Abstract: This paper presents an analytical method to solve
governing consolidation parabolic partial differential equation (PDE)
for inelastic porous Medium (soil) with consideration of variation of
equation coefficient under cyclic loading. Since under cyclic loads,
soil skeleton parameters change, this would introduce variable
coefficient of parabolic PDE. Classical theory would not rationalize
consolidation phenomenon in such condition. In this research, a
method based on time space mapping to a virtual time space along
with superimposing rule is employed to solve consolidation of
inelastic soils in cyclic condition. Changes of consolidation
coefficient applied in solution by modification of loading and
unloading duration by introducing virtual time. Mapping function is
calculated based on consolidation partial differential equation results.
Based on superimposing rule a set of continuous static loads in
specified times used instead of cyclic load. A set of laboratory
consolidation tests under cyclic load along with numerical
calculations were performed in order to verify the presented method.
Numerical solution and laboratory tests results showed accuracy of
presented method.
Abstract: The seeds of cotton (Gossypium hirsutum) fall among the lesser known oil seeds. Cottonseeds are not normally consumed in their natural state due to their gossypol content, an antinutrient. The effect of processing on the sensory characteristics and chemical composition of cottonseed and its extract was studied by subjecting the cottonseed extract to heat treatment (boiling) and the cottonseed to fermentation. The cottonseed extract was boiled using the open pot and the pressure pot for 30 minutes respectively. The fermentation of the cottonseed was carried out for 6 days with samples withdrawn at intervals of 2 days. The extract and fermented samples were subjected to chemical analysis and sensory evaluated for colour, aroma, taste, mouth feel, appearance and overallacceptability. The open pot sample was more preferred. Fermentation for 6 days resulted into a significant reduction in gossypol level of the cottonseed; however, sample fermented for 2 days was most preferred.
Abstract: A simple approach is demonstrated for growing large
scale, nearly vertically aligned ZnO nanowire arrays by thermal
oxidation method. To reveal effect of temperature on growth and
physical properties of the ZnO nanowires, gold coated zinc substrates
were annealed at 300 °C and 400 °C for 4 hours duration in air. Xray
diffraction patterns of annealed samples indicated a set of well
defined diffraction peaks, indexed to the wurtzite hexagonal phase of
ZnO. The scanning electron microscopy studies show formation of
ZnO nanowires having length of several microns and average of
diameter less than 500 nm. It is found that the areal density of wires
is relatively higher, when the annealing is carried out at higher
temperature i.e. at 400°C. From the field emission studies, the values
of the turn-on and threshold field, required to draw emission current
density of 10 μA/cm2 and 100 μA/cm2 are observed to be 1.2 V/μm
and 1.7 V/μm for the samples annealed at 300 °C and 2.9 V/μm and
3.7 V/μm for that annealed at 400 °C, respectively. The field
emission current stability, investigated over duration of more than 2
hours at the preset value of 1 μA, is found to be fairly good in both
cases. The simplicity of the synthesis route coupled with the
promising field emission properties offer unprecedented advantage
for the use of ZnO field emitters for high current density
applications.
Abstract: Cylindrical concrete reservoirs are appropriate choice
for storing liquids as water, oil and etc. By using of the pre-cast
concrete reservoirs instead of the in-situ constructed reservoirs, the
speed and precision of the construction would considerably increase.
In this construction method, wall and roof panels would make in
factory with high quality materials and precise controlling. Then,
pre-cast wall and roof panels would carry out to the construction site
for assembling. This method has a few faults such as: the existing
weeks in connection of wall panels together and wall panels to
foundation. Therefore, these have to be resisted under applied loads
such as seismic load. One of the innovative methods which was
successfully applied for seismic retrofitting of numerous pre-cast
cylindrical water reservoirs in New Zealand, using of the high tensile
cables around the reservoirs and post-tensioning them. In this paper,
analytical modeling of wall and roof panels and post-tensioned
cables are carried out with finite element method and the effect of
height to diameter ratio, post-tensioning force value, liquid level in
reservoir, installing position of tendons on seismic response of
reservoirs are investigated.
Abstract: Computer based geostatistical methods can offer effective data analysis possibilities for agricultural areas by using
vectorial data and their objective informations. These methods will help to detect the spatial changes on different locations of the large
agricultural lands, which will lead to effective fertilization for optimal yield with reduced environmental pollution. In this study, topsoil (0-20 cm) and subsoil (20-40 cm) samples were taken from a
sugar beet field by 20 x 20 m grids. Plant samples were also collected
from the same plots. Some physical and chemical analyses for these
samples were made by routine methods. According to derived variation coefficients, topsoil organic matter (OM) distribution was more than subsoil OM distribution. The highest C.V. value of
17.79% was found for topsoil OM. The data were analyzed
comparatively according to kriging methods which are also used
widely in geostatistic. Several interpolation methods (Ordinary,Simple and Universal) and semivariogram models (Spherical,
Exponential and Gaussian) were tested in order to choose the suitable
methods. Average standard deviations of values estimated by simple
kriging interpolation method were less than average standard
deviations (topsoil OM ± 0.48, N ± 0.37, subsoil OM ± 0.18) of measured values. The most suitable interpolation method was simple
kriging method and exponantial semivariogram model for topsoil,
whereas the best optimal interpolation method was simple kriging
method and spherical semivariogram model for subsoil. The results
also showed that these computer based geostatistical methods should
be tested and calibrated for different experimental conditions and semivariogram models.
