Abstract: In this study, multiwall carbon nanotubes (MWNTs)
were modified with nitric acid chemically and by dielectric barrier
discharge (DBD) plasma in an oxygen-based atmosphere. Used
carbon nanotubes (CNTs) were prepared by chemical vapour
deposition (CVD) floating catalyst method. For removing amorphous
carbon and metal catalyst, MWNTs were exposed to dry air and
washed with hydrochloric acid. Heating purified CNTs under helium
atmosphere caused elimination of acidic functional groups. Fourier
transformed infrared spectroscopy (FTIR) shows formation of
oxygen containing groups such as C=O and COOH. Brunauer,
Emmett, Teller (BET) analysis revealed that functionalization causes
generation of defects on the sidewalls and opening of the ends of
CNTs. Results of temperature-programmed desorption (TPD) and gas
chromatography(GC) indicate that nitric acid treatment create more
acidic groups than plasma treatment.
Abstract: More and more governments around the world are
introducing e-government as a means of reducing costs, improving
services, saving time and increasing effectiveness and efficiency in
the public sector Therefore e-government has been identified as one
of the top priorities for Saudi government and all its agencies.
However, the adoption of e-government is facing many challenges
and barriers such as technological, cultural, organizational, and social
issues which must be considered and treated carefully by any
government contemplating its adoption. This paper reports on a pilot
study amongst online (e-ready) citizens to identify the challenges and
barriers that affect the adoption of e-government services especially
from their perspective in Saudi society. Based on the analysis of data
collected from an online survey the researcher was able to identify
some of the important barriers and challenges from the e-ready
citizen perspective. As a result, this study has generated a list of
possible strategies to move towards successful adoption of egovernment
services in Saudi Arabia.
Abstract: The aim of this paper is description of the notion of
the death for prisoners and the ways of deal with. They express
indifference, coldness, inability to accept the blame, they have no
shame and no empathy. Is it enough to perform acts verging on the
death. In this paper we described mechanisms and regularities of selfdestructive
behaviour in the view of the relevant literature? The
explanation of the phenomenon is of a biological and sociopsychological
nature. It must be clearly stated that all forms of selfdestructive
behaviour result from various impulses, conflicts and
deficits. That is why they should be treated differently in terms of
motivation and functions which they perform in a given group of
people. Behind self-destruction there seems to be a motivational
mechanism which forces prisoners to rebel and fight against the hated
law and penitentiary systems. The imprisoned believe that pain and
suffering inflicted on them by themselves are better than passive
acceptance of repression. The variety of self-destruction acts is wide,
and some of them take strange forms. We assume that a life-death
barrier is a kind of game for them. If they cannot change the
degrading situation, their life loses sense.
Abstract: The effects of ethylene (C2H4) feed position and
O2/C2H4 feed molar ratio on ethylene epoxidation in a parallel
dielectric barrier discharge (DBD) were studied. The results showed
that the ethylene feed position fraction of 0.5 and the feed molar
ratio of O2/C2H4 of 0.2:1 gave the highest EO selectivity of 34.3%
and the highest EO yield of 5.28% with low power consumptions of
2.11×10-16 Ws/molecule of ethylene converted and 6.34×10-16
Ws/molecule of EO produced when the DBD system was operated
under the best conditions: an applied voltage of 19 kV, an input
frequency of 500 Hz and a total feed flow rate of 50 cm3/min. The
separate ethylene feed system provided much higher epoxidation
activity as compared to the mixed feed system which gave EO
selectivity of 15.5%, EO yield of 2.1% and the power consumption of
EO produced of 7.7×10-16 Ws/molecule.
Abstract: This presentation reviews recent advances in superalloys and thermal barrier coating (TBC) for application in hot sections of energy-efficient gas-turbine engines. It has been reviewed that in the modern combined-cycle gas turbines (CCGT) applying single-crystal energy materials (SC superalloys) and thermal barrier coatings (TBC), and – in one design – closed-loop steam cooling, thermal efficiency can reach more than 60%. These technological advancements contribute to profitable and clean power generation with reduced emission. Alternatively, the use of advanced superalloys (e.g. GTD-111 superalloy, Allvac 718Plus superalloy) and advanced thermal barrier coatings (TBC) in modern gas-turbines has been shown to yield higher energy-efficiency in power generation.
