Abstract: Considering the demand to reduce global warming potential and importance of solidification in various applications, there is an increasing interest in energy storage systems to find the efficient phase change materials. Therefore, this paper presents an experimental study and comparison on the potential of titania nanofluids with and without surfactant for cooling energy storage systems. A designed cooling generation device based on compression refrigeration cycle is used to explore nanofluids solidification characteristics. In this work, titania nanoparticles of 0.01, 0.02 and 0.04 wt.% are dispersed in deionized water as base fluid. Measurement of phase change parameters of nanofluids illustrates that the addition of polyvinylpyrrolidone (PVP) as surfactant to titania nanofluids advances the onset nucleation time and leads to lower solidification time. Also, the experimental results show that only adding 0.02 wt.% titania nanoparticles, especially in the case of nanofluids with a surfactant, can evidently reduce the supercooling degree by nearly 70%. Hence, it is concluded that there is a great energy saving potential in the energy storage systems using titania nanofluid with PVP.
Abstract: Titania slag is a high quality raw material containing titanium in the subsequent process of titanium pigment. The effects of cooling approaches of granulating, water cooling, and air cooling on chemical, phases, and acidolysis of Panzhihua titania slag were investigated. Compared to the original slag which was prepared by the conventional processing route, the results show that the titania slag undergoes oxidation of Ti3+during different cooling ways. The Ti2O3 content is 17.50% in the original slag, but it is 16.55% and 16.84% in water cooled and air-cooled slag, respectively. Especially, the Ti2O3 content in granulated slag is decreased about 27.6%. The content of Fe2O3 in granulated slag is approximately 2.86% also obviously higher than water (
Abstract: This paper aims to discuss the hydrophilicity about the anodic aluminum oxide (AAO) template with titania nanotubes (NTs). The AAO templates with pore size diameters of 20-250 nm were generated by anodizing 6061 aluminum alloy substrates in acid solution of sulfuric acid (H2SO4), oxalic acid (COOH)2, and phosphoric acid (H3PO4), respectively. TiO2-NTs were grown on AAO templates by the sol-gel deposition process successfully. The water contact angle on AAO/TiO2-NTs surface was lower compared to the water contact angle on AAO surface. So, the characteristic of hydrophilicity was significantly associated with the AAO pore size and what kinds of materials were immersed variables.
Abstract: Rayleigh-B´enard convection of a nanoliquid in shallow, square and tall enclosures is studied using the Khanafer-Vafai-Lightstone single-phase model. The thermophysical properties of water, copper, copper-oxide, alumina, silver and titania at 3000 K under stagnant conditions that are collected from literature are used in calculating thermophysical properties of water-based nanoliquids. Phenomenological laws and mixture theory are used for calculating thermophysical properties. Free-free, rigid-rigid and rigid-free boundary conditions are considered in the study. Intractable Lorenz model for each boundary combination is derived and then reduced to the tractable Ginzburg-Landau model. The amplitude thus obtained is used to quantify the heat transport in terms of Nusselt number. Addition of nanoparticles is shown not to alter the influence of the nature of boundaries on the onset of convection as well as on heat transport. Amongst the three enclosures considered, it is found that tall and shallow enclosures transport maximum and minimum energy respectively. Enhancement of heat transport due to nanoparticles in the three enclosures is found to be in the range 3% - 11%. Comparison of results in the case of rigid-rigid boundaries is made with those of an earlier work and good agreement is found. The study has limitations in the sense that thermophysical properties are calculated by using various quantities modelled for static condition.
