Abstract: Permeability reduction induced by asphaltene
precipitation during gas injection is one of the serious problems in
the oil industry. This problem can lead to formation damage and
decrease the oil production rate. In this work, Malaysian light oil
sample has been used to investigate the effect CO2 injection and
Water Alternating Gas (WAG) injection on permeability reduction.
In this work, dynamic core flooding experiments were conducted to
study the effect of CO2 and WAG injection on the amount of
asphaltene precipitated. Core properties after displacement were
inspected for any permeability reduction to study the effect of
asphaltene precipitation on rock properties.
The results showed that WAG injection gave less asphaltene
precipitation and formation damage compared to CO2 injection. The
study suggested that WAG injection can be one of the important
factors of managing asphaltene precipitation.
Abstract: Recent research on seeds of bio-diesel plants like
Jatropha curcas, constituting 40-50% bio-crude oil indicates its
potential as one of the most promising alternatives to conventional
sources of energy. Also, limited studies on utilization of de-oiled cake
have revealed that Jatropha bio-waste has good potential to be used as
organic fertilizers produced via aerobic and anaerobic treatment.
However, their commercial exploitation has not yet been possible. The
present study aims at developing appropriate bio-processes and
formulations utilizing Jatropha seed cake as organic fertilizer, for
improving the growth of Polianthes tuberose L. (Tuberose). Pot
experiments were carried out by growing tuberose plants on soil
treated with composted formulations of Jatropha de-oiled cake, Farm
Yard Manure (FYM) and inorganic fertilizers were also blended in
soil. The treatment was carried out through soil amendment as well as
foliar spray. The growth and morphological parameters were
monitored for entire crop cycle.
The growth Length and number of leaves, spike length, rachis
length, number of bulb per plant and earliness of sprouting of bulb and
yield enhancement were comparable to that achieved under inorganic
fertilizer. Furthermore, performance of inorganic fertilizer also showed
an improvement when blended with composted bio-waste. These
findings would open new avenues for Jatropha based bio-wastes to be
composted and used as organic fertilizers for commercial floriculture.
Abstract: One of the robust fault detection filter (RFDF)
designing method is based on sliding-mode theory. The main purpose
of our study is to introduce an innovative simplified reference
residual model generator to formulate the RFDF as a sliding-mode
observer without any manipulation package or transformation matrix,
through which the generated residual signals can be evaluated. So the
proposed design is more explicit and requires less design parameters
in comparison with approaches requiring changing coordinates. To
the best author's knowledge, this is the first time that the sliding
mode technique is applied to detect actuator and sensor faults in a
real boiler. The designing procedure is proposed in a drum boiler in
Synvendska Kraft AB Plant in Malmo, Sweden as a multivariable
and strongly coupled system. It is demonstrated that both sensor and
actuator faults can robustly be detected. Also sensor faults can be
diagnosed and isolated through this method.
Abstract: This paper aims to study decomposition behavior in
pyrolytic environment of four lignocellulosic biomass (oil palm shell,
oil palm frond, rice husk and paddy straw), and two commercial
components of biomass (pure cellulose and lignin), performed in a
thermogravimetry analyzer (TGA). The unit which consists of a
microbalance and a furnace flowed with 100 cc (STP) min-1 Nitrogen,
N2 as inert. Heating rate was set at 20⁰C min-1 and temperature
started from 50 to 900⁰C. Hydrogen gas production during the
pyrolysis was observed using Agilent Gas Chromatography Analyzer
7890A. Oil palm shell, oil palm frond, paddy straw and rice husk
were found to be reactive enough in a pyrolytic environment of up to
900°C since pyrolysis of these biomass starts at temperature as low as
200°C and maximum value of weight loss is achieved at about
500°C. Since there was not much different in the cellulose,
hemicelluloses and lignin fractions between oil palm shell, oil palm
frond, paddy straw and rice husk, the T-50 and R-50 values obtained
are almost similar. H2 productions started rapidly at this temperature
as well due to the decompositions of biomass inside the TGA.
Biomass with more lignin content such as oil palm shell was found to
have longer duration of H2 production compared to materials of high
cellulose and hemicelluloses contents.
Abstract: The present study attempted to improve the Mercury
(Hg) sorption capacity of kanuma volcanic ash soil (KVAS) by
impregnating the cupper (Cu). Impregnation was executed by 1 and
5% Cu powder and sorption characterization of optimum Hg
removing Cu impregnated KVAS was performed under different
operational conditions, contact time, solution pH, sorbent dosage and
Hg concentration using the batch operation studies. The 1% Cu
impregnated KVAS pronounced optimum improvement (79%) in
removing Hg from water compare to control. The present
investigation determined the equilibrium state of maximum Hg
adsorption at 6 h contact period. The adsorption revealed a pH
dependent response and pH 3.5 showed maximum sorption capacity
of Hg. Freundlich isotherm model is well fitted with the experimental
data than that of Langmuir isotherm. It can be concluded that the Cu
impregnation improves the Hg sorption capacity of KVAS and 1%
Cu impregnated KVAS could be employed as cost-effective
adsorbent media for treating Hg contaminated water.
