Abstract: Studies have shown that the SnAgCu solder family has been widely used as a replacement for conventional Sn-Pb solders. An attractive approach is by introducing alloying additives (rare earth elements (RE), Zn, Co, Fe, Ni, Sb) into the SnAgCu solder, which helps in refining the microstructure also improving the mechanical and wetting properties of the solder. The present work focuses on the effect of additions of 0.5% Ce and Fe into Sn-3.0Ag-0.5Cu solder, in attempt to reduce the intermetallic compound (IMC) growth and reflow properties of the solder on Cu and Ni (P) surface finish, as well as effects thermal aging on the formation of intermetallic compound (IMC) on different surface finish. Excessive intermetallic compound growth may effect the interface and solder joint due to the brittle nature of the intermetallic compounds. Thus, by introducing alloying elements, IMC layer thickness can be decrease, resulting in better joint and solder reliability.
Abstract: Porcelain specimens were fired at 6C/min to 1250C (dwell time 0.5-3h) and cooled at 6C/min to room temperature. Additionally, three different slower firing/cooling cycles were tried. Sintering profile and effects on MOR, crystalline phase content and morphology were investigated using dilatometry, 4-point bending strength, XRD and FEG-SEM respectively. Industrial-sized specimens prepared using the promising cycle were tested basing on the ANSI standards. Increasing dwell time from 1h to 3h at peak temperature of 1250C resulted in neither a significant effect on the quartz and mullite content nor MOR. Reducing the firing/cooling rate to below 6C/min, for peak temperature of 1250C (dwell time of 1h) does not result in improvement of strength of porcelain. The industrial sized specimen exhibited flashover voltages of 20.3kV (dry) and 9.3kV (wet) respectively, transverse strength of 12.5kN and bulk density of 2.27g/cm3, which are satisfactory. There was however dye penetration during porosity test. KeywordsDwell time, Microstructure, Porcelain, Strength.
Abstract: Low oxygen content vanadium powder was
prepared by hydrogenation dehydrogenization (HDH). The
effect of purification treatment on hydrogen absorption kinetics
of dendritic vanadium was tested, and the effects of milling
technique on powder yield and grain size were studied. The
crystal phase, oxygen and nitrgen content, and grain size of
prepared powder were characterized and analyzed by X-ray
diffraction (XRD), oxygen and nitrogen analyzer and grain size
analyzer. The results show that the alkaline cleaning can
improve the hydrogen absorption of vanadium. The yield of
vanadium hydride powder can reach as high as 90% by 4h
ball-milling, The resultant product also have an oxygen content
less than 600μg/g, and the grain size is smaller than 37μm.
Meanwhile, the XRD results show that the phase of hydride
vanadium powder is mainly VH0.81. After a hydrogen
desorption treatment in vacuum at 700Ôäâ, the phase of the
powder converts into V and a little of V2H.
Abstract: Metal cutting is a severe plastic deformation process
involving large strains, high strain rates, and high temperatures.
Conventional analysis of the chip formation process is based on bulk
material deformation disregarding the inhomogeneous nature of the
material microstructure. A series of orthogonal cutting tests of AISI
1045 and 1144 steel were conducted which yielded similar process
characteristics and chip formations. With similar shear angles and cut
chip thicknesses, shear strains for both chips were found to range
from 2.0 up to 2.8. The manganese-sulfide (MnS) precipitate in the
1144 steel has a very distinct and uniform shape which allows for
comparison before and after chip formation. From close observations
of MnS precipitates in the cut chips it is shown that the conventional
approach underestimates plastic strains in metal cutting.
Experimental findings revealed local shear strains around a value of
6. These findings and their implications are presented and discussed.
Abstract: Limited infrastructure development on peats and
organic soils is a serious geotechnical issues common to many
countries of the world especially Malaysia which distributed 1.5 mill
ha of those problematic soil. These soils have high water content and
organic content which exhibit different mechanical properties and
may also change chemically and biologically with time. Constructing
structures on peaty ground involves the risk of ground failure and
extreme settlement. Nowdays, much efforts need to be done in
making peatlands usable for construction due to increased landuse.
