Effect of Different Conditions on the Sorption Behavior of Co2+ Using Celatom- ZeoliteY Composite
Composite of Celatom-ZeoliteY (Cel-ZY) was used to
remove cobalt ion from an aqueous solution using batch mode.
ZeoliteY has successfully superimposed on Celatom FW-14 surface
using hydrothermal treatment .The product was synthesized as a
novel of hierarchical porous material. It was observed from the
results that Cel-ZY has higher ability to remove cobalt ions than the
pure ZeoliteY powder (PZY) synthesized under the same conditions.
Several parameters were studied in this project to investigate the
effect of removal cobalt ion such as pH and initial cobalt
concentration. It was clearly observed that the uptake of cobalt ions
was affected with increase these parameters. The results proved that
the product can be used effectively to remove Co2+ ions from
wastewater as an environmentally friendly alternative.
<p>[1] ND M.Dulama, M.Pavelesscu, L.Pasare, “ Combined radioactivity
liquid waste treatment process involving inorganic sorbents and micro/
altrafiltration”, journal physics 2009;Vol: 54 (Bucharest).
[2] I EnDyna, ” Potential nano-enabled environmental application of
radionuclides”, Environmental Protection Agency,EPA/402/R-09/002
January 2009(Washington, DC 20460).
[3] M Streat, J Patrick, M Perez ,“Sorption of phenol and parachlorophenol
from water using conventional and novel activated
carbons”, Water Research 1995;29(2):467-472.
[4] A Chmielewski, M Harasimowicz, G Zakrzewska-Trznadel,” Membrane
technologies for liquid radioactive waste treatment”, Czechoslovak
Journal of Physics 1999;49(0):979-985.
[5] HEGMM Bakr, ” Diatomite : its characterization, modifications and
applications” , Asian Journal of Materials Science 2010;2(3):121-136.
[6] H Arik, ”Synthesis of Si3N4 by the carbo-thermal reduction and
nitridation of diatomite”, Journal of the European Ceramic Society
2003;23((12)): pp. 2005-2014.
[7] MS Hassan, I.A. Ibrahim, I.S. Ismael, “Diatomaceous deposits of
Fayium, Egypt: Characterization and evaluation for industrial
application”, Chinese J .Geochemis.1999;18:233-241.
[8] DL Durham”Diatomite” Us Geological Mineral Resource,Us
Geological Survey Professional Paper 1973;820:pp.191–5.
[9] B Gao, P Jiang, F An, S Zhao, Z Ge ” Studies on the surface
modification of diatomite with polyethyleneimine and trapping effect of
the modified diatomite for phenol” Applied surface science
2005;250(1):273-279.
[10] RP Xu, W.; J.Yu; Q Huo; J Chen and Z Gao “Chemistry of Zeolite and
related porous materials”. Wiley: Singapore 2007:pp 145-146.
0
50
100
150
200
0 100 200 300 400
Adsorption capacity qe (mg/g)
Equlibrium concentration Ce (mg/L)
Exp. Data
Langmuir model
Frenudlich model
0
5E-09
1E-08
1.5E-08
2E-08
2.5E-08
3E-08
0 2 4 6
Separation Factor (RL)
Initial Concentration C0 (mg/L)
[11] ER Allen, and D.W. Ming. “Recent progress in the use of natural
zeolites in agronomy and horticulture”, International Committee on
Natural Zeolites,1995(Brockport, N.Y):477-490.
[12] N Gao, S Kume, K Watari “Zeolite–carbon composites prepared from
industrial wastes:(I) Effects of processing parameters” Materials
Science and Engineering: A 2005;399(1):216-221.
[13] A Dyer,” An introduction to zeolite molecular sieves”, 1988.
[14] O Hernandez-Ramirez,” Hierarchical bio-structures incorporating zeolite
Y for wastewater treatment applications”, A thesis submitted to the
University of Manchester for the degree of Doctor of Philosophy in the
Faculty of Engineering and Physical Sciences 2009.
[15] O Hernández-Ramírez, PI Hill, DJ Doocey, SM Holmes, ” Removal and
immobilisation of cobalt ions by a novel, hierarchically structured,
diatomite/zeolite Y composite”, Journal of Materials Chemistry
2007;17(18):1804-1808.
[16] I Kula, M Ugurlu, H Karaoglu, A Çelik, “Adsorption of Cd (II) ions
from aqueous solutions using activated carbon prepared from olive stone
by ZnCl2 activation”,Bioresource Technology 2008;99(3):492-501.
[17] S Wang, H Li, L Xu ,”Application of zeolite MCM-22 for basic dye
removal from wastewater”, Journal of colloid and interface science
2006;295(1):71-78.
