Abstract: An ecofriendly Citrus paradisipeel extract mediated synthesis of TiO2 nanoparticles is reported under sonication. U.V.-vis, Transmission electron microscopy, Dynamic light scattering, and X-ray analyses are performed to characterize the formation of TiO2 nanoparticles. It is almost spherical in shape, having a size of 60–140 nm and the XRD peaks at 2θ = 25.363° confirm the characteristic facets for anatase form. The synthesized nanocatalyst is highly active in the decomposition of methyl orange (64 mg/L) in sunlight (~73%) for 2.5h.
Abstract: In a complex project environment, project teams face
multi-dimensional communication problems that can ultimately lead
to project breakdown. Team Performance varies in Face-to-Face
(FTF) environment versus groups working remotely in a computermediated
communication (CMC) environment. A brief review of the
Input_Process_Output model suggested by James E. Driskell, Paul H.
Radtke and Eduardo Salas in “Virtual Teams: Effects of
Technological Mediation on Team Performance (2003)", has been
done to develop the basis of this research. This model theoretically
analyzes the effects of technological mediation on team processes,
such as, cohesiveness, status and authority relations, counternormative
behavior and communication. An empirical study
described in this paper has been undertaken to test the
“cohesiveness" of diverse project teams in a multi-national
organization. This study uses both quantitative and qualitative
techniques for data gathering and analysis. These techniques include
interviews, questionnaires for data collection and graphical data
representation for analyzing the collected data. Computer-mediated
technology may impact team performance because of difference in
cohesiveness among teams and this difference may be moderated by
factors, such as, the type of communication environment, the type of
task and the temporal context of the team. Based on the reviewed
model, sets of hypotheses are devised and tested. This research,
reports on a study that compared team cohesiveness among virtual
teams using CMC and non-CMC communication mediums. The
findings suggest that CMC can help virtual teams increase team
cohesiveness among their members, making CMC an effective
medium for increasing productivity and team performance.
Abstract: Environmental contamination is a common problem in ex-industrial and industrial sites. This article gives a brief description of general applied environmental investigation methodologies and possible remediation applications in Latvia. Most of contaminated areas are situated in former and active industrial, military areas and ports. Industrial and logistic activities very often have been with great impact for more than hundred years thus the contamination level with heavy metals, hydrocarbons, pesticides, persistent organic pollutants is high and is threatening health and environment in general. 242 territories now are numbered as contaminated and fixed in the National Register of contaminated territories in Latvia. Research and remediation of contamination in densely populated areas are of important environmental policy domain. Four different investigation case studies of contaminated areas are given describing the history of use, environmental quality assessment as well as planned environmental management actions. All four case study locations are situated in Riga - the capital of the Republic of Latvia. The aim of this paper is to analyze the situation and problems with management of contaminated areas in Latvia, give description of field research methods and recommendations for remediation industry based on scientific data and innovations.
Abstract: Theobjective of this study was to evaluate the optimal
treatment condition of Fenton oxidation process to removal
contaminant in soil slurry contaminated by petroleum hydrocarbons.
This research studied somefactors that affect the removal efficiency
of petroleum hydrocarbons in soil slurry including molar ratio of
hydrogen peroxide (H2O2) to ferrous ion(Fe2+), pH condition and
reaction time.The resultsdemonstrated that the optimum condition
was that the molar ratio of H2O2:Fe3+ was 200:1,the pHwas 4.0and
the rate of reaction was increasing rapidly from starting point to 7th
hour and destruction kinetic rate (k) was 0.24 h-1. Approximately
96% of petroleum hydrocarbon was observed(initialtotal petroleum
hydrocarbon (TPH) concentration = 70±7gkg-1)
Abstract: Pentachlorophenol (PCP) is a polychlorinated
aromatic compound that is widespread in industrial effluents and is
considered to be a serious pollutant. Among the variety of industrial
effluents encountered, effluents from tanning industry are very
important and have a serious pollution potential. PCP is also formed
unintentionally in effluents of paper and pulp industries. It is highly
persistent in soils and is lethal to a wide variety of beneficial
microorganisms and insects, human beings and animals. The natural
processes that breakdown toxic chemicals in the environment have
become the focus of much attention to develop safe and environmentfriendly
deactivation technologies. Microbes and plants are among
the most important biological agents that remove and degrade waste
materials to enable their recycling in the environment. The present
investigation was carried out with the aim of developing a microbial
system for bioremediation of PCP polluted soils. A number of plant
species were evaluated for their ability to tolerate different
concentrations of pentachlorophenol (PCP) in the soil. The
experiment was conducted for 30 days under pot culture conditions.
