Submicron Size of Alumina/Titania Tubes for CO2-CH4 Conversion

This research provides a systematic way to study and
better understand double nano-tubular structure of alunina (Al2O3) and
titania (TiO2). The TiO2 NT was prepared by immersing Al2O3
template in 0.02 M titanium fluoride (TiF4) solution (pH=3) at 25 °C
for 120 min, followed by annealing at 450 °C for 1 h to obtain anatase
TiO2 NT in the Al2O3 template. Large-scale development of film for
nanotube-based CO2 capture and conversion can potentially result in
more efficient energy harvesting. In addition, the production process
will be relatively environmentally friendly. The knowledge generated
by this research will significantly advance research in the area of
Al2O3, TiO2, CaO, and Ca2O3 nano-structure film fabrication and
applications for CO2 capture and conversion. This green energy source
will potentially reduce reliance on carbon-based energy resources and
increase interest in science and engineering careers.




References:
[1] Inoue T, Fujishima A, Konishi S, Honda K, “Photoelectrocatalytic
Reduction of Carbon Dioxide in Aqueous Suspensions of Semiconductor
Powders”, Nature, vol. 277, pp. 637-638, 1979.
[2] Halmann M, Ulman M, Blajeni BA, “Photochemical Solar Collector for
The Photoassisted Reduction of Aqueous Carbon Dioxide”, Sol. Energy,
vol. 31, pp. 429-431, 1983.
[3] Adachi K, Ohta K, Mizuna T, “Photocatalytic Reduction of Carbon
Dioxide to Hydrocarbon Using Copper-load Titanium Dioxide”, Sol.
Energy, vol. 53, pp. 187-190, 1994.
[4] Anpo M, Yamashita H, Ichihashi Y, Ehara S, “Photocatalytic Reduction
of CO2 with H2O on Various Titanium Oxide Catalysts”, J. Electroanal.
Chem., vol. 396, pp. 21-26, 1995.
[5] Thampi KR, Kiwi J, Graetzel M, “Methanation and Photo-methanation of
Carbon Dioxide at Room Temperature and Atmospheric Pressure”,
Nature, vol. 327, pp. 506-508, 1987.
[6] Zumdahl SS, Zumdahl SA, Chemistry, 7TH edition, Houghton Mifflin,
New York, USA, pp. 353, 2009.
[7] Ohko Y, Tryk DA, Hashimoto K, Fujishima A, “Autoxidation of
Acetaldehyde Initiated by TiO2 Photocatalysis under Weak UV
Illumination” , J. Phys. Chem. B, vol. 102, pp. 2699-2704, 1998.
[8] Ishitani O, Inoue C, Suzuki Y, Ibusuki T, “Photocatalytic Reduction of
Carbon Dioxide to Methane and Acetic Acid by an Aqueous Suspension
of Metal-deposited TiO2”, J. Photochem. Photobiol. A: Chem., vol. 72, pp.
269-271, 1993.
[9] Slamet HW, Nasution E, Purnama S, Kosela J, Gunlazuardi J,
“Photocatalytic Reduction of CO2 on Copper-doped Titania Catalysts
Prepared by Improved-impregnation Method”, Catal. Commun.,vol. 6, pp.
313-319, 2005.
[10] Varghese OK, Paulose M, Tempa TJ, Grimes CA, “High-Rate Solar
Photocatalytic Conversion of CO2 and Water Vapor to Hydrocarbon
Fuels”, Nano Letts., vol. 9, pp. 731-737, 2009.
[11] Chen CC, Chen JH, Chao CG, “Post-treatment Method of Producing
Ordered Array of Anodic Aluminum Oxide Using General Purity
Commercial (99.7%) Aluminum”, Jpn. J. Appl. Phys., vol. 44, pp.
1529-1533, 2005.
[12] Chen SH, Chen CC, Luo ZP, Chao CG, “Fabrication and characterization
of eutectic bismuth-tin (Bi-Sn) nanowires”, Mater. Lett., vol. 63, pp.
1665-1668, 2009.
[13] Chen SH, Chen CC, Chao CG, “Novel Morphology and Solidification
Behavior of Eutectic Bismuth-Tin (Bi-Sn) Nanowires”, J. Alloys and
Compounds, vol. 481, pp. 270-273, 2009.
[14] Chen CC, Cheng CH, Tang G, Lin T, Lin CK, “Template Assisted
Fabrication of TiO2 and BaTiO3 Nanotubes”, Applied Mechanics and
Materials, vol. 271-272, pp. 107-111, 2013.