Deep mixing method employing cement as binders, is generally used
as measure again peaty/ organic ground failure problem. Where the
technique is widely adopted because it can improved ground
considerably in a short period of time. An understanding of
geotechnical properties as shear strength, stiffness and compressibility
behavior of these soils was requires before continues construction on
it. Therefore, 1- 1.5 meter peat soil sample from states of Johor and
an organic soil from Melaka, Malaysia were investigated. Cement
were added to the soil in the pre-mixing stage with water cement ratio
at range 3.5,7,14,140 for peats and 5,10,30 for organic soils,
essentially to modify the original soil textures and properties. The
mixtures which in slurry form will pour to polyvinyl chloride (pvc)
tube and cured at room temperature 250C for 7,14 and 28 days.
Laboratory experiments were conducted including unconfined
compressive strength and bender element , to monitor the improved
strength and stiffness of the 'stabilised mixed soils'. In between,
scanning electron miscroscopic (SEM) were observations to
investigate changes in microstructures of stabilised soils and to
evaluated hardening effect of a peat and organic soils stabilised
cement. This preliminary effort indicated that pre-mixing peat and
organic soils contributes in gaining soil strength while help the
engineers to establish a new method for those problematic ground
improvement in further practical and long term applications.
Abstract: Low carbon deep drawing steel DC 01 according to EN 10130-91 was nitrooxidized in dissociated ammonia at 580°C/45 min and consequently oxidised at 380°C/5 min in vapour of distilled water. Material after nitrooxidation had 54 % increase of yield point, 34 % increase of strength and 10-times increased resistance to atmospheric corrosion in comparison to the material before nitrooxidation. The microstructure of treated material consisted of thin ε-phase layer connected to layer containing precipitated massive needle shaped Fe4N - γ' nitrides. This layer passed to a diffusion layer consisting of fine irregular shaped Fe16N2 - α'' nitrides regularly dispersed in ferritic matrix. Fatigue properties were examined under bending load with frequency of 20 kHz and sinusoidal symmetric cycle. The results confirmed positive influence of nitrooxidation on fatigue properties as fatigue limit of treated material was double in comparison to untreated material.
Abstract: Equal Channel Angular Pressing (ECAP) is currently
being widely investigated because of its potential to produce ultrafine
grained microstructures in metals and alloys. A sound
knowledge of the plastic deformation and strain distribution is
necessary for understanding the relationships between strain
inhomogeneity and die geometry. Considerable research has been
reported on finite element analysis of this process, assuming threedimensional
plane strain condition. However, the two-dimensional
models are not suitable due to the geometry of the dies, especially in
cylindrical ones. In the present work, three-dimensional simulation of
ECAP process was carried out for six outer corner radii (sharp to 10
mm in steps of 2 mm), with channel angle 105¶Çü▒, for strain hardening
aluminium alloy (AA 6101) using ABAQUS/Standard software.
Strain inhomogeneity is presented and discussed for all cases. Pattern
of strain variation along selected radial lines in the body of the workpiece
is presented. It is found from the results that the outer corner
has a significant influence on the strain distribution in the body of
work-piece. Based on inhomogeneity and average strain criteria,
there is an optimum outer corner radius.
Abstract: This study reports the preparation of soft magnetic
ribbons of Fe-based amorphous alloys using the single-roller melt-spinning technique. Ribbon width varied from 142 mm to 213
mm and, with a thickness of approximately 22 μm ± 2 μm. The microstructure and magnetic properties of the ribbons were
characterized by differential scanning calorimeter (DSC), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and electrical resistivity measurements (ERM). The amorphous material
properties dependence of the cooling rate and nozzle pressure have uneven surface in ribbon thicknesses are investigated. Magnetic
measurement results indicate that some region of the ribbon exhibits good magnetic properties, higher saturation induction and lower coercivity. However, due to the uneven surface of 213 mm wide
ribbon, the magnetic responses are not uniformly distributed. To
understand the transformer magnetic performances, this study analyzes the measurements of a three-phase 2 MVA amorphous-cored transformer. Experimental results confirm that the transformer with a
ribbon width of 142 mm has better magnetic properties in terms of lower core loss, exciting power, and audible noise.