The toxic effect of PCP on plants was studied by monitoring seed
germination, plant growth and biomass. As the concentration of PCP
was increased to 50 ppm, the inhibition of seed germination, plant
growth and biomass was also increased. Although PCP had a
negative effect on all plant species tested, maize and groundnut
showed the maximum tolerance to PCP. Other tolerating crops
included wheat, safflower, sunflower, and soybean. From the
rhizosphere soil of the tolerant seedlings, as many as twenty seven
PCP tolerant bacteria were isolated. From soybean, 8; sunflower, 3;
safflower 8; maize 2; groundnut and wheat, 3 each isolates were
made. They were screened for their PCP degradation potentials.
HPLC analyses of PCP degradation revealed that the isolate MAZ-2
degraded PCP completely. The isolate MAZ-1 was the next best
isolate with 90 per cent PCP degradation. These strains hold promise
to be used in the bioremediation of PCP polluted soils.
Abstract: Contamination of heavy metals in tin tailings has
caused an interest in the scientific approach of their remediation. One
of the approaches is through phytoremediation, which is using tree
species to extract the heavy metals from the contaminated soils. Tin
tailings comprise of slime and sand tailings. This paper reports only
on the finding of the four timber species namely Acacia mangium,
Hopea odorata, Intsia palembanica and Swietenia macrophylla on
the removal of cadmium (Cd) and lead (Pb) from the slime tailings.
The methods employed for sampling and soil analysis are established
methods. Six trees of each species were randomly selected from a
0.25 ha plot for extraction and determination of their heavy metals.
The soil samples were systematically collected according to 5 x 5 m
grid from each plot. Results showed that the concentration of heavy
metals in soils and trees varied according to species. Higher
concentration of heavy metals was found in the stem than the
primary roots of all the species. A. Mangium accumulated the highest
total amount of Pb per hectare basis.
Abstract: As a result of urbanization, the unpredictable growth of industry and transport, production of chemicals, military activities, etc. the concentration of anthropogenic toxicants spread in nature exceeds all the permissible standards. Most dangerous among these contaminants are organic compounds having great persistence, bioaccumulation, and toxicity along with our awareness of their prominent occurrence in the environment and food chain. Among natural ecological tools, plants still occupying above 40% of the world land, until recently, were considered as organisms having only a limited ecological potential, accumulating in plant biomass and partially volatilizing contaminants of different structure. However, analysis of experimental data of the last two decades revealed the essential role of plants in environment remediation due to ability to carry out intracellular degradation processes leading to partial or complete decomposition of carbon skeleton of different structure contaminants. Though, phytoremediation technologies still are in research and development, their various applications have been successfully used. The paper aims to analyze mechanisms of organic contaminants uptake and detoxification in plants, being the less studied issue in evaluation and exploration of plants potential for environment remediation.
Abstract: Influence of octane and benzene on plant cell
ultrastructure and enzymes of basic metabolism, such as nitrogen
assimilation and energy generation have been studied. Different
plants: perennial ryegrass (Lolium perenne) and alfalfa (Medicago
sativa); crops- maize (Zea mays L.) and bean (Phaseolus vulgaris);
shrubs – privet (Ligustrum sempervirens) and trifoliate orange
(Poncirus trifoliate); trees - poplar (Populus deltoides) and white
mulberry (Morus alba L.) were exposed to hydrocarbons of different
concentrations (1, 10 and 100 mM). Destructive changes in bean and
maize leaves cells ultrastructure under the influence of benzene
vapour were revealed at the level of photosynthetic and energy
generation subcellular organells. Different deviations at the level of
subcellular organelles structure and distribution were observed in
alfalfa and ryegrass root cells under the influence of benzene and
octane, absorbed through roots. The level of destructive changes is
concentration dependent. Benzene at low 1 and 10 mM concentration
caused the increase in glutamate dehydrogenase (GDH) activity in
maize roots and leaves and in poplar and mulberry shoots, though to
higher extent in case of lower, 1mM concentration. The induction
was more intensive in plant roots. The highest tested 100mM
concentration of benzene was inhibitory to the enzyme in all plants.