Abstract: The rapid depletion of high-grade iron ore (Fe2O3) has gained attention on the use of other sources of iron ore. Titaniferous magnetite ore (TMO) is a special type of magnetite ore having high titania content (23.23% TiO2 present in this case). Due to high TiO2 content and high density, TMO cannot be treated by the conventional smelting reduction. In this present work, the TMO has been collected from high-grade metamorphic terrain of the Precambrian Chotanagpur gneissic complex situated in the eastern part of India (Shaltora area, Bankura district, West Bengal) and the hematite ore has been collected from Visakhapatnam Steel Plant (VSP), Visakhapatnam. At VSP, iron ore is received from Bailadila mines, Chattisgarh of M/s. National Mineral Development Corporation. The preliminary characterization of TMO and hematite ore (HMO) has been investigated by WDXRF, XRD and FESEM analyses. Similarly, good quality of coal (mainly coking coal) is also getting depleted fast. The basic purpose of this work is to find how lean grade coal can be utilised along with TMO for smelting to produce pig iron. Lean grade coal has been characterised by using TG/DTA, proximate and ultimate analyses. The boiler grade coal has been found to contain 28.08% of fixed carbon and 28.31% of volatile matter. TMO fines (below 75 μm) and HMO fines (below 75 μm) have been separately agglomerated with lean grade coal fines (below 75 μm) in the form of briquettes using binders like bentonite and molasses. These green briquettes are dried first in oven at 423 K for 30 min and then reduced isothermally in tube furnace over the temperature range of 1323 K, 1373 K and 1423 K for 30 min & 60 min. After reduction, the reduced briquettes are characterized by XRD and FESEM analyses. The best reduced TMO and HMO samples are taken and blended in three different weight percentage ratios of 1:4, 1:8 and 1:12 of TMO:HMO. The chemical analysis of three blended samples is carried out and degree of metallisation of iron is found to contain 89.38%, 92.12% and 93.12%, respectively. These three blended samples are briquetted using binder like bentonite and lime. Thereafter these blended briquettes are separately smelted in raising hearth furnace at 1773 K for 30 min. The pig iron formed is characterized using XRD, microscopic analysis. It can be concluded that 90% yield of pig iron can be achieved when the blend ratio of TMO:HMO is 1:4.5. This means for 90% yield, the maximum TMO that could be used in the blend is about 18%.
Abstract: This research provides a systematic way to study and
better understand double nano-tubular structure of alunina (Al2O3) and
titania (TiO2). The TiO2 NT was prepared by immersing Al2O3
template in 0.02 M titanium fluoride (TiF4) solution (pH=3) at 25 °C
for 120 min, followed by annealing at 450 °C for 1 h to obtain anatase
TiO2 NT in the Al2O3 template. Large-scale development of film for
nanotube-based CO2 capture and conversion can potentially result in
more efficient energy harvesting. In addition, the production process
will be relatively environmentally friendly. The knowledge generated
by this research will significantly advance research in the area of
Al2O3, TiO2, CaO, and Ca2O3 nano-structure film fabrication and
applications for CO2 capture and conversion. This green energy source
will potentially reduce reliance on carbon-based energy resources and
increase interest in science and engineering careers.
Abstract: In this study, the experiments were carried out to
determine the best coolant for the quenching process among waterbased
silica, alumina, titania and copper oxide nanofluids (0.1 vol%).
A sphere made up off brass material was used in the experiments.
When the spherical test specimen was heated at high temperatures, it
was suddenly immersed into the nanofluids. All experiments were
carried out at saturated conditions and under atmospheric pressure.
After the experiments, the cooling curves were obtained by using the
temperature-time data of the specimen. The experimental results
showed that the cooling performance of test specimen depended on
the type of nanofluids. The silica nanoparticles enhanced the
performance of boiling heat transfer and it is the best coolant for the
quenching among other nanoparticles.
Abstract: Poly vinyl acetate (PVA)-based titania (TiO2)–carbon
nanotube composite nanofibers (PVA-TCCNs) with various
PVA-to-solvent ratios and PVA-based TiO2 composite nanofibers
(PVA-TN) were synthesized using an electrospinning process,
followed by thermal treatment. The photocatalytic activities of these
nanofibers in the degradation of airborne monocyclic aromatics under
visible-light irradiation were examined. This study focuses on the
application of these photocatalysts to the degradation of the target
compounds at sub-part-per-million indoor air concentrations. The
characteristics of the photocatalysts were examined using scanning
electron microscopy, X-ray diffraction, ultraviolet-visible
spectroscopy, and Fourier-transform infrared spectroscopy. For all the
target compounds, the PVA-TCCNs showed photocatalytic
degradation efficiencies superior to those of the reference PVA-TN.
Specifically, the average photocatalytic degradation efficiencies for
benzene, toluene, ethyl benzene, and o-xylene (BTEX) obtained using
the PVA-TCCNs with a PVA-to-solvent ratio of 0.3 (PVA-TCCN-0.3)
were 11%, 59%, 89%, and 92%, respectively, whereas those observed
using PVA-TNs were 5%, 9%, 28%, and 32%, respectively.
