Adsorption Kinetics of Alcohols over MCM-41 Materials
Adsorption of methanol and ethanol over mesoporous
siliceous material are studied in the current paper. The pure
mesoporous silica is prepared using tetraethylorthosilicate (TEOS) as
silica source and dodecylamine as template at low pH. The prepared
material was characterized using nitrogen adsorption,nX-ray
diffraction (XRD) and scanning electron microscopy (SEM). The
adsorption kinetics of methanol and ethanol from aqueous solution
were studied over the prepared mesoporous silica material. The
percent removal of alcohol was calculated per unit mass of adsorbent
used. The 1st order model is found to be in agreement with both
adsorbates while the 2nd order model fit the adsorption of methanol
only.
[1] F. A. Twaiq, A.R. Mohamed and S. Bhatia, "Liquid Hydrocarbon Fuels
from Palm oil by Catalytic Cracking over Aluminosilicate Mesoporous
Catalysts with Various Si/Al Ratios". Mesoporous Materials. 64, 2003.
pp. 95-107
[2] J.Y. Ying, and C.P. Mehnert "Synthesis and Applications of
Supramolecular-Templated Mesoporous Materials", Angew. Chem. Int.
Ed, 38, 1999, pp. 57 - 74.
[3] S. Biz and M. L. Ocelli, "Synthesis and Characterization of
Mesostructures Materials", Catal. Rev. Sci. Eng., 40(3), 1998, pp. 329 -
407.
[4] B.G. Trewyn, I.I. Slowing, S. Giri, H.-T. Chen, V. S-Y Lin. "Synthesis
and Functionalization of a Mesoporous Silica Nanoparticle Based on the
Sol-Gel Process and Applications in Controlled Release". Accounts of
Chemical Research. 40 (9), 2007, pp. 846-853
[5] M. Yates, J. Blanco, M. A. Martin-Luengo and M. P. "Vapour adsorption
capacity of controlled porosity honeycomb monoliths". Microporous
Materials. 65 (2-3) 2003, pp. 219-231.
[6] M. Vallet-Regí, F Balas, D.Arcos "Mesoporous materials for drug
delivery" Angew. Chem. Int. Ed. 46, 2007, pp. 7548-7558.
[7] B. H. Hameed, "Equilibrium and kinetic studies of methyl violet sorption
by agricultural by-product" Journal of Hazardous Materials. 154, (1-3),
2008, pp. 204-212.
[8] H. A. Jamali, A. H. Mahvi and S. Nazmara. "Removal of Cadmium from
Aqueous Solutions by Hazel Nut Shell". World Applied Science Journal.
5, 2009, pp. 16-20.
[9] K. Kasim, N. Abu-bakur, S.N. Mustafa, A.M. and Mohamed Z.M. Daud.
"Methylene Blue Removal from Simulated Wastewater by Adsorption
Using Gandoderma Cultivation Waste Sawdust". World Applied
Sciences Journal, 2009, pp. 104-113.
[10] S.A. Mirji, S.B. Halligudi, N. Mathew, N.E. Jacob, K.R. Patil, A.B.
Gaikwad. "Adsorption of methanol on mesoporous SBA-15". Materials
Letters, 61, 2007, pp. 88-92.
[11] A. Galíková and A. Galík. "The study of the adsorption kinetics of
acetylene and methanol on silica gel by gravimetry and global fitting".
31th Intl Conf of SSCHE. Tatransk'e Matliare, Slovakia.May 24-28,
2004, pp.1.
[12] E. Demirbasa, M. Kobyab, E. Senturkb, T. Ozkana. "Adsorption kinetics
for the removal of chromium (VI) from aqueous solutions on the
activated carbons prepared from agricultural wastes". Water SA, 30 (4),
2004, pp. 533-5337.