Abstract: The study aimed to investigate the effect of rice types on chewing behaviours (chewing time, number of chews, and portion size) and bolus properties (bolus moisture content, solid loss, and particle size distribution (PSD)) in human subjects. Five cooked rice types including brown rice (BR), white rice (WR), parboiled white rice (PR), high amylose white rice (HR) and waxy white rice (WXR) were chewed by six subjects. The chewing behaviours were recorded and the food boluses were collected during mastication. Rice typeswere found to significantly influence all chewing parameters evaluated. The WXR and BR showed the most pronounced differences compared with other rice types. The initial moisture content of un-chewed WXR was lowest (43.39%) whereas those of other rice types were ranged from 66.86 to 70.33%. The bolus obtained from chewing the WXR contained lowest moisture content (56.43%) whilst its solid loss (22.03%) was not significant different from those of all rice types. In PSD evaluation using Mastersizer S, the diameter of particles measured was ranged between 4 to 3500 μm. The particle size of food bolus from BR, HR, and WXR contained much finer particles than those of WR and PR.
Abstract: Cogeneration may be defined as a system which
contains electricity production and regain of the thermo value of
exhaust gases simultaneously. The examination is based on the data-s
of an active cogeneration plant. This study, it is aimed to determine
which component of the system should be revised first to raise the
efficiency and decrease the loss of exergy. For this purpose, second
law analysis of thermodynamics is applied to each component due to
consider the effects of environmental conditions and take the quality
of energy into consideration as well as the quantity of it. The exergy
balance equations are produced and exergy loss is calculated for each
component. 44,44 % loss of exergy in heat exchanger, 29,59 % in
combustion chamber, 18,68 % in steam boiler, 5,25 % in gas turbine
and 2,03 % in compressor is calculated.
Abstract: Losses of surfactant due to sorption need to be
considered when selecting surfactant doses for soil bioremediation.
The degree of surfactant sorption onto soil depends primarily on the
organic carbon fraction of soil and the chemical nature of the
surfactant. The use of biosurfactants in the control of the
bioavailability of toxicants in soils is an attractive option because of
their biodegradability. In this work biosurfactants were produced
from a cheap raw material, trimming vine shoots, employing
Lactobacillus pentosus. When biosurfactants from L. pentosus was
added to sediments the surface tensión of the water containing the
sediments rapidly increase, the same behaviour was observed with
the chemical surfactant Tween 20; whereas sodyum dodecyl sulphate
(SDS) kept the surface tension of the water around 36 mN/m. It
means, that the behaviour of biosurfactants from L. pentosus is more
similar to non-ionic surfactatns than to anionic surfactants.
Abstract: Gilaburu (Viburnum opulus L.) grown naturally in
Anatolia. In this study, some physico-chemical (sugar, acid, protein,
crude fat, crude fiber, ash etc.) characteristics and mineral
composition of Gilaburu fruit have been investigated. The length,
width, thickness, weight, total soluble solid, protein, crude ash, crude
fiber and crude oil of fruit were found to be 1.12 cm, 1.58 cm, 1.87
cm, 0.87 g, 14.73 %, 0.2 %, 0.11 %, 6.56 % and 0.4 %, respectively.
The seed of fruit mean weight, length, width and thickness were
determinated as 0.08 g, 7.76 cm, 7.67 cm and 1.66, respectively. In
addition 27 mineral elements (Al, Mg, Na, Ba, Ca, Ni, Cd, P, Cr, Pb,
S, Cu, Se, Fe, K, Sr, Li, Z, V, Ag, Bi, Co, Mn, B, Ga, In, Ti) were
analyzed. Gilaburu (Viburnum opulus L.) fruit was richest in
potassium (10764.764 ppm), Mg (1289.088 ppm) and P (1304.169
ppm).
