of the hollow fibre membranes (thickness,
infiltration into the carrier, defects, homogeneity). No surface film,
has been obtained, as observed by SEM and EDX analysis and
confirmed by high temperature variation of N2 and CO2 gas
permeances before cation exchange. Local analysis and characterise
(SEM and EDX) and overall (by ICP elemental analysis) were
conducted on two samples exchanged to determine the quantity and
distribution of the cation of cesium on the cross section fibre of the
zeolite between the cavities.
Abstract: Cs-type nanocomposite zeolite membrane was successfully synthesized on an alumina ceramic hollow fibre with a mean outer diameter of 1.7 mm; cesium cationic exchange test was carried out inside test module with mean wall thickness of 230 μm and an average crossing pore size smaller than 0.2 μm. Separation factor of n-butane/H2 obtained indicate that a relatively high quality closed to 20. Maxwell-Stefan modeling provides an equivalent thickness lower than 1 µm. To compare the difference an application to CO2/N2 separation has been achieved, reaching separation factors close to (4,18) before and after cation exchange on H-zeolite membrane formed within the pores of a ceramic alumina substrate.
Abstract: The main aim of this work is to develop a model of hydrogen sulfide (H2S) separation from natural gas by using membrane separation technology. The model is developed by incorporating three diffusion mechanisms which are Knudsen, viscous and surface diffusion towards membrane selectivity and permeability. The findings from the simulation result shows that the permeability of the gas is dependent toward the pore size of the membrane, operating pressure, operating temperature as well as feed composition. The permeability of methane has the highest value for Poly (1-trimethylsilyl-1-propyne ) PTMSP membrane at pore size of 0.1nm and decreasing toward a minimum peak at pore range 1 to 1.5 nm as pore size increased before it increase again for pore size is greater than 1.5 nm. On the other hand, the permeability of hydrogen sulfide is found to increase almost proportionally with the increase of membrane pore size. Generally, the increase of pressure will increase the permeability of gas since more driving force is provided to the system while increasing of temperature would decrease the permeability due to the surface diffusion drop off effect. A corroboration of the simulation result also showed a good agreement with the experimental data.
Abstract: Scatter behavior of fatigue life in die-cast AM60B
alloy was investigated. For comparison, those in rolled AM60B alloy
and die-cast A365-T5 aluminum alloy were also studied. Scatter
behavior of pore size was also investigated to discuss dominant
factors for fatigue life scatter in die-cast materials. Three-parameter
Weibull function was suitable to explain the scatter behavior of both
fatigue life and pore size. The scatter of fatigue life in die-cast
AM60B alloy was almost comparable to that in die-cast A365-T5
alloy, while it was significantly large compared to that in the rolled
AM60B alloy. Scatter behavior of pore size observed at fracture
nucleation site on the fracture surface was comparable to that
observed on the specimen cross-section and also to that of fatigue
life. Therefore, the dominant factor for large scatter of fatigue life in
die-cast alloys would be the large scatter of pore size. This
speculation was confirmed by the fracture mechanics fatigue life
prediction, where the pore observed at fatigue crack nucleation site
was assumed as the pre-existing crack.
Abstract: Properties of cement pastes with fine-ground ceramics
used as an alternative binder replacing Portland cement up to 20% of
its mass are investigated. At first, the particle size distribution of
cement and fine-ground ceramics is measured using laser analyser.
Then, the material properties are studied in the early hardening
period up to 28 days. The hydration process of studied materials is
monitored by electrical conductivity measurement using TDR
sensors. The changes of materials- structures within the hardening are
observed using pore size distribution measurement. The compressive
strength measurements are done as well. Experimental results show
that the replacement of Portland cement by fine-ground ceramics in
the amount of up to 20% by mass is acceptable solution from the
mechanical point of view. One can also assume similar physical
properties of designed materials to the reference material with only
Portland cement as binder.
Abstract: Multiphase flow transport in porous medium is very common and significant in science and engineering applications. For example, in CO2 Storage and Enhanced Oil Recovery processes, CO2 has to be delivered to the pore spaces in reservoirs and aquifers. CO2 storage and enhance oil recovery are actually displacement processes, in which oil or water is displaced by CO2. This displacement is controlled by pore size, chemical and physical properties of pore surfaces and fluids, and also pore wettability. In this study, a technique was developed to measure the pressure profile for driving gas/liquid to displace water in pores. Through this pressure profile, the impact of pore size on the multiphase flow transport and displacement can be analyzed. The other rig developed can be used to measure the static and dynamic pore wettability and investigate the effects of pore size, surface tension, viscosity and chemical structure of liquids on pore wettability.