Octane caused induction of GDH in all grassy plants at all tested
concentrations; however the rate of induction decreased parallel to
increase of the hydrocarbon concentration. Octane at concentration 1
mM caused induction of GDH in privet, trifoliate and white mulberry
shoots. The highest, 100mM octane was characterized by inhibitory
effect to GDH activity in all plants. Octane had inductive effect on
malate dehydrogenase in almost all plants and tested concentrations,
indicating the intensification of Trycarboxylic Acid Cycle.
The data could be suggested for elaboration of criteria for plant
selection for phytoremediation of oil hydrocarbons contaminated
soils.
Abstract: Over the past decade, mobile has experienced a
revolution that will ultimately change the way we communicate.All
these technologies have a common denominator exploitation of
computer information systems, but their operation can be tedious
because of problems with heterogeneous data sources.To overcome
the problems of heterogeneous data sources, we propose to use a
technique of adding an extra layer interfacing applications of
management or supervision at the different data sources.This layer
will be materialized by the implementation of a mediator between
different host applications and information systems frequently used
hierarchical and relational manner such that the heterogeneity is
completely transparent to the VoIP platform.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.
Abstract: The remediation of water resources pollution in
developing countries requires the application of alternative
sustainable cheaper and efficient end-of-pipe wastewater treatment
technologies. The feasibility of use of South African cheap and
abundant pine tree (Pinus patula) sawdust for development of lowcost
AC of comparable quality to expensive commercial ACs in the
abatement of water pollution was investigated. AC was developed at
optimized two-stage N2-superheated steam activation conditions in a
fixed bed reactor, and characterized for proximate and ultimate
properties, N2-BET surface area, pore size distribution, SEM, pHPZC
and FTIR. The sawdust pyrolysis activation energy was evaluated by
TGA. Results indicated that the chars prepared at 800oC and 2hrs
were suitable for development of better quality AC at 800oC and 47%
burn-off having BET surface area (1086m2/g), micropore volume
(0.26cm3/g), and mesopore volume (0.43cm3/g) comparable to
expensive commercial ACs, and suitable for water contaminants
removal. The developed AC showed basic surface functionality at
pHPZC at 10.3, and a phenol adsorption capacity that was higher than
that of commercial Norit (RO 0.8) AC. Thus, it is feasible to develop
better quality low-cost AC from (Pinus patula) sawdust using twostage
N2-steam activation in fixed-bed reactor.
Abstract: Palladium-catalyzed hydrodechlorination is a
promising alternative for the treatment of environmentally relevant
water bodies, such as groundwater, contaminated with chlorinated
organic compounds (COCs). In the aqueous phase
hydrodechlorination of COCs, Pd-based catalysts were found to have
a very high catalytic activity. However, the full utilization of the
catalyst-s potential is impeded by the sensitivity of the catalyst to
poisoning and deactivation induced by reduced sulfur compounds
(e.g. sulfides). Several regenerants have been tested before to recover
the performance of sulfide-fouled Pd catalyst. But these only
delivered partial success with respect to re-establishment of the
catalyst activity. In this study, the deactivation behaviour of
Pd/Al2O3 in the presence of sulfide was investigated. Subsequent to
total deactivation the catalyst was regenerated in the aqueous phase
using potassium permanganate. Under neutral pH condition,
oxidative regeneration with permanganate delivered a slow recovery
of catalyst activity. However, changing the pH of the bulk solution to
acidic resulted in the complete recovery of catalyst activity within a
regeneration time of about half an hour. These findings suggest the
superiority of permanganate as regenerant in re-activating Pd/Al2O3
by oxidizing Pd-bound sulfide.