[18] A El-Kamash, ”Evaluation of zeolite A for the sorptive removal of Cs<
sup>+</sup> and Sr< sup> 2+</sup> ions from aqueous solutions using
batch and fixed bed column operations”, Journal of Hazardous
Materials 2008;151(2):432-445.
[19] G Memon, M Bhanger, M Akhtar,”Peach-nut shells-an effective and low
cost adsorbent for the removal of endosulfan from aqueous solutions”,
Pak. J. Anal. Environ. Chem 2009;10:14-18.
[20] MMJ Treacy, JB Higgins, R von Ballmoos,Commission IZAS,”
Collection of simulated XRD powder patterns for zeolites”, Elsevier
New York; 1996.
[21] VJ Inglezakis, C.D Papadeus, M.D Loizidou, H.P Grigoropoulou,”
Effects of pretreatment on physical and ion exchange properties of
natural clinoptilolite” Environ.Technol. 2001;22:75– 82.
[22] M Doula, A.Ioannou, A.Dimirkou, “Copper adsorption and Si, Al, Ca,
Mg, and Na release from clinoptilolite”. J.Colloid Interface 2002;Sci.
245:237– 250.
[23] MI Panayotova,” Kinetics and thermodynamics of copper ions removal
from wastewater by use of zeolite”, Waste Manag. 2001;21:671– 676.
[24] O Hernandez-Ramirez, SK Al-Nasri, SM Holmes, ”Hierarchical
structures based on natural carbons and zeolites”, Journal of Materials
Chemistry 2011;21(41):16529-16534.
[25] YB Onundi, A Mamun, M Al Khatib, Y Ahmed ,”Adsorption of copper,
nickel and lead ions from Synthetic semiconductor industrial wastewater
by palm shell activated carbon”, Int. J. Environ. Sci. Tech
2010;7(4):751-758.
[26] AM Ei-Kamash “Evaluation of zeolite A for the sportive removal of
Cs+ and Sr2+ions from aqueous solutions using batch and fixed bed
column operation”, Hazardous Materials 2007;151(2008):432-445.
[27] YS Ho ,” Isotherms for the sorption of lead onto peat:comparison of
linear and non-linear methods”, Polish Journal of Environmental Studies
2006;15(1):81-86.</p>
<p>[1] ND M.Dulama, M.Pavelesscu, L.Pasare, “ Combined radioactivity
liquid waste treatment process involving inorganic sorbents and micro/
altrafiltration”, journal physics 2009;Vol: 54 (Bucharest).
[2] I EnDyna, ” Potential nano-enabled environmental application of
radionuclides”, Environmental Protection Agency,EPA/402/R-09/002
January 2009(Washington, DC 20460).
[3] M Streat, J Patrick, M Perez ,“Sorption of phenol and parachlorophenol
from water using conventional and novel activated
carbons”, Water Research 1995;29(2):467-472.
[4] A Chmielewski, M Harasimowicz, G Zakrzewska-Trznadel,” Membrane
technologies for liquid radioactive waste treatment”, Czechoslovak
Journal of Physics 1999;49(0):979-985.
[5] HEGMM Bakr, ” Diatomite : its characterization, modifications and
applications” , Asian Journal of Materials Science 2010;2(3):121-136.
[6] H Arik, ”Synthesis of Si3N4 by the carbo-thermal reduction and
nitridation of diatomite”, Journal of the European Ceramic Society
2003;23((12)): pp. 2005-2014.
[7] MS Hassan, I.A. Ibrahim, I.S. Ismael, “Diatomaceous deposits of
Fayium, Egypt: Characterization and evaluation for industrial
application”, Chinese J .Geochemis.1999;18:233-241.
[8] DL Durham”Diatomite” Us Geological Mineral Resource,Us
Geological Survey Professional Paper 1973;820:pp.191–5.
[9] B Gao, P Jiang, F An, S Zhao, Z Ge ” Studies on the surface
modification of diatomite with polyethyleneimine and trapping effect of
the modified diatomite for phenol” Applied surface science
2005;250(1):273-279.
[10] RP Xu, W.; J.Yu; Q Huo; J Chen and Z Gao “Chemistry of Zeolite and
related porous materials”. Wiley: Singapore 2007:pp 145-146.
0
50
100
150
200
0 100 200 300 400
Adsorption capacity qe (mg/g)
Equlibrium concentration Ce (mg/L)
Exp. Data
Langmuir model
Frenudlich model
0
5E-09
1E-08
1.5E-08
2E-08
2.5E-08
3E-08
0 2 4 6
Separation Factor (RL)
Initial Concentration C0 (mg/L)
[11] ER Allen, and D.W. Ming. “Recent progress in the use of natural
zeolites in agronomy and horticulture”, International Committee on
Natural Zeolites,1995(Brockport, N.Y):477-490.