Abstract: The paper investigates parallel channel instabilities of
natural circulation boiling water reactor. A thermal-hydraulic model
is developed to simulate two-phase flow behavior in the natural circulation boiling water reactor (NCBWR) with the incorporation of
ex-core components and recirculation loop such as steam separator, down-comer, lower-horizontal section and upper-horizontal section
and then, numerical analysis is carried out for parallel channel
instabilities of the reactor undergoing both in-phase and out-of-phase
modes of oscillations. To analyze the relative effect on stability of the reactor due to inclusion of various ex-core components and
recirculation loop, marginal stable point is obtained at a particular inlet enthalpy of the reactor core without the inclusion of ex-core
components and recirculation loop and then with the inclusion of the
same. Numerical simulations are also conducted to determine the
relative dominance between two modes of oscillations i.e. in-phase and out-of-phase. Simulations are also carried out when the channels
are subjected to asymmetric power distribution keeping the inlet enthalpy same.
Abstract: Hydrogen sulfide (H2S) is a very toxic gas that is produced in very large quantities in the oil and gas industry. It cannot be flared to the atmosphere and Claus process based gas plants are used to recover the sulfur and convert the hydrogen to water. In this paper, we present optical characterization of an atmospheric pressure microwave plasma torch for H2S dissociation into hydrogen and sulfur. The torch is operated at 2.45 GHz with power up to 2 kW. Three different gases can simultaneously be injected in the plasma torch. Visual imaging and optical emission spectroscopy are used to characterize the plasma for varying gas flow rates and microwave power. The plasma length, emission spectra and temperature are presented. The obtained experimental results validate our earlier published simulation results of plasma torch.
Abstract: Attempt was made to improve certain characteristics of bio-oil derived from palm kernel pyrolysis by blending it with diesel fuel and alcohols. Two types of alcohol, ethanol or butanol, was used as cosolvent to stabilize the phase of ternary systems. Phase behaviors and basic fuel properties of palm kernel bio-oildiesel- alcohol systems were investigated in this study. Alcohol types showed a significant influence on the phase characteristics with palm kernel bio-oil-diesel-butanol system giving larger soluble area than that of palm kernel bio-oil-diesel-ethanol system. For fuel properties, blended fuels showed superior properties including lower values of density (~860 kg/m3 at 25°C), viscosity (~4.12 mm2/s at 40°C), carbon residue (1.02-2.53 wt%), ash (0.018-0.034 wt%) and pour point (
Abstract: Paddy being cultivated since about 10,000 years B.C in Ganga Valley in India, its production reached up to 99 million tons in the year 2012. BGA are of much ecological importance for maintaining the soil fertility and reclaiming the alkalinity. In present investigation attempts were made to identify the local cyanobacterial genera from the paddy fields, BGA application for green farming enabling the paddy to utilize more amount of nitrogen released and to examine its impact along with Urea upon growth and yield responses of the Paddy crop. It was observed that combined treatment of BGA with Urea proved better response in almost all growth parameters and yield attributes except number of tillers/ Plant and grains/ panicle as compared to application of either Urea or BGA alone. The Paddy growers should be encouraged to adopt BGA along with Urea as source of Nitrogen for Paddy cultivation.
Abstract: This study, focusing on the importance of encouraging
outdoor activities for children, aims to propose and implement a
Web-GIS based outdoor education program for elementary schools,
which will then be evaluated by users. Specifically, for the purpose of
improved outdoor activities in the elementary school education, the
outdoor education program, with chiefly using the Web-GIS that
provides a good information provision and sharing tool, is proposed
and implemented before being evaluated by users. Conclusions of the
study boil down to:
(1) An eight-staged outdoor education program based on the Web-GIS
was proposed for a “second school" of an elementary school that
was then implemented before being evaluated by users (teachers,
instructors, students, and their parents).
(2) The program generally received a good evaluation, while a lot of
students and their parents evaluated negatively for the degree of
discovery and for the degree of interest, respectively, in the
questionnaire survey of students and their parents conducted after
the “second school". The surveys clearly show that an issue to be
solved, from the viewpoint of teachers in particular, is the
establishment of the GIS that will easily represent teaching materials
developed by teachers and of Web-GIS, and improved significance
of the use of GIS and Web-GIS for their widespread.
Abstract: Nitrogen loss from irrigated cropland, particularly
sandy soils, significantly contributes to nitrate (NO3
-) levels in
surface and groundwaters. Thus, it is of great interest to use
inexpensive natural products that can increase the fertilizer efficiency
and decrease nitrate leaching. In this study, the ability of natural
Iranian zeolite clinoptilolite (Cp) and surfactant modified zeolite
clinoptilolite (SMZ) to remove NH4
+ and NO3
-, respectively, from
aqueous solutions was determined. The feasibility of using Cp and
SMZ as soil amendment to reduce nitrate leaching from soil using
lysimeters was also investigated. Zeolite showed 10.23% to 88.42%
NH4
+ removal efficiency over a wide range of initial NH4
+
concentrations. Nitrate removal efficiency by SMZ was 32.26% to
82.26%. Field study results showed that Cp and SMZ significantly (p
< 0.05) reduced leachate NO3-N concentration compared to control.