Abstract: Coal will continue to be the predominant source of
global energy for coming several decades. The huge generation of fly
ash (FA) from combustion of coal in thermal power plants (TPPs) is
apprehended to pose the concerns of its disposal and utilization. FA
application based on its typical characteristics as soil ameliorant for
agriculture and forestry is the potential area, and hence the global
attempt. The inferences drawn suffer from the variations of ash
characteristics, soil types, and agro-climatic conditions; thereby
correlating the effects of ash between various plant species and soil
types is difficult. Indian FAs have low bulk density, high water
holding capacity and porosity, rich silt-sized particles, alkaline
nature, negligible solubility, and reasonable plant nutrients. Findings
of the demonstrations trials for more than two decades from lab/pot
to field scale long-term experiments are developed as FA soil
amendment technology (FASAT) by Central Institute of Mining and
Fuel Research (CIMFR), Dhanbad. Performance of different crops
and plant species in cultivable and problematic soils, are
encouraging, eco-friendly, and being adopted by the farmers. FA
application includes ash alone and in combination with
inorganic/organic amendments; combination treatments including
bio-solids perform better than FA alone. Optimum dose being up to
100 t/ha for cultivable land and up to/ or above 200 t/ha of FA for
waste/degraded land/mine refuse, depending on the characteristics of
ash and soil. The elemental toxicity in Indian FA is usually not of
much concern owing to alkaline ashes, oxide forms of elements, and
elemental concentration within the threshold limits for soil
application. Combating toxicity, if any, is possible through
combination treatments with organic materials and phytoremediation.
Government initiatives through extension programme
involving farmers and ash generating organizations need to be
accelerated
Abstract: In films, visual effects have played the role of
expressing realities more realistically or describing imaginations as if
they are real. Such images are immediated images representing
realism, and the logic of immediation for the reality of images has
been perceived dominant in visual effects. In order for immediation to
have an identity as immediation, there should be the opposite concept
hypermediation.
In the mid 2000s, hypermediated images were settled as a code of
mass culture in Asia. Thus, among Asian films highly popular in those
days, this study selected five displaying hypermediated images – 2 Korean, 2 Japanese, and 1 Thailand movies – and examined the
semiotic meanings of such images using Roland Barthes- directional and implicated meaning analysis and Metz-s paradigmatic analysis
method, focusing on how hypermediated images work in the general
context of the films, how they are associated with spaces, and what
meanings they try to carry.
Abstract: An attempt was made for availability of wastewater reuse/reclamation for irrigation purposes using phytoremediation “the low cost and less technology", using six local aquatic macrophytes “e.g. T. angustifolia, B. maritimus, Ph. australis, A. donax, A. plantago-aquatica and M. longifolia (Linn)" as biological waste purifiers. Outdoor experiments/designs were conducted from May 03, 2007 till October 15, 2008, close to one of the main sewage channels of Sulaimani City/Iraq*. All processes were mainly based on conventional wastewater treatment processes, besides two further modifications were tested, the first was sand filtration pots, implanted by individual species of experimental macrophytes and the second was constructed wetlands implanted by experimental macrophytes all together. Untreated and treated wastewater samples were analyzed for their key physico-chemical properties (only heavy metals Fe, Mn, Zn and Cu with particular reference to removal efficiency by experimental macrophytes are highlighted in this paper). On the other hand, vertical contents of heavy metals were also evaluated from both pots and the cells of constructed wetland. After 135 days, macrophytes were harvested and heavy metals were analyzed in their biomass (roots/shoots) for removal efficiency assessment (i.e. uptake/ bioaccumulation rate). Results showed that; removal efficiency of all studied heavy metals was much higher in T. angustifolia followed by Ph. Australis, B. maritimus and A. donax in triple experiment sand pots. Constructed wetland experiments have revealed that; the more replicated constructed wetland cells the highest heavy metal removal efficiency was indicated.