Abstract: Martensitic stainless steels have been extensively used for their good corrosion resistance and better mechanical properties. Heat treatment was suggested as one of the most excellent ways to this regard; hence, it affects the microstructure, mechanical and corrosion properties of the steel. In the current research work the microstructural changes and corrosion behavior in an AISI 420A stainless steel exposed to temperatures in the 980-1035oC range were investigated. The heat treatment is carried out in vacuum furnace within the said temperature range. The quenching of the samples was carried out in oil, brine and water media. The formation and stability of passive film was studied by Open Circuit Potential, Potentiodynamic polarization and Electrochemical Scratch Tests. The Electrochemical Impedance Spectroscopy results simulated with Equivalent Electrical Circuit suggested bilayer structure of outer porous and inner barrier oxide films. The quantitative data showed thick inner barrier oxide film retarded electrochemical reactions. Micrographs of the quenched samples showed sigma and chromium carbide phases which prove the corrosion resistance of steel alloy.
Abstract: Primary barrier of membrane type LNG containment system consist of corrugated 304L stainless steel. This 304L stainless steel is austenitic stainless steel which shows different material behaviors owing to phase transformation during the plastic work. Even though corrugated primary barriers are subjected to significant amounts of pre-strain due to press working, quantitative mechanical behavior on the effect of pre-straining at cryogenic temperatures are not available. In this study, pre-strain level and pre-strain temperature dependent tensile tests are carried to investigate mechanical behaviors. Also, constitutive equations with material parameters are suggested for a verification study.
Abstract: Mobile agent has motivated the creation of a new
methodology for parallel computing. We introduce a methodology
for the creation of parallel applications on the network. The proposed
Mobile-Agent parallel processing framework uses multiple Javamobile
Agents. Each mobile agent can travel to the specified
machine in the network to perform its tasks. We also introduce the
concept of master agent, which is Java object capable of
implementing a particular task of the target application. Master agent
is dynamically assigns the task to mobile agents. We have developed
and tested a prototype application: Mobile Agent Based Parallel
Computing. Boosted by the inherited benefits of using Java and
Mobile Agents, our proposed methodology breaks the barriers
between the environments, and could potentially exploit in a parallel
manner all the available computational resources on the network.
This paper elaborates performance issues of a mobile agent for
parallel computing.
Abstract: With the development of the Internet, E-commerce is
growing at an exponential rate, and lots of online stores are built up to
sell their goods online. A major factor influencing the successful
adoption of E-commerce is consumer-s trust. For new or unknown
Internet business, consumers- lack of trust has been cited as a major
barrier to its proliferation. As web sites provide key interface for
consumer use of E-Commerce, we investigate the design of web site to
build trust in E-Commerce from a design science approach. A
conceptual model is proposed in this paper to describe the ontology of
online transaction and human-computer interaction. Based on this
conceptual model, we provide a personalized webpage design
approach using Bayesian networks learning method. Experimental
evaluation are designed to show the effectiveness of web
personalization in improving consumer-s trust in new or unknown
online store.
Abstract: This paper explores gender related barriers to interagency collaboration in statutory children safeguard partnerships against a theoretical framework that considers individuals, professions and organisations interacting as part of a complex adaptive system. We argue that gender-framed obstacles to effective communication between culturally discrepant agencies can ultimately impact on the effectiveness of policy delivery,. We focused our research on three partnership structures in Sefton Metropolitan Borough in order to observe how interactions occur, whether the agencies involved perceive their occupational environment as being gender affected and whether they believe this can hinder effective collaboration with other biased organisations. Our principal empirical findings indicate that there is a general awareness amongst professionals of the role that gender plays in each of the agencies reviewed, that gender may well constitute a barrier to effective communication, but there is a sense in which there is little scope for change in the short term. We aim to signal here, however, the need to change against the risk of service failure.
Abstract: Australian government agencies have a natural desire
to provide migrants a wide range of opportunities. Consequently,
government online services should be equally available to migrants
with a non-English speaking background (NESB). Despite the
commendable efforts of governments and local agencies in Australia
to provide such services, in reality, many NESB communities are not
taking advantage of these services. This article–based on an
extensive case study regarding the use of online government services
by the Arabic NESB community in Australia–reports on the
possible reasons for this issue, as well as suggestions for
improvement. The conclusion is that Australia should implement
ICT-based or e-government policies, programmes, and services that
more accurately reflect migrant cultures and languages so that
migrant integration can be more fully accomplished. Specifically, this
article presents an NESB Model that adopts the value of usercentricity
or a more individual-focused approach to government
online services in Australia.
