Abstract: This research provides a systematic way to study and
better understand double nano-tubular structure of alunina (Al2O3) and
titania (TiO2). The TiO2 NT was prepared by immersing Al2O3
template in 0.02 M titanium fluoride (TiF4) solution (pH=3) at 25 °C
for 120 min, followed by annealing at 450 °C for 1 h to obtain anatase
TiO2 NT in the Al2O3 template. Large-scale development of film for
nanotube-based CO2 capture and conversion can potentially result in
more efficient energy harvesting. In addition, the production process
will be relatively environmentally friendly. The knowledge generated
by this research will significantly advance research in the area of
Al2O3, TiO2, CaO, and Ca2O3 nano-structure film fabrication and
applications for CO2 capture and conversion. This green energy source
will potentially reduce reliance on carbon-based energy resources and
increase interest in science and engineering careers.
Abstract: This paper aims to scale up Dye-sensitized Solar Cell
(DSSC) production using a commonly available industrial material –
stainless steel - and industrial plasma equipment. A working DSSC
electrode formed by (1) coating titania nanotube (TiO2 NT) film on
304 stainless steel substrate using a plasma spray technique; then, (2)
filling the nano-pores of the TiO2 NT film using a TiF4 sol-gel method.
A DSSC device consists of an anode absorbed photosensitive dye
(N3), a transparent conductive cathode with platinum (Pt)
nano-catalytic particles adhered to its surface, and an electrolytic
solution sealed between the anode and the transparent conductive
cathode. The photo-current conversion efficiency of the DSSC sample
was tested under an AM 1.5 Solar Simulator. The sample has a short
current (Isc) of 0.83 mA cm-2, open voltage (Voc) of 0.81V, filling
factor (FF) of 0.52, and conversion efficiency (η) of 2.18% on a 0.16
cm2 DSSC work-piece.