Abstract: A research project dealing with the phytoremediation
of a soil polluted by some heavy metals is currently running. The
case study is represented by a mining area in Hamedan province in
the central west part of Iran. The potential of phytoextraction and
phytostabilization of plants was evaluated considering the
concentration of heavy metals in the plant tissues and also the
bioconcentration factor (BCF) and the translocation factor (TF). Also
the several established criteria were applied to define
hyperaccumulator plants in the studied area. Results showed that
none of the collected plant species were suitable for phytoextraction
of Cu, Zn, Fe and Mn, but among the plants, Euphorbia macroclada
was the most efficient in phytostabilization of Cu and Fe, while,
Ziziphora clinopodioides, Cousinia sp. and Chenopodium botrys
were the most suitable for phytostabilization of Zn and Chondrila
juncea and Stipa barbata had the potential for phytostabilization of
Mn. Using the most common criterion, Euphorbia macroclada and
Verbascum speciosum were Fe hyperaccumulator plants. Present
study showed that native plant species growing on contaminated sites
may have the potential for phytoremediation.
Abstract: Water hyacinth has been used in aquatic systems for
wastewater purification in many years worldwide. The role of water
hyacinth (Eichhornia crassipes) species in polishing nitrate and
phosphorus concentration from municipal wastewater treatment plant
effluent by phytoremediation method was evaluated. The objective
of this project is to determine the removal efficiency of water
hyacinth in polishing nitrate and phosphorus, as well as chemical
oxygen demand (COD) and ammonia. Water hyacinth is considered
as the most efficient aquatic plant used in removing vast range of
pollutants such as organic matters, nutrients and heavy metals. Water
hyacinth, also referred as macrophytes, were cultivated in the
treatment house in a reactor tank of approximately 90(L) x 40(W) x
25(H) in dimension and built with three compartments. Three water
hyacinths were placed in each compartments and water sample in
each compartment were collected in every two days. The plant
observation was conducted by weight measurement, plant uptake and
new young shoot development. Water hyacinth effectively removed
approximately 49% of COD, 81% of ammonia, 67% of phosphorus
and 92% of nitrate. It also showed significant growth rate at starting
from day 6 with 0.33 shoot/day and they kept developing up to 0.38
shoot/day at the end of day 24. From the studies conducted, it was
proved that water hyacinth is capable of polishing the effluent of
municipal wastewater which contains undesirable amount of nitrate
and phosphorus concentration.
Abstract: Contamination of heavy metals represents one of the
most pressing threats to water and soil resources as well as human
health. Phytoremediation can be potentially used to remediate metalcontaminated
sites. A major step towards the development of
phytoremediation of heavy metal impacted soils is the discovery of
the heavy metal hyperaccumulation in plants. In this study, the
several established criteria to define a hyperaccumulator plant were
applied. The case study was represented by a mining area in
Hamedan province in the central west part of Iran. Obtained results
showed that the most of sampled species were able to grow on
heavily metal-contaminated soils and also were able to accumulate
extraordinarily high concentrations of some metals such as Zn, Mn,
Cu, Pb and Fe. Using the most common criteria, Euphorbia
macroclada and Centaurea virgata can be classified as
hyperaccumulators of some measured heavy metals and, therefore,
they have suitable potential for phytoremediation of contaminated
soils.
Abstract: Mercury adsorption on soil was investigated at
different ionic strengths using Ca(NO3)2 as a background electrolyte.
Results fitted the Langmuir equation and the adsorption isotherms
reached a plateau at higher equilibrium concentrations. Increasing
ionic strength decreased the sorption of mercury, due to the
competition of Ca ions for the sorption sites in the soils. The
influence of ionic strength was related to the mechanisms of heavy
metal sorption by the soil. These results can be of practical
importance both in the agriculture and contaminated soils since the
solubility of mercury in soils are strictly dependent on the adsorption
and release process.
Abstract: Although oil-based drilling fluids are of paramount practical and economical interest, they represent a serious source of pollution, once released into the environment as drill cuttings. The aim of this study is to assess the capability of isolated microorganisms to degrade gasoil fuel. The commonly used physicochemical and biodegradation remediation techniques of petroleum contaminated soil were both investigated. The study revealed that natural biodegradation is favorable. Even though, the presence of heavy metals, the moisture level of (8.55%) and nutrient deficiencies put severe constrains on microorganisms- survival ranges inhibiting the biodegradation process. The selected strains were able to degrade the diesel fuel at significantly high rates (around 98%).