Abstract: Organochlorine pesticides (OCPs) are known to be
persistent and bioaccumulative toxicants that may cause reproductive
impairments in wildlife as well as human. The current study uses the
snail-eating turtle Malayemys macrocephala, a long-lived animal
commonly distribute in rice field habitat in central part of Thailand,
as a sentinel to monitor OCP contamination in environment. The
nest soil, complete clutch of eggs, and blood of the turtle were
collected from agricultural areas in the Chao Phraya River Basin,
Thailand during the nesting season of 2007-2008. The novel
methods for tissue extraction by an accelerated solvent extractor
(ASE, for egg) and liquid-liquid extraction (for blood) have been
developed. The nineteen OCP residues were analyzed by gas
chromatography with micro-electron captured detector (GC-μECD).
The validated methods have met requirements of the AOAC
standard. The results indicated that significant amounts of OCPs are
still contaminated in nest soil and eggs of the turtle even though the
OCPs had been banned in this area for many years. This suggested
the potential risk to health of wildlife as well as human in the area.
Abstract: Offset Double-Disk Opener (DDO) is a popular
furrow opener in conservation tillage. It has some limitations such as
negative suction to penetrate in the soil, hair pinning and mixing seed
and fertilizer in the slot. Because of importance of separation of seed
and fertilizer in the slot, by adding two horizontal mini disks to DDO
a modified opener was made (MDO) which placed the fertilizer
between and under two rows of seed. To consider performance of
novel opener an indoor comparison test between DDO and MDO was
performed at soil bin. The experiment was conducted with three
working speeds (3, 6 and 8 km h-1), two bulk densities of soil (1.1
and 1.4 Mg m-3) and two levels of residues (1 and 2 ton ha-1). The
experimental design consisted in a (3×2×2) complete randomized
factorial with three replicates for each test. Moisture of seed furrow,
separation of seed and fertilizer, hair pinning and resultant forces
acting on the openers were used as assessing indexes. There was no
significant difference between soil moisture content in slots created
by DDO and MDO at 0-4 cm depth, but at 4-8 cm the in the slot
created by MDO moisture content was higher about 9%. Horizontal
force for both openers increased with increasing speed and soil bulk
density. Vertical force for DDO was negative so it needed additional
weight for penetrating in the soil, but vertical force for MDO was
positive and, which can solve the challenge of penetration in the soil
in DDO. In soft soil with heavy residues some trash was pushed by
DDO into seed furrow (hair pinning) but at MDO seed were placed at
clean groove. Lateral and vertical separation of seed and fertilizer
was performed effectively by MDO (4.5 and 5 cm, respectively)
while DDO put seed and fertilizer close to each other. Overall, the
Modified Offset Double-disks (MDO) had better performance. So by
adapting this opener with no-tillage drillers it would possible to have
higher yield in conservation tillage where the most appropriate
opener is disk type.
Abstract: Two-phase frictional pressure drop data were
obtained for condensation of carbon dioxide in single horizontal
micro tube of inner diameter ranged from 0.6 mm up to 1.6 mm over
mass flow rates from 2.5*10-5 to 17*10-5 kg/s and vapor qualities
from 0.0 to 1.0. The inlet condensing pressure is changed from 33.5
to 45 bars. The saturation temperature ranged from -1.5 oC up to 10
oC. These data have then been compared against three (two-phase)
frictional pressure drop prediction methods. The first method is by
Muller-Steinhagen and Heck (Muller-Steinhagen H, Heck K. A
simple friction pressure drop correlation for two-phase flow in pipes.
Chem. Eng. Process 1986;20:297–308) and that by Gronnerud R.
Investigation of liquid hold-up, flow-resistance and heat transfer in
circulation type evaporators, part IV: two-phase flow resistance in
boiling refrigerants, Annexe 1972. Then the method used by
FriedelL. Improved friction pressures drop in horizontal and vertical
two-phase pipe flow. European Two-Phase Flow Group Meeting,
Paper E2; 1979 June, Ispra, Italy. The methods are used by M.B Ould
Didi et al (2001) “Prediction of two-phase pressure gradients of
refrigerant in horizontal tubes". Int.J.of Refrigeration 25(2002) 935-
947. The best available method for annular flow was that of Muller-
Steinhagen and Heck. It was observed that the peak in the two-phase
frictional pressure gradient is at high vapor qualities.