Abstract: Experiments with pumpkin-rowanberry marmalade
candies were carried out at the Faculty of Food Technology of the
Latvia University of Agriculture. The objective of this investigation
was to evaluate the quality changes of pumpkin-rowanberry
marmalade candies packed in different packaging materials during
the storage of 15 weeks, and to find the most suitable packaging
material for prolongation of low sugar marmalade candies shelf-life.
An active packaging in combination with modified atmosphere
(MAP, CO2 100%) was examined and compared with traditional
packaging in air ambiance. Polymer Multibarrier 60 and paper bags
were used. Influence of iron based oxygen absorber in sachets of 500
cc obtained from Mitsubishi Gas Chemical Europe Ageless® on the
marmalade candies’ quality was tested during shelf life. Samples of
80±5 g were packaged in polymer pouches (110 mm x 110 mm),
hermetically sealed by MULTIVAC C300 vacuum chamber machine,
and stored in a room temperature +21±0.5 °C. The physiochemical
properties –moisture content, hardness, aw, pH, changes of
atmosphere content (CO2 and O2), ascorbic acid, total carotenoids,
total phenols in headspace of packs, and microbial conditions were
analysed before packaging and in the 1st, 3rd , 5th, 8th, 11th and 15th
weeks of storage.
Abstract: In this paper, we present a vertical nanowire thin film transistor with gate-all-around architecture, fabricated using CMOS compatible processes. A novel method of fabricating polysilicon vertical nanowires of diameter as small as 30 nm using wet-etch is presented. Both n-type and p-type vertical poly-silicon nanowire transistors exhibit superior electrical characteristics as compared to planar devices. On a poly-crystalline nanowire of 30 nm diameter, high Ion/Ioff ratio of 106, low drain-induced barrier lowering (DIBL) of 50 mV/V, and low sub-threshold slope SS~100mV/dec are demonstrated for a device with channel length of 100 nm.
Abstract: Communication is an important factor and a prop in
directing corporate activities efficiently, in ensuring the flow of
knowledge which is necessary for the continuity of the institution, in
creating a common language in the institution, in transferring
corporate culture and ultimately in corporate success. The idea of
transmitting the knowledge among the workers in a healthy manner
has revived knowledge communication. Knowledge communication
can be defined as the act of mutual creation and communication of
intuitions, assessments, experiences and capabilities, as long as
maintained effectively, can provide advantages such as corporate
continuity, access to corporate objectives and making true
administrative decisions. Although the benefits of the knowledge
communication to corporations are known, and the necessary worth
and care is given, some hardships may arise which makes it difficult
or even block it. In this article, difficulties that prevent knowledge
communication will be discussed and solutions will be proposed.
Abstract: In recent years various types of electric vehicles
has gained again increasing attention as an environmentally
benign technology in transport. Especially for urban areas with
high local pollution this Zero-emission technology (at the point
of use) is considered to provide proper solutions. Yet, the bad
economics and the limited driving ranges are still major barriers
for a broader market penetration of battery electric vehicles
(BEV) and of fuel cell vehicles (FCV). The major result of our
analyses is that the most important precondition for a further
dissemination of BEV in urban areas are emission-free zones.
This is an instrument which allows the promotion of BEV
without providing excessive subsidies. In addition, it is
important to note that the full benefits of EV can only be
harvested if the electricity used is produced from renewable
energy sources. That is to say, it has to be ensured that the use of
BEV in urban areas is clearly linked to a green electricity
purchase model. And moreover, the introduction of a CO2-
emission-based tax system would support this requirement.
Abstract: Nanotechnology is the science of creating, using and
manipulating objects which have at least one dimension in range of
0.1 to 100 nanometers. In other words, nanotechnology is
reconstructing a substance using its individual atoms and arranging
them in a way that is desirable for our purpose.
The main reason that nanotechnology has been attracting
attentions is the unique properties that objects show when they are
formed at nano-scale. These differing characteristics that nano-scale
materials show compared to their nature-existing form is both useful
in creating high quality products and dangerous when being in
contact with body or spread in environment.
In order to control and lower the risk of such nano-scale particles,
the main following three topics should be considered:
1) First of all, these materials would cause long term diseases that
may show their effects on body years after being penetrated in human
organs and since this science has become recently developed in
industrial scale not enough information is available about their
hazards on body.
2) The second is that these particles can easily spread out in
environment and remain in air, soil or water for very long time,
besides their high ability to penetrate body skin and causing new
kinds of diseases.