[12] N Gao, S Kume, K Watari “Zeolite–carbon composites prepared from
industrial wastes:(I) Effects of processing parameters” Materials
Science and Engineering: A 2005;399(1):216-221.
[13] A Dyer,” An introduction to zeolite molecular sieves”, 1988.
[14] O Hernandez-Ramirez,” Hierarchical bio-structures incorporating zeolite
Y for wastewater treatment applications”, A thesis submitted to the
University of Manchester for the degree of Doctor of Philosophy in the
Faculty of Engineering and Physical Sciences 2009.
[15] O Hernández-Ramírez, PI Hill, DJ Doocey, SM Holmes, ” Removal and
immobilisation of cobalt ions by a novel, hierarchically structured,
diatomite/zeolite Y composite”, Journal of Materials Chemistry
2007;17(18):1804-1808.
[16] I Kula, M Ugurlu, H Karaoglu, A Çelik, “Adsorption of Cd (II) ions
from aqueous solutions using activated carbon prepared from olive stone
by ZnCl2 activation”,Bioresource Technology 2008;99(3):492-501.
[17] S Wang, H Li, L Xu ,”Application of zeolite MCM-22 for basic dye
removal from wastewater”, Journal of colloid and interface science
2006;295(1):71-78.
[18] A El-Kamash, ”Evaluation of zeolite A for the sorptive removal of Cs<
sup>+</sup> and Sr< sup> 2+</sup> ions from aqueous solutions using
batch and fixed bed column operations”, Journal of Hazardous
Materials 2008;151(2):432-445.
[19] G Memon, M Bhanger, M Akhtar,”Peach-nut shells-an effective and low
cost adsorbent for the removal of endosulfan from aqueous solutions”,
Pak. J. Anal. Environ. Chem 2009;10:14-18.
[20] MMJ Treacy, JB Higgins, R von Ballmoos,Commission IZAS,”
Collection of simulated XRD powder patterns for zeolites”, Elsevier
New York; 1996.
[21] VJ Inglezakis, C.D Papadeus, M.D Loizidou, H.P Grigoropoulou,”
Effects of pretreatment on physical and ion exchange properties of
natural clinoptilolite” Environ.Technol. 2001;22:75– 82.
[22] M Doula, A.Ioannou, A.Dimirkou, “Copper adsorption and Si, Al, Ca,
Mg, and Na release from clinoptilolite”. J.Colloid Interface 2002;Sci.
245:237– 250.
[23] MI Panayotova,” Kinetics and thermodynamics of copper ions removal
from wastewater by use of zeolite”, Waste Manag. 2001;21:671– 676.
[24] O Hernandez-Ramirez, SK Al-Nasri, SM Holmes, ”Hierarchical
structures based on natural carbons and zeolites”, Journal of Materials
Chemistry 2011;21(41):16529-16534.
[25] YB Onundi, A Mamun, M Al Khatib, Y Ahmed ,”Adsorption of copper,
nickel and lead ions from Synthetic semiconductor industrial wastewater
by palm shell activated carbon”, Int. J. Environ. Sci. Tech
2010;7(4):751-758.
[26] AM Ei-Kamash “Evaluation of zeolite A for the sportive removal of
Cs+ and Sr2+ions from aqueous solutions using batch and fixed bed
column operation”, Hazardous Materials 2007;151(2008):432-445.
[27] YS Ho ,” Isotherms for the sorption of lead onto peat:comparison of
linear and non-linear methods”, Polish Journal of Environmental Studies
2006;15(1):81-86.</p>
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:50538", author = "Salam K. Al-Nasri and SM Holmes", title = "Effect of Different Conditions on the Sorption Behavior of Co2+ Using Celatom- ZeoliteY Composite", abstract = "Composite of Celatom-ZeoliteY (Cel-ZY) was used to
remove cobalt ion from an aqueous solution using batch mode.
ZeoliteY has successfully superimposed on Celatom FW-14 surface
using hydrothermal treatment .The product was synthesized as a
novel of hierarchical porous material. It was observed from the
results that Cel-ZY has higher ability to remove cobalt ions than the
pure ZeoliteY powder (PZY) synthesized under the same conditions.
Several parameters were studied in this project to investigate the
effect of removal cobalt ion such as pH and initial cobalt
concentration. It was clearly observed that the uptake of cobalt ions
was affected with increase these parameters. The results proved that
the product can be used effectively to remove Co2+ ions from
wastewater as an environmentally friendly alternative.
", keywords = "Adsorption, Celatom-Zeolite, Cobalt ions, Isotherm
models.", volume = "7", number = "9", pages = "644-7", }
