Effect of Greywater Irrigation on Air-Water Interfacial area in Porous Medium

In this study, the effect of greywater irrigation on airwater interfacial area is investigated. Several soil column experiments were conducted for different greywater irrigation to develop the pressure-saturation curves. Surface tension was measured for different greywater concentration and fitted for Gibbs adsorption equation. Pressure-saturation curves show that the reduction of capillary rise stops when it reaches its critical micelle concentration (CMC). A simple theory is derived from pressure-saturation curves for calculating air-water interfacial area in porous medium during greywater irrigation by introducing a term 'hydraulic radius' for the pores. This term diminishes any effect of pore shapes on the air-water interfacial area. The air-water interfacial area was calculated using the pressure-saturation curves and found that it decreases with increasing moisture content. But no significant effect was observed on air-water interfacial area for different greywater irrigation. A maximum of 10% variation in interfacial area was observed at the residual saturation zone.





References:
[1] Travis, M.J., Weisbrod, N. and Gross, A., Accumulation of oil and grease in soils irrigated with greywater and their potential role in soil
water repellency, Sci. Total Environ., 2008, vol. 394(1), pp. 68-74.
[2] Friedler, E., Quality of individual domestic greywater streams and its
implication for on-site treatment and reuse possibilities, Environ.
Technol. 2004, vol. 25(9), pp. 997-1008.
[3] DHWA (Deaprtement of Health Western Australia), Code of Practice
for the reuse of greywater in Western Australia, 2005.
[4] Shafran, A.W., Gross, A., Ronen, Z., Weisbrod, N. and Adar, E., Effects
of surfactants originating from reuse of greywater on capillary rise in the
soil, Water Sci. & Technol., 2005, vol. 52(10-11), pp. 157-166.
[5] Shafran, A.W., Ronen, Z., Weisbrod, N., Adar, E. and Gross, A.,
Potential changes in soil properties following irrigation with surfactantrich
greywater, Ecol. Eng. 2006, vol. 26(4), pp. 348-354.
[6] Abu-Zreig, M., Rudra, P.R. and Dickinson, T.W., Effect of application
of surfactants on hydraulic properties of soils", Biosyst. Eng., 2003, vol.
84(3), pp. 363-372.
[7] Anwar, A.H.M.F., Bettahar, M. and Matsubayashi, U., A method for
determining air-water interfacial area in variably saturated porous media.
J. of Contam. Hydrol., 2000, vol. 43(2), pp. 129-146.
[8] Anwar, A.H.M.F., Effect of Greywater Irrigation on Soil Characteristics,
In Proc. of Int. Conf. Environ. Sci. & Develop (CD-ROM), Mumbai
India, pp. 15-18, January, 2011.
[9] Misra, R.K. and Sivongxay, A., Reuse of laundry greywater as affected
by its interaction with saturated soil, J. of Hydrol., 2009, vol. 366(1-4),
pp. 55-61.
[10] Bradford, S. A. and Leij, F. J., Estimating interfacial areas for multifluid
soil systems. J. of Contam. Hydrol., 1997, vol. 27, pp. 83-105.
[11] Reeves, P. C. and Celia, M. A., A functional relationship between
capillary pressure, saturation and interfacial area as revealed by a porescale
network model. Water Resour. Res., 1996, vol. 32(8), 2345-2358.
[12] Kawanishi, T., Hayashi, W., Roberts, P. V. and Blunt, M. J., Fluid-fluid
interfacial area during two and three phase fluid displacement in porous
media: A network model study. Proc. of the GQ-98 conf. on
Groundwater quality: Remediation and Protection, Tubingen, Germany.
IAHS publ., 1998, no. 250, pp. 89-96.
[13] Skopp, J., Oxygen uptake and transport in soils: Analysis of the airwater
interfacial area. Soil Sci. Soc. Am. J., 1985, vol. 49(6), pp. 1327-
1331.
[14] Miller, C. T., Poirier-McNeill, M. M. and Mayer, A.S., Dissolution of
trapped nonaqueous phase liquids: Mass transfer characteristics. Water
Resour. Res., 1990, vol. 26(11), pp. 2783-2796.
[15] Cary, J. W., Estimating the surface area of fluid phase interfaces in
porous media. J. of Contam. Hydrol., 1994, vol. 15, pp. 243-248.
[16] Karkare, M. V. and Fort, T., Determination of the air-water interfacial
area in wet unsaturated porous media. Langmuir, 1996, vol. 12(8), pp.
2041-2044.
[17] Kim, H., Rao, P. S. C. and Annable, M. D., Determination of effective
air-water interfacial area in partially saturated porous media using
surfactant adsorption. Water Resour. Res., 1997, vol. 33(12), pp. 2705-
2711.
[18] Schaefer, C. E., D. A. DiCarlo, and M. J. Blunt, Experimental
measurement of air-water interfacial area during gravity drainage and
secondary imbibitions in porous media, Water Resour. Res., 2000, vol.
36, pp. 885- 890.
[19] Montemagno, C. D., and W. G. Gray, Photoluminescent volumetric
imaging: A technique for the exploration of multiphase flow and
transport in porous media, Geophys. Res. Lett., 1995, vol. 22(4), pp.
425- 428, doi:10.1029/ 94GL02697
[20] Culligan, K. A., D. Wildenschild, B. S. B. Christensen, W. G. Gray, M.
L. Rivers, and A. F. B. Tompson, Interfacial area measurements for unsaturated flow through a porous medium, Water Resour. Res., 2004,
vol. 40, W12413, doi:10.1029/2004WR003278.
[21] Brusseau, M. L., S. Peng, G. Schnaar, and A. Murao, Measuring
airwater interfacial areas with X-ray microtomography and interfacial
partitioning tracer tests, Environ. Sci. Technol., 2007, vol. 41, pp. 1956–
1961.
[22] Costanza-Robinson, M. S., K. H. Harrold, and R. M. Lieb-Lappen, Xray
microtomography determination of air-water interfacial area-water
saturation relationships in sandy porous media, Environ. Sci. Technol.,
2008, vol. 42, pp. 2949–2956.
[23] Anwar, A. H. M. F. and Matsubayashi, U., Method of estimating airliquid
interfacial area using soil characteristics curve. J. of Groundwater
Hydrol., 2000, vol. 42(2), pp. 159-174.
[24] Dullien, F. A. L., Porous media: Fluid transport and pore structure.
Academic, New York, 1979.
[25] Rosen, M. J., Surfactant and interfacial phenomena. John Wiley, New
York, 1989.
[26] Lanfax Lab, http://www.lanfaxlabs.com.au/ (accessed August 15, 2010)