Abstract: The remediation of water resources pollution in
developing countries requires the application of alternative
sustainable cheaper and efficient end-of-pipe wastewater treatment
technologies. The feasibility of use of South African cheap and
abundant pine tree (Pinus patula) sawdust for development of lowcost
AC of comparable quality to expensive commercial ACs in the
abatement of water pollution was investigated. AC was developed at
optimized two-stage N2-superheated steam activation conditions in a
fixed bed reactor, and characterized for proximate and ultimate
properties, N2-BET surface area, pore size distribution, SEM, pHPZC
and FTIR. The sawdust pyrolysis activation energy was evaluated by
TGA. Results indicated that the chars prepared at 800oC and 2hrs
were suitable for development of better quality AC at 800oC and 47%
burn-off having BET surface area (1086m2/g), micropore volume
(0.26cm3/g), and mesopore volume (0.43cm3/g) comparable to
expensive commercial ACs, and suitable for water contaminants
removal. The developed AC showed basic surface functionality at
pHPZC at 10.3, and a phenol adsorption capacity that was higher than
that of commercial Norit (RO 0.8) AC. Thus, it is feasible to develop
better quality low-cost AC from (Pinus patula) sawdust using twostage
N2-steam activation in fixed-bed reactor.
Abstract: spherical porous carbon particles with
controllable porosity with a mean size of 2.5m have been
prepared using a spray drying method with organic particle
colloidal template. As a precursor, a mixing solution of carbon
nanopowder and polystyrene (PS) particles as a template was
used. The result showed that the particles with a good porous
structure could be obtained. The pore size and shape (spherical)
were identical to the initial template, giving a potential way for
further developments. The control of particle porosity was also
possible and reported in this paper, in which this control could
be achieved by means of PS concentration.
Abstract: Experimental investigation of the effect of
hydrophobic injection on siloxane basis on the properties of oldfashioned
type of ceramic brick is presented in the paper. At the
experimental testing, the matrix density, total open porosity, pore size
distribution, sorptivity, water absorption coefficient, sorption and
desorption isotherms are measured for the original, as well as the
hydrophobic-injection treated brick. On the basis of measured data,
the functionality of the hydrophobic injection for the moisture ingress
prevention into the studied ceramic brick is assessed.
Abstract: In this work Membrane Distillation is applied to
concentrate orange Juice. Clarified orange juice (11o Brix) obtained
from fresh fruits and a sugar solution was subjected to membrane
distillation. The experiments were performed on a flat sheet module
using orange juice and sucrose solution as feeds. The concentration
of a sucrose solution, used as a model fruit juice and also orange
juice, was carried out in a direct contact membrane distillation using
hydrophobic PTFE membrane of pore size 0.2 μm and porosity 70%.
Surface modification of PTFE membrane has been carried out by
treating membrane with alcohol and water solution to make it
hydrophilic and then hydrophobicity was regained by drying. The
influences of the feed temperature, feed concentration, flow rate,
operating time on the permeate flux were studied for treated and non
treated membrane. In this work treated and non treated membrane
were compared in terms of water flux, Within the tested range, MD
with surface modified membrane the water flux has been
significantly improved by treating the membrane surface.
Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.
Abstract: This study presents the performance of membrane
bioreactor in treating high phosphate wastewater. The laboratory
scale MBR was operated at permeate flux of 25 L/m2.h with a hollow
fiber membrane (polypropylene, approx. pore size 0.01 - 0.2 μm) at
hydraulic retention time (HRT) of 12 hrs. Scanning electron
microscopy (SEM) and energy diffusive X-ray (EDX) analyzer were
used to characterize the membrane foulants. Results showed that the
removal efficiencies of COD, TSS, NH3-N and PO4
3- were 93, 98, 80
and 30% respectively. On average 91% of influent soluble microbial
products (SMP) were eliminated, with the eliminations of
polysaccharides mostly above 80%. The main fouling resistance was
cake resistance. It should be noted that SMP were found in major
portions of mixed liquor that played a relatively significant role in
membrane fouling. SEM and EDX analyses indicated that the
foulants covering the membrane surfaces comprises not only organic
substances but also inorganic elements including Mg, Ca, Al, K and
P.