PVA-TCCN-0.3 displayed the highest photocatalytic degradation
efficiency for BTEX, suggesting the presence of an optimal
PVA-to-solvent ratio for the synthesis of PVA-TCCNs. The average
photocatalytic efficiencies for BTEX decreased from 11% to 4%, 59%
to 18%, 89% to 37%, and 92% to 53%, respectively, when the flow
rate was increased from 1.0 to 4.0 L min1. In addition, the average
photocatalytic efficiencies for BTEX increased 11% to ~0%, 59% to
3%, 89% to 7%, and 92% to 13%, respectively, when the input
concentration increased from 0.1 to 1.0 ppm. The prepared
PVA-TCCNs were effective for the purification of airborne aromatics
at indoor concentration levels, particularly when the operating
conditions were optimized.
Abstract: Rhodamine B (RB) is a toxic dye used extensively in
textile industry, which must be remediated before its drainage to
environment. In the present study, supported gold nanoparticles on
commercially available titania and zincite were successfully prepared
and then their activity on the photodegradation of RB under UV A
light irradiation were evaluated. The synthesized photocatalysts were
characterized by ICP, BET, XRD, and TEM. Kinetic results showed
that Au/TiO2 was an inferior photocatalyst to Au/ZnO. This
observation could be attributed to the strong reflection of UV
irradiation by gold nanoparticles over TiO2 support.
Abstract: This paper aims to scale up Dye-sensitized Solar Cell
(DSSC) production using a commonly available industrial material –
stainless steel - and industrial plasma equipment. A working DSSC
electrode formed by (1) coating titania nanotube (TiO2 NT) film on
304 stainless steel substrate using a plasma spray technique; then, (2)
filling the nano-pores of the TiO2 NT film using a TiF4 sol-gel method.
A DSSC device consists of an anode absorbed photosensitive dye
(N3), a transparent conductive cathode with platinum (Pt)
nano-catalytic particles adhered to its surface, and an electrolytic
solution sealed between the anode and the transparent conductive
cathode. The photo-current conversion efficiency of the DSSC sample
was tested under an AM 1.5 Solar Simulator. The sample has a short
current (Isc) of 0.83 mA cm-2, open voltage (Voc) of 0.81V, filling
factor (FF) of 0.52, and conversion efficiency (η) of 2.18% on a 0.16
cm2 DSSC work-piece.
Abstract: The steady mixed convection boundary layer flow from
a vertical cone in a porous medium filled with a nanofluid is
numerically investigated using different types of nanoparticles as Cu
(copper), Al2O3 (alumina) and TiO2 (titania). The boundary value
problem is solved by using the shooting technique by reducing it
into an ordinary differential equation. Results of interest for the local
Nusselt number with various values of the constant mixed convection
parameter and nanoparticle volume fraction parameter are evaluated.
It is found that dual solutions exist for a certain range of mixed
convection parameter.
Abstract: In this study, we sought to investigate the mercury
removal efficiency of manganese oxides from natural gas. The
fundamental studies on mercury removal with manganese oxides
sorbents were carried out in a laboratory scale fixed bed reactor at 30
°C with a mixture of methane (20%) and nitrogen gas laden with 4.8
ppb of elemental mercury. Manganese oxides with varying surface
area and crystalline phase were prepared by conventional precipitation
method in this study. The effects of surface area, crystallinity and
other metal oxides on mercury removal efficiency were investigated.
Effect of Ag impregnation on mercury removal efficiency was also
investigated. Ag supported on metal oxide such titania and zirconia as
reference materials were also used in this study for comparison. The
characteristics of mercury removal reaction with manganese oxide
was investigated using a temperature programmed desorption (TPD)
technique.
Manganese oxides showed very high Hg removal activity (about
73-93% Hg removal) for first time use. Surface area of the manganese
oxide samples decreased after heat-treatment and resulted in complete
loss of Hg removal ability for repeated use after Hg desorption in the
case of amorphous MnO2, and 75% loss of the initial Hg removal
activity for the crystalline MnO2. Mercury desorption efficiency of
crystalline MnO2 was very low (37%) for first time use and high (98%)
after second time use. Residual potassium content in MnO2 may have
some effect on the thermal stability of the adsorbed Hg species.
Desorption of Hg from manganese oxides occurs at much higher
temperatures (with a peak at 400 °C) than Ag/TiO2 or Ag/ZrO2.
Mercury may be captured on manganese oxides in the form of mercury
manganese oxide.