Abstract: Reinforced Concrete (RC) structures strengthened
with fiber reinforced polymer (FRP) lack in thermal resistance under
elevated temperatures in the event of fire. This phenomenon led to
the lining of strengthened concrete with thin high performance
cementitious composites (THPCC) to protect the substrate against
elevated temperature. Elevated temperature effects on THPCC, based
on different cementitious materials have been studied in the past but
high-alumina cement (HAC)-based THPCC have not been well
characterized. This research study will focus on the THPCC based on
HAC replaced by 60%, 70%, 80% and 85% of ground granulated
blast furnace slag (GGBS). Samples were evaluated by the
measurement of their mechanical strength (28 & 56 days of curing)
after exposed to 400°C, 600°C and 28°C of room temperature for
comparison and corroborated by their microstructure study. Results
showed that among all mixtures, the mix containing only HAC
showed the highest compressive strength after exposed to 600°C as
compared to other mixtures. However, the tensile strength of THPCC
made of HAC and 60% GGBS content was comparable to the
THPCC with HAC only after exposed to 600°C. Field emission
scanning electron microscopy (FESEM) images of THPCC
accompanying Energy Dispersive X-ray (EDX) microanalysis
revealed that the microstructure deteriorated considerably after
exposure to elevated temperatures which led to the decrease in
mechanical strength.
Abstract: Reinforced concrete has good durability and excellent structural performance. But there are cases of early deterioration due to a number of factors, one prominent factor being corrosion of steel reinforcement. The process of corrosion sets in due to ingress of moisture, oxygen and other ingredients into the body of concrete, which is unsound, permeable and absorbent. Cracks due to structural and other causes such as creep, shrinkage, etc also allow ingress of moisture and other harmful ingredients and thus accelerate the rate of corrosion. There are several interactive factors both external and internal, which lead to corrosion of reinforcement and ultimately failure of structures. Suitable addition of mineral admixture like silica fume (SF) in concrete improves the strength and durability of concrete due to considerable improvement in the microstructure of concrete composites, especially at the transition zone. Secondary reinforcement in the form of fibre is added to concrete, which provides three dimensional random reinforcement in the entire mass of concrete. Reinforced concrete beams of size 0.1 m X 0.15 m and length 1m have been cast using M 35 grade of concrete. The beams after curing process were subjected to corrosion process by impressing an external Direct Current (Galvanostatic Method) for a period of 15 days under stressed and unstressed conditions. The corroded beams were tested by applying two point loads to determine the ultimate load carrying capacity and cracking pattern and the results of specimens were compared with that of the companion specimens. Gravimetric method is used to quantify corrosion that has occurred.
Abstract: Microstructure, wetting behavior and interfacial
reactions between Sn–0.7Cu and Sn–0.3Ag–0.7Cu (SAC0307)
solders solidified on Ni coated Al substrates were compared and
investigated. Microstructure of Sn–0.7Cu alloy exhibited a eutectic
matrix composed of primary β-Sn dendrites with a fine dispersion of
Cu6Sn5 intermetallics whereas microstructure of SAC0307 alloy
exhibited coarser Cu6Sn5 and finer Ag3Sn precipitates of IMCs with
decreased tin dendrites. Contact angles ranging from 22° to 26° were
obtained for Sn–0.7Cu solder solidified on substrate surface whereas
for SAC0307 solder alloy contact angles were found to be in the
range of 20° to 22°. Sn–0.7Cu solder/substrate interfacial region
exhibited faceted (Cu, Ni)6Sn5 IMCs protruding into the solder matrix
and a small amount of (Cu, Ni)3Sn4 intermetallics at the interface.
SAC0307 solder/substrate interfacial region showed mainly (Cu,
Ni)3Sn4 intermetallics adjacent to the coating layer and (Cu,
Ni)6Sn5 IMCs in the solder matrix. The improvement in the
wettability of SAC0307 solder alloy on substrate surface is attributed
to the formation of cylindrical shape (Cu,Ni)6Sn5 and a layer of
(Cu, Ni)3Sn4 IMCs at the interface.