[1] F. A. Twaiq, A.R. Mohamed and S. Bhatia, "Liquid Hydrocarbon Fuels
from Palm oil by Catalytic Cracking over Aluminosilicate Mesoporous
Catalysts with Various Si/Al Ratios". Mesoporous Materials. 64, 2003.
pp. 95-107
[2] J.Y. Ying, and C.P. Mehnert "Synthesis and Applications of
Supramolecular-Templated Mesoporous Materials", Angew. Chem. Int.
Ed, 38, 1999, pp. 57 - 74.
[3] S. Biz and M. L. Ocelli, "Synthesis and Characterization of
Mesostructures Materials", Catal. Rev. Sci. Eng., 40(3), 1998, pp. 329 -
407.
[4] B.G. Trewyn, I.I. Slowing, S. Giri, H.-T. Chen, V. S-Y Lin. "Synthesis
and Functionalization of a Mesoporous Silica Nanoparticle Based on the
Sol-Gel Process and Applications in Controlled Release". Accounts of
Chemical Research. 40 (9), 2007, pp. 846-853
[5] M. Yates, J. Blanco, M. A. Martin-Luengo and M. P. "Vapour adsorption
capacity of controlled porosity honeycomb monoliths". Microporous
Materials. 65 (2-3) 2003, pp. 219-231.
[6] M. Vallet-Regí, F Balas, D.Arcos "Mesoporous materials for drug
delivery" Angew. Chem. Int. Ed. 46, 2007, pp. 7548-7558.
[7] B. H. Hameed, "Equilibrium and kinetic studies of methyl violet sorption
by agricultural by-product" Journal of Hazardous Materials. 154, (1-3),
2008, pp. 204-212.
[8] H. A. Jamali, A. H. Mahvi and S. Nazmara. "Removal of Cadmium from
Aqueous Solutions by Hazel Nut Shell". World Applied Science Journal.
5, 2009, pp. 16-20.
[9] K. Kasim, N. Abu-bakur, S.N. Mustafa, A.M. and Mohamed Z.M. Daud.
"Methylene Blue Removal from Simulated Wastewater by Adsorption
Using Gandoderma Cultivation Waste Sawdust". World Applied
Sciences Journal, 2009, pp. 104-113.
[10] S.A. Mirji, S.B. Halligudi, N. Mathew, N.E. Jacob, K.R. Patil, A.B.
Gaikwad. "Adsorption of methanol on mesoporous SBA-15". Materials
Letters, 61, 2007, pp. 88-92.
[11] A. Galíková and A. Galík. "The study of the adsorption kinetics of
acetylene and methanol on silica gel by gravimetry and global fitting".
31th Intl Conf of SSCHE. Tatransk'e Matliare, Slovakia.May 24-28,
2004, pp.1.
[12] E. Demirbasa, M. Kobyab, E. Senturkb, T. Ozkana. "Adsorption kinetics
for the removal of chromium (VI) from aqueous solutions on the
activated carbons prepared from agricultural wastes". Water SA, 30 (4),
2004, pp. 533-5337.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:55360", author = "Farouq Twaiq and Mustafa Nasser and Siham Al-Hajri and Mansoor Al-Hasani", title = "Adsorption Kinetics of Alcohols over MCM-41 Materials", abstract = "Adsorption of methanol and ethanol over mesoporous
siliceous material are studied in the current paper. The pure
mesoporous silica is prepared using tetraethylorthosilicate (TEOS) as
silica source and dodecylamine as template at low pH. The prepared
material was characterized using nitrogen adsorption,nX-ray
diffraction (XRD) and scanning electron microscopy (SEM). The
adsorption kinetics of methanol and ethanol from aqueous solution
were studied over the prepared mesoporous silica material. The
percent removal of alcohol was calculated per unit mass of adsorbent
used. The 1st order model is found to be in agreement with both
adsorbates while the 2nd order model fit the adsorption of methanol
only.", keywords = "Adsorption, Kinetics, Mesoprous silica, Methanol", volume = "6", number = "8", pages = "735-5", }