There was no significant difference between maximum and mean
leachate NO3-N concentration of SMZ lysimeters and those of Cp
lysimeters.
Abstract: The direct sewage sludge application is a relative
cheap method for their liquidation. In the past heavy metal contents
increase in soils treated with sewage sludge was observed. In 2003
there was acceptance on act n.188/2003 about sewage sludge
application on soils. The basic philosophy of act is a safety of the
environmental proof of sludge application on soils. The samples of
soils from wastewater treatment plant (WTP) Poprad (35) and WTP
Michalovce (33 samples) were analyzed which were chosen for
sludge application on soils. According to the results only 14 areas for
Poprad and 25 areas for Michalovce are suitable for sludge
application according to act No. 188/2003. The application dose of
sludge was calculated 50 t.ha-1 or 75 t. ha-1 once in 5 years to ensure
that heavy metal contents in treated soils will be kept.
Abstract: The present research focus on the processing of mullite-based ceramics from oil refinery industrial wastes and byproducts of agricultural industry and on the investigating of silane modified surface of ceramics. Two waste products were used as initial material – waste aluminum oxide and waste rice husk. The burning - out additives used were waste rise husk. It is known that the oxide ceramics surface is hydrophilic due to the presence of – OH groups in it. The nature of ceramic surface regarding permeation of water and hydrocarbons can be changed by further treatment with silanes. The samples were studied mainly by X-ray analysis, FT-IR absorbance measurements and microscopic analysis. The X-ray analyses showed the phase composition depends on the firing temperature and on the purity of the starting alumina. Two kind of silanes were used for the transformation of surface from hydrophilic to hydrophobic – trimethoxymethylsilane (TMMS) and trimethylclorsilane (TMCS).
Abstract: Bubble generation was observed using a high-speed
camera in subcooled flow boiling at low void fraction. Constant heat
flux was applied on one side of an upward rectangular channel to
make heated test channel. Water as a working fluid from high
subcooling to near saturation temperature was injected step by step to
investigate bubble behavior during void development. Experiments
were performed in two different pressures condition close to 2bar and
4bar. It was observed that in high subcooling when boiling was
commenced, bubble after nucleation departed its origin and slid
beside heated surface. In an observation window mean release
frequency of bubble fb,mean, nucleation site Ns and mean bubble
volume Vb,mean in each step of experiments were measured to
investigate wall vaporization rate. It was found that in proximity of
PNVG vaporization rate was increased significantly in compare with
condensation rate which remained in low value.
Abstract: Heavy metals have bad effects on environment and
soils and it can uptake by natural HAP .natural Hap is an inexpensive
material that uptake large amounts of various heavy metals like Zn
(II) .Natural HAP (N-HAP), extracted from bovine cortical bone ash,
is a good choice for substitution of commercial HAP. Several
experiments were done to investigate the sorption capacity of Zn (II)
to N-HAP in various particles sizes, temperatures, initial
concentrations, pH and reaction times. In this study, the sorption of
Zinc ions from a Zn solution onto HAP particles with sizes of 1537.6
nm and 47.6 nm at three initial pH values of 4.50, 6.00 and 7.50 was
studied. The results showed that better performance was obtained
through a 47.6 nm particle size and higher pH values. The
experimental data were analyzed using Langmuir, Freundlich, and
Arrhenius equations for equilibrium, kinetic and thermodynamic
studies. The analysis showed a maximum adsorption capacity of NHAP
as being 1.562 mmol/g at a pH of 7.5 and small particle size.
Kinetically, the prepared N-HAP is a feasible sorbent that retains Zn
(II) ions through a favorable and spontaneous sorption process.
Abstract: Gaharu that produced by Aquilaria spp. is classified as
one of the most valuable forest products traded internationally as it is
very resinous, fragrant and highly valuable heartwood. Gaharu has
been widely used in aromatheraphy, medicine, perfume and religious
practices. This work aimed to determine the factors affecting solid
liquid extraction of gaharu oil using hexane as solvent under
experimental condition. The kinetics of extraction was assumed and
verified based on a second-order mechanism. The effect of three
main factors, which were temperature, reaction time and solvent to
solid ratio were investigated to achieve maximum oil yield. The
optimum condition were found at temperature 65°C, 9 hours reaction
time and solvent to solid ratio of 12:1 with 14.5% oil yield. The
kinetics experimental data agrees and well fitted with the second
order extraction model. The initial extraction rate (h) was 0.0115
gmL-1min-1; the extraction capacity (Cs) was 1.282gmL-1; the second
order extraction constant (k) was 0.007 mLg-1min-1 and coefficient of
determination, R2 was 0.945.