Abstract: This study aims to investigate mechanical behavior of
deep-drawn cups consisting of aluminum (A1050)/ duralumin
(A2017) multi-layered clad structures with micro- and macro-scale
functional gradients. Such multi-layered clad structures are possibly
used for a new type of crash-boxes in automobiles to effectively
absorb the impact forces generated when automobiles having
collisions. The effect of heat treatments on microstructure,
compositional gradient, micro hardness in 2 and 6-layered aluminum/
duralumin clad structures, which were fabricated by hot rolling, have
been investigated. Impact compressive behavior of deep-drawn cups
consisting of such aluminum/ duralumin clad structures has been also
investigated in terms of energy absorption and maximum force.
Deep-drawn cups consisting of 6-layerd clad structures with microand
macro-scale functional gradients exhibit superior properties in
impact compressive tests.
Abstract: The paper presents the results of microhardness and
microstructure of low carbon steel surface melted using carbon
dioxide laser with a wavelength of 10.6μm and a maximum output
power of 2000W. The processing parameters such as the laser power,
and the scanning rate were investigated in this study. After surface
melting two distinct regions formed corresponding to the melted zone
MZ, and the heat affected zone HAZ. The laser melted region
displayed a cellular fine structures while the HAZ displayed
martensite or bainite structure. At different processing parameters,
the original microstructure of this steel (Ferrite+Pearlite) has been
transformed to new phases of martensitic and bainitic structures. The
fine structure and the high microhardness are evidence of the high
cooling rates which follow the laser melting. The melting pool and
the transformed microstructure in the laser surface melted region of
carbon steel showed clear dependence on laser power and scanning
rate.
Abstract: Most buildings have been using anchor bolts
commonly for installing outdoor advertising structures. Anchor bolts
of common carbon steel are widely used and often installed
indiscriminately by inadequate installation standards. In the area
where strong winds frequently blow, falling accidents of outdoor
advertising structures can occur and cause a serious disaster, which is
very dangerous and to be prevented. In this regard, the development of
high-performance anchor bolts is urgently required. In the present
study, 25Cr-8Ni-1.5Si-1Mn-0.4C alloy was produced by traditional
vacuum induction melting (VIM) for the application of anchor bolt.
The alloy composition is revealed as a duplex microstructure from
thermodynamic phase analysis by FactSage® and confirmed by
metallographic experiment. Addition of Nitrogen to the alloy was
found to reduce the ferritic phase domain and significantly increase the
hardness and the tensile strength. Microstructure observation revealed
mixed structure of austenite and ferrite with fine carbide distributed
along the grain and phase boundaries.
Abstract: The study of the fouling deposition of pink guava
juice (PGJ) is relatively new research compared to milk fouling
deposit. In this work, a new experimental set-up was developed to
imitate the fouling formation in heat exchanger, namely a continuous
flow experimental set-up heat exchanger. The new experimental setup
was operated under industrial pasteurization temperature of PGJ,
which was at 93°C. While the flow rate and pasteurization period
were based on the experimental capacity, which were 0.5 and 1
liter/min for the flow rate and the pasteurization period was set for 1
hour. Characterization of the fouling deposit was determined by
using various methods. Microstructure of the deposits was carried
out using ESEM. Proximate analyses were performed to determine
the composition of moisture, fat, protein, fiber, ash and carbohydrate
content. A study on the hardness and stickiness of the fouling deposit
was done using a texture analyzer. The presence of seedstone in pink
guava juice was also analyzed using a particle analyzer. The findings
shown that seedstone from pink guava juice ranging from 168 to
200μm and carbohydrate was found to be a major composition
(47.7% of fouling deposit consists of carbohydrate). Comparison
between the hardness and stickiness of the deposits at two different
flow rates showed that fouling deposits were harder and denser at
higher flow rate. Findings from this work provide basis knowledge
for further study on fouling and cleaning of PGJ.
Abstract: In the present investigation, H13 tool steel has been
deposited on copper alloy substrate using both CO2 and diode laser.
A detailed parametric analysis has been carried out in order to find
out optimum processing zone for coating defect free H13 tool steel
on copper alloy substrate. Followed by parametric optimization, the
microstructure and microhardness of the deposited clads have been
evaluated. SEM micrographs revealed dendritic microstructure in
both clads. However, the microhardness of CO2 laser deposited clad
was much higher compared to diode laser deposited clad.
