A new SUZ-4 zeolite membrane with
tetraethlyammonium hydroxide as the template was fabricated on
mullite tube via hydrothermal sol-gel synthesis in a rotating
autoclave reactor. The suitable synthesis condition was SiO2:Al2O3
ratio of 21.2 for 4 days at 155 °C crystallization under autogenous
pressure. The obtained SUZ-4 possessed a high BET surface area of
396.4 m2/g, total pore volume at 2.611 cm3/g, and narrow pore size
distribution with 97 nm mean diameter and 760 nm long of needle
crystal shape. The SUZ-4 layer obtained from seeding crystallization
was thicker than that of without seeds or in situ crystallization.
[1] S. A. Barri. "Crystalline (metallo) silicates and germanates-SUZ-4,"
United States 5,118, 483, 1992.
[2] S. L. Lawton, J. M. Bennett, J. L. Schlenker and M. K. Rubin.
"Synthesis and proposed framework topology of zeolite SUZ-4," J.
Chem. Soc., Chem. Commun. vol. 11, pp. 894-896. 1993.
[3] K. G. Strohmaier, M. Afeworki and D. L. Dorset. "The crystal
structures of polymorphic SUZ-4," Z. Kristallogr., vol. 221, pp. 689-
698. 2006.
[4] W. C. Paik, C. H. Shin and S. B. Hong. "Synthesis of zeolites P1 and
SUZ-4 through a synergy of organic N,N,N,N',N',N'
hexaethylpentanediammonium and inorganic cations," J. Chem. Soc.,
Chem. Commun., pp. 1609-1610. 2000.
[5] W. C. Paik, C. H. Shin, J. M. Lee, B. J. Ahn and S. B. Hong. "Hostguest
interactions in P1, SUZ-4, and ZSM-57 zeolites containing
N,N,N,N',N',N' hexaethylpentanediammonium ion as a guest molecule,"
J. Phys. Chem. B, vol.105, pp. 9994-10000. 2001.
[6] D. B. Lukyanov, V. L. Zholobenko, J. Dwyer, S. A. I. Barri and W. J.
Smith. "On the structural, acidic and catalytic properties of zeolite SUZ-
4," J. Phys. Chem. vol. 103, pp. 197-202, 1999.
[7] H. Choo, S. B. Hong and L. Keven. "Comparative ESR and catalytic
studies of ethylene dimerization on Pd(II)-exchanged clinoptilolite,
mordenite, ferrierite, and SUZ-4," J. Phys. Chem. B, vol. 105, pp. 7730-
7738. 2001.
[8] M. A. Asensi, M. A. Camblor and A. Martinez. "Zeolite SUZ-4:
Reproducible synthesis, physicochemical characterization and catalytic
evaluation for the skeletalisomerization of n-butenes," Micropor.
Mesopor. Mater. vol. 28, pp. 427-436, 1999.
[9] A. Subbiah, B. K. Cho, R. J. Blint, A. C. Gujar, G. L. Price and J. E. Yie.
"NOx reduction over metal-ion exchanged novel zeolite under lean
conditions: activity and hydrothermal stability," Applied Catalysis B:
Environmental, vol.42, pp. 155-178. 2003.
[10] S. Jiang, Y. K. Hwang, S. H. Jhung, J.-S. Chang and J.-S. Hwang.
"Zeolite SUZ-4 as selctive dehydration catalyst for methanol conversion
to dimethyl ether," Chemistry Letters, vol.33, pp. 1048-1049, 2004.
[11] S.-H. Lee, C.-H. Shin, G. J. Choi, T.-J. Park, I.-S. Nam, B. Han and S. B.
Hong. Zeolite synthesis in the presence of flexible diquaternary
alkylammonium ions (C2H5)3N+(CH2)N+(C2H5)3 with n = 3-10 as
structure-directing agents. Micropor. Mesopor. Mater., vol. 60, pp. 237-
249, 2003.
[12] A. C. Gujar, A. A. Moye, P. A. Coghill, D. C. Teeters, K. P. Roberts and
G. L. Price. "Raman investigation of the SUZ-4 zeolite," Micropor.
Mesopor. Mater. vol.78, pp. 131-137. 2005.
[13] V. L. Zholobenko, D. B. Lukyanov and J. Dwyer. "Ferrierite and SUZ-4
Zeolites: Characterization of Acid Sites." J. Phys. Chem. vol. 102, pp.
2715-2721, 1998.
[14] J. Caro, M. Noack, P. KOlsch and R. Schafer. "Zeolite membranes-state
of their development and perspective," Micropor. Mesopor. Mater. vol.
38, pp. 3-24, 2000.
[15] A. C. Gujar and G. L. Price. "Synthesis of SUZ-4 in the K+/TEA+
system," Micropor. Mesopor. Mater. vol. 54, pp. 201-205, 2002.
[16] D.-K. Kim, Y. H. Kim, Y. K. Kwang, J.-S. Chang and S.-E. Park.
"Effect of synthesis conditions on physicochemical properties of zeolite
SUZ-4 (in Korean, English abstract)," J. the Korean Chemical Society
vol. 48, pp. 623-628, 2004.
[17] S.-H. Lee, C.-H. Shin and S. B. Hong. "Investigations into the origin of
the remarkable catalytic performance of aged H-ferrierite for the skeletal
isomerization of 1-butene to isobutene," J. Catalysis, vol.223, pp. 200-
211. 2004.
[1] S. A. Barri. "Crystalline (metallo) silicates and germanates-SUZ-4,"
United States 5,118, 483, 1992.