3) The third one is that to protect body and environment against
the danger of these particles, the protective barriers must be finer than
these small objects and such defenses are hard to accomplish.
This paper will review, discuss and assess the risks that human and
environment face as this new science develops at a high rate.
Abstract: This paper presents the outcomes of a qualitative
study which aims to investigate the pedagogical potentials of serious
games in the preparation of future teachers. The authors discuss the
existing problems and barriers associated with the organization of
teaching practices in Bulgaria as part of the pre-service teacher
training, as well as the attitudes and perceptions of the interviewed
academics, teachers and trainees concerning the integration of serious
games in the teaching practicum. The study outcomes strongly
confirm the positive attitudes of the respondents to the introduction
of virtual learning environments for the development of professional
skills of future teachers as a supplement to the traditional forms of
education. Through the inclusion of serious games it is expected to
improve the quality of practical training of pre-service teachers as
they overcome many of the problems identified in the existing
teaching practices. The outcomes of the study will inform the design
of the educational simulation software which is part of the project
SimAula Tomorrow's Teachers Training.
Abstract: Magnesium alloys have gained increased attention in recent years in automotive, electronics, and medical industry. This because of magnesium alloys have better properties than aluminum alloys and steels in respects of their low density and high strength to weight ratio. However, the main problems of magnesium alloy welding are the crack formation and the appearance of porosity during the solidification. This paper proposes a unique technique to weld two thin sheets of AZ31B magnesium alloy using a paste containing Ag nanoparticles. The paste containing Ag nanoparticles of 5 nm in average diameter and an organic solvent was used to coat the surface of AZ31B thin sheet. The coated sheet was heated at 100 °C for 60 s to evaporate the solvent. The dried sheet was set as a lower AZ31B sheet on the jig, and then lap fillet welding was carried out by using a pulsed Nd:YAG laser in a closed box filled with argon gas. The characteristics of the microstructure and the corrosion behavior of the joints were analyzed by opticalmicroscopy (OM), energy dispersive spectrometry (EDS), electron probe micro-analyzer (EPMA), scanning electron microscopy (SEM), and immersion corrosion test. The experimental results show that the wrought AZ31B magnesium alloy can be joined successfully using Ag nanoparticles. Ag nanoparticles insert promote grain refinement, narrower the HAZ width and wider bond width compared to weld without and insert. Corrosion rate of welded AZ31B with Ag nanoparticles reduced up to 44 % compared to base metal. The improvement of corrosion resistance of welded AZ31B with Ag nanoparticles due to finer grains and large grain boundaries area which consist of high Al content. β-phase Mg17Al12 could serve as effective barrier and suppressed further propagation of corrosion. Furthermore, Ag distribution in fusion zone provide much more finer grains and may stabilize the magnesium solid solution making it less soluble or less anodic in aqueous
Abstract: At present, increased concerns about global
environmental problems have magnified the importance of
sustainability management. To move towards sustainability,
companies need to look at everything from a holistic perspective in
order to understand the interconnections between economic growth
and environmental and social sustainability. This paper aims to gain
an understanding of key determinants that drive sustainability
management and barriers that hinder its development. It employs
semi-structured interviews with key informants, site observation and
documentation. The informants are production, marketing and
environmental managers of the leading wine producer, which aims to
become an Asia-s leader in wine & wine based products. It is found
that corporate image and top management leadership are the primary
factors influencing the adoption of sustainability management. Lack
of environmental knowledge and inefficient communication are
identified as barriers.
Abstract: The research object was apple-black currant
marmalade candies. Experiments were carried out at the Faculty of
Food Technology of the Latvia University of Agriculture. An active
packaging in combination with modified atmosphere (MAP, CO2
100%) was examined and compared with traditional packaging in air
ambiance. Polymer Multibarrier 60 and paper bags were used.
Influence of iron based oxygen absorber in sachets of 500 cc
obtained from Mitsubishi Gas Chemical Europe Ageless® was tested
on the quality during the shelf of marmalade. Samples of 80±5 g
were packaged in polymer pouches (110 mm x 110 mm),
hermetically sealed by MULTIVAC C300 vacuum chamber machine,
and stored in room temperature +20.0±1.0 °C. The physiochemical
properties – weight losses, moisture content, hardness, aw, pH, colour,
changes of atmosphere content (CO2 and O2) in headspace of packs,
and microbial conditions were analysed before packaging and in the
1st, 3rd , 5th, 8th, 11th and 15th weeks of storage.