Abstract: Dual phase steels (DPS)s have a microstructure
consisting of a hard second phase called Martensite in the soft Ferrite
matrix. In recent years, there has been interest in dual-phase steels,
because the application of these materials has made significant usage;
particularly in the automotive sector Composite microstructure of
(DPS)s exhibit interesting characteristic mechanical properties such
as continuous yielding, low yield stress to tensile strength
ratios(YS/UTS), and relatively high formability; which offer
advantages compared with conventional high strength low alloy
steels(HSLAS). The research dealt with the characterization of
damage in (DPS)s. In this study by review the mechanisms of failure
due to volume fraction of martensite second phase; a new method is
introduced to identifying the mechanisms of failure in the various
phases of these types of steels. In this method the acoustic emission
(AE) technique was used to detect damage progression. These failure
mechanisms consist of Ferrite-Martensite interface decohesion and/or
martensite phase fracture. For this aim, dual phase steels with
different volume fraction of martensite second phase has provided by
various heat treatment methods on a low carbon steel (0.1% C), and
then AE monitoring is used during tensile test of these DPSs. From
AE measurements and an energy ratio curve elaborated from the
value of AE energy (it was obtained as the ratio between the strain
energy to the acoustic energy), that allows detecting important
events, corresponding to the sudden drops. These AE signals events
associated with various failure mechanisms are classified for ferrite
and (DPS)s with various amount of Vm and different martensite
morphology. It is found that AE energy increase with increasing Vm.
This increasing of AE energy is because of more contribution of
martensite fracture in the failure of samples with higher Vm. Final
results show a good relationship between the AE signals and the
mechanisms of failure.
Abstract: The present paper concerns with the influence of fiber
packing on the transverse plastic properties of metal matrix
composites. A micromechanical modeling procedure is used to
predict the effective mechanical properties of composite materials at
large tensile and compressive deformations. Microstructure is
represented by a repeating unit cell (RUC). Two fiber arrays are
considered including ideal square fiber packing and random fiber
packing defined by random sequential algorithm. The
micromechanical modeling procedure is implemented for
graphite/aluminum metal matrix composite in which the
reinforcement behaves as elastic, isotropic solids and the matrix is
modeled as an isotropic elastic-plastic solid following the von Mises
criterion with isotropic hardening and the Ramberg-Osgood
relationship between equivalent true stress and logarithmic strain.
The deformation is increased to a considerable value to evaluate both
elastic and plastic behaviors of metal matrix composites. The yields
strength and true elastic-plastic stress are determined for
graphite/aluminum composites.
Abstract: Electrochemical-oxidation of Reactive Black-5 (RB- 5) was conducted for degradation using DSA type Ti/RuO2-SnO2- Sb2O5 electrode. In the study, for electro-oxidation, electrode was indigenously fabricated in laboratory using titanium as substrate. This substrate was coated using different metal oxides RuO2, Sb2O5 and SnO2 by thermal decomposition method. Laboratory scale batch reactor was used for degradation and decolorization studies at pH 2, 7 and 11. Current density (50mA/cm2) and distance between electrodes (8mm) were kept constant for all experiments. Under identical conditions, removal of color, COD and TOC at initial pH 2 was 99.40%, 55% and 37% respectively for initial concentration of 100 mg/L RB-5. Surface morphology and composition of the fabricated electrode coatings were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) respectively. Coating microstructure was analyzed by X-ray diffraction (XRD). Results of this study further revealed that almost 90% of oxidation occurred within 5-10 minutes.
Abstract: In this paper, the wear of high speed steel hobs during
hobbing has been studied. The wear mechanisms are strongly
influenced by the choice of cutting speed. At moderate and high
cutting speeds three major wear mechanisms were identified:
abrasion, mild adhesive and severe adhesive. The microstructure and
wear behavior of two high speed steel grades (M2 and ASP30) has
been compared. In contrast, a variation in chemical composition or
microstructure of HSS tool material generally did not change the
dominant wear mechanism. However, the tool material properties
determine the resistance against the operating wear mechanism and
consequently the tool life. The metallographic analysis and wear
measurement at the tip of hob teeth included scanning electron
microscopy and stereoscope microscopy. Roughness profilometery is
used for measuring the gear surface roughness.