[2] S. L. Lawton, J. M. Bennett, J. L. Schlenker and M. K. Rubin.
"Synthesis and proposed framework topology of zeolite SUZ-4," J.
Chem. Soc., Chem. Commun. vol. 11, pp. 894-896. 1993.
[3] K. G. Strohmaier, M. Afeworki and D. L. Dorset. "The crystal
structures of polymorphic SUZ-4," Z. Kristallogr., vol. 221, pp. 689-
698. 2006.
[4] W. C. Paik, C. H. Shin and S. B. Hong. "Synthesis of zeolites P1 and
SUZ-4 through a synergy of organic N,N,N,N',N',N'
hexaethylpentanediammonium and inorganic cations," J. Chem. Soc.,
Chem. Commun., pp. 1609-1610. 2000.
[5] W. C. Paik, C. H. Shin, J. M. Lee, B. J. Ahn and S. B. Hong. "Hostguest
interactions in P1, SUZ-4, and ZSM-57 zeolites containing
N,N,N,N',N',N' hexaethylpentanediammonium ion as a guest molecule,"
J. Phys. Chem. B, vol.105, pp. 9994-10000. 2001.
[6] D. B. Lukyanov, V. L. Zholobenko, J. Dwyer, S. A. I. Barri and W. J.
Smith. "On the structural, acidic and catalytic properties of zeolite SUZ-
4," J. Phys. Chem. vol. 103, pp. 197-202, 1999.
[7] H. Choo, S. B. Hong and L. Keven. "Comparative ESR and catalytic
studies of ethylene dimerization on Pd(II)-exchanged clinoptilolite,
mordenite, ferrierite, and SUZ-4," J. Phys. Chem. B, vol. 105, pp. 7730-
7738. 2001.
[8] M. A. Asensi, M. A. Camblor and A. Martinez. "Zeolite SUZ-4:
Reproducible synthesis, physicochemical characterization and catalytic
evaluation for the skeletalisomerization of n-butenes," Micropor.
Mesopor. Mater. vol. 28, pp. 427-436, 1999.
[9] A. Subbiah, B. K. Cho, R. J. Blint, A. C. Gujar, G. L. Price and J. E. Yie.
"NOx reduction over metal-ion exchanged novel zeolite under lean
conditions: activity and hydrothermal stability," Applied Catalysis B:
Environmental, vol.42, pp. 155-178. 2003.
[10] S. Jiang, Y. K. Hwang, S. H. Jhung, J.-S. Chang and J.-S. Hwang.
"Zeolite SUZ-4 as selctive dehydration catalyst for methanol conversion
to dimethyl ether," Chemistry Letters, vol.33, pp. 1048-1049, 2004.
[11] S.-H. Lee, C.-H. Shin, G. J. Choi, T.-J. Park, I.-S. Nam, B. Han and S. B.
Hong. Zeolite synthesis in the presence of flexible diquaternary
alkylammonium ions (C2H5)3N+(CH2)N+(C2H5)3 with n = 3-10 as
structure-directing agents. Micropor. Mesopor. Mater., vol. 60, pp. 237-
249, 2003.
[12] A. C. Gujar, A. A. Moye, P. A. Coghill, D. C. Teeters, K. P. Roberts and
G. L. Price. "Raman investigation of the SUZ-4 zeolite," Micropor.
Mesopor. Mater. vol.78, pp. 131-137. 2005.
[13] V. L. Zholobenko, D. B. Lukyanov and J. Dwyer. "Ferrierite and SUZ-4
Zeolites: Characterization of Acid Sites." J. Phys. Chem. vol. 102, pp.
2715-2721, 1998.
[14] J. Caro, M. Noack, P. KOlsch and R. Schafer. "Zeolite membranes-state
of their development and perspective," Micropor. Mesopor. Mater. vol.
38, pp. 3-24, 2000.
[15] A. C. Gujar and G. L. Price. "Synthesis of SUZ-4 in the K+/TEA+
system," Micropor. Mesopor. Mater. vol. 54, pp. 201-205, 2002.
[16] D.-K. Kim, Y. H. Kim, Y. K. Kwang, J.-S. Chang and S.-E. Park.
"Effect of synthesis conditions on physicochemical properties of zeolite
SUZ-4 (in Korean, English abstract)," J. the Korean Chemical Society
vol. 48, pp. 623-628, 2004.
[17] S.-H. Lee, C.-H. Shin and S. B. Hong. "Investigations into the origin of
the remarkable catalytic performance of aged H-ferrierite for the skeletal
isomerization of 1-butene to isobutene," J. Catalysis, vol.223, pp. 200-
211. 2004.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:58820", author = "P. Worathanakul and P. Kongkachuichay", title = "New SUZ-4 Zeolite Membrane from Sol-Gel Technique", abstract = "A new SUZ-4 zeolite membrane with
tetraethlyammonium hydroxide as the template was fabricated on
mullite tube via hydrothermal sol-gel synthesis in a rotating
autoclave reactor. The suitable synthesis condition was SiO2:Al2O3
ratio of 21.2 for 4 days at 155 °C crystallization under autogenous
pressure. The obtained SUZ-4 possessed a high BET surface area of
396.4 m2/g, total pore volume at 2.611 cm3/g, and narrow pore size
distribution with 97 nm mean diameter and 760 nm long of needle
crystal shape. The SUZ-4 layer obtained from seeding crystallization
was thicker than that of without seeds or in situ crystallization.", keywords = "Membrane, seeding, sol-gel, SUZ-4 Zeolite.", volume = "2", number = "11", pages = "318-5", }