Abstract: Nano-MgO was successfully deposited on titania using deposition-precipitation method. The catalyst produced was characterised using FTIR, XRD, BET and XRF and its activity was tested on the transesterification reaction of soybean oil to biodiesel. The catalyst activity improved when the reaction temperature was increasedfrom 150 and 225 OC. It was also observed that increasing the reaction time above 1h had no significant benefit on conversion. The stability fixed MgO on TiO2 was investigated using XRF and ICP-OES. It was observed that MgO loss during the reaction was between 0.5-2.3 percent and that there was no correlation between the reaction temperature and the MgO loss.
Abstract: TiO2 nanoparticles were synthesized by hydrothermal
method at 180°C from TiOSO4 aqueous solution with1m/l
concentration. The obtained products were coated with silica by
means of a seeded polymerization technique for a coating time of
1440 minutes to obtain well defined TiO2@SiO2 core-shell structure.
The uncoated and coated nanoparticles were characterized by using
X-Ray diffraction technique (XRD), Fourier Transform Infrared
Spectroscopy (FT-IR) to study their physico-chemical properties.
Evidence from XRD and FTIR results show that SiO2 is
homogenously coated on the surface of titania particles. FTIR spectra
show that there exists an interaction between TiO2 and SiO2 and
results in the formation of Ti-O-Si chemical bonds at the interface of
TiO2 particles and SiO2 coating layer. The non linear optical limiting
properties of TiO2 and TiO2@SiO2 nanoparticles dispersed in
ethylene glycol were studied at 532nm using 5ns Nd:YAG laser
pulses. Three-photon absorption is responsible for optical limiting
characteristics in these nanoparticles and it is seen that the optical
nonlinearity is enhanced in core-shell structures when compared with
single counterparts. This effective three-photon type absorption at
this wavelength, is of potential application in fabricating optical
limiting devices.
Abstract: This research study the application of the immobilized
TiO2 layer and Cu-TiO2 layer on graphite substrate as a negative
electrode or anode for Li-ion battery. The titania layer was produced
through chemical bath deposition method, meanwhile Cu particles
were deposited electrochemically. A material can be used as an
electrode as it has capability to intercalates Li ions into its crystal
structure. The Li intercalation into TiO2/Graphite and Cu-
TiO2/Graphite were analyzed from the changes of its XRD pattern
after it was used as electrode during discharging process. The XRD
patterns were refined by Le Bail method in order to determine the
crystal structure of the prepared materials. A specific capacity and the
cycle ability measurement were carried out to study the performance
of the prepared materials as negative electrode of the Li-ion battery.
The specific capacity was measured during discharging process from
fully charged until the cut off voltage. A 300 was used as a load.
The result shows that the specific capacity of Li-ion battery with
TiO2/Graphite as negative electrode is 230.87 ± 1.70mAh.g-1 which is
higher than the specific capacity of Li-ion battery with pure graphite
as negative electrode, i.e 140.75 ±0.46mAh.g-1. Meanwhile
deposition of Cu onto TiO2 layer does not increase the specific
capacity, and the value even lower than the battery with
TiO2/Graphite as electrode. The cycle ability of the prepared battery
is only two cycles, due to the Li ribbon which was used as cathode
became fragile and easily broken.
Abstract: Highly ordered TiO2 nanotube (TNT) arrays were
fabricated onto a pre-treated titanium foil by anodic oxidation with a
voltage of 20V in phosphoric acid/sodium fluoride electrolyte. A pretreatment
of titanium foil involved washing with acetone,
isopropanol, ethanol and deionized water. Carbon doped TiO2
nanotubes (C-TNT) was fabricated 'in-situ' with the same method in
the presence of polyvinyl alcohol and urea as carbon sources. The
affects of polyvinyl alcohol concentration and oxidation time on the
composition, morphology and structure of the C-TN were studied by
FE-SEM, EDX and XRD techniques. FESEM images of the
nanotubes showed uniform arrays of C-TNTs. The density and
microstructures of the nanotubes were greatly affected by the content
of PVA. The introduction of the polyvinyl alcohol into the electrolyte
increases the amount of C content inside TiO2 nanotube arrays
uniformly. The influence of carbon content on the photo-current of
C-TNT was investigated and the I-V profiles of the nanotubes were
established. The preliminary results indicated that the 'in-situ'
doping technique produced a superior quality nanotubes compared to
post doping techniques.
Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.