Abstract: This experiment was conducted to investigate the
effect of different levels of dietary chromium yeast (Cr-yeast) on
thigh meat quality of broiler chicks reared under heat stress
condition. Two hundred and forty Ross male chickens in heat stress
condition (33±3°C) were allocated to five treatments in a completely
randomized design. Treatments were supplemented with 0 (control),
200, 400, 800 and 1200 μg kg-1 Cr in the form of Cr yeast. Twelve
chicks from each treatment were slaughtered at 42 d, to evaluate
moisture, protein, lipid, pH and lipid oxidation of thigh meat.
Protein, moisture, lipid and pH of thigh meat were not affected by
supplemental Cr. Thigh meat lipid tended to decrease in broilers
received 1200 μg kg-1. Storage time increased lipid oxidation of
meat (P
Abstract: The compatibility of optical resonators with microfluidic systems may be relevant for chemical and biological applications. Here, a fluorescent-core microcavity (FCM) is investigated as a refractometric sensor for heavy oils. A high-index film of silicon quantum dots (QDs) was formed inside the capillary, supporting cylindrical fluorescence whispering gallery modes (WGMs). A set of standard refractive index oils was injected into a capillary, causing a shift of the WGM resonances toward longer wavelengths. A maximum sensitivity of 240 nm/RIU (refractive index unit) was found for a nominal oil index of 1.74. As well, a sensitivity of 22 nm/RIU was obtained for a lower index of 1.48, more typical of fuel hydrocarbons. Furthermore, the observed spectra and sensitivities were compared to theoretical predictions and reproduced via FDTD simulations, showing in general an excellent agreement. This work demonstrates the potential use of FCMs for oil sensing applications and the more generally for detecting liquid solutions with a high refractive index or high viscosity.
Abstract: Principally, plants grown in soilless culture may be
attacked by the same pests and diseases as cultivated traditionally in
soil. The most destructive phytopathogens are fungi, such as
Phythium, Phytophthora and Fusarium, followed by viruses, bacteria
and nematodes. We investigated effect of carbon nanotube filters on
disease management of soilless culture. Tomato seedlings transplant
in plastic pots filled with a soilless media of vermiculite. The crop
irrigated and fertilized using a hydroponic nutrient solution. We used
carbon nanotube filters for nutrient solution disinfection. Our results
show that carbon nanotube filtration significantly reduces pathogens
on tomato plants. Fungal elimination (Fusarium oxysporum and
Pythium spp.) was usually successful at about 96 to 99.9% all over
the cultural season. It is seem that in tomato soilless culture,
nanofiltration constitutes a reliable method that allows control of the
development of diseases caused by pathogenic fungi
Abstract: Two Amphiphilic catalysts, iron (III) dodecylbenzene
sulfonate and nickel (II) dodecylbenzene sulfonate, were synthesized
and used in the catalytic aquathermolysis of heavy crude oil to reduce
its viscosity. The prepared catalysts exhibited good performance in
the aquathermolysis and the viscosity is reduced by ~ 78.9 % for
Egyptian heavy crude oil. The chemical and physical properties of
heavy oil both before and after reaction were investigated by FT-IR,
dynamic viscosity, molecular weight and SARA analysis. The results
indicated that the content of resin, asphaltene, average molecular
weight and sulfur content of heavy oil is reduced after the catalytic
aquathermolysis.
Abstract: The winding hot-spot temperature is one of the most
critical parameters that affect the useful life of the power
transformers. The winding hot-spot temperature can be calculated as
function of the top-oil temperature that can estimated by using the
ambient temperature and transformer loading measured data. This
paper proposes the estimation of the top-oil temperature by using a
method based on Least Squares Support Vector Machines approach.
The estimated top-oil temperature is compared with measured data of
a power transformer in operation. The results are also compared with
methods based on the IEEE Standard C57.91-1995/2000 and
Artificial Neural Networks. It is shown that the Least Squares
Support Vector Machines approach presents better performance than
the methods based in the IEEE Standard C57.91-1995/2000 and
artificial neural networks.
Abstract: Small-scale RC models of both piles and tunnel ducts
were produced as mockups of reality and loaded under soil
confinement conditionsto investigate the damage evolution of
structural RC interacting with soil. Experimental verifications usinga
3D nonlinear FE analysis program called COM3D, which was
developed at the University of Tokyo, are introduced. This analysis
has been used in practice for seismic performance assessment of
underground ducts and in-ground LNG storage tanks in consideration
of soil-structure interactionunder static and dynamic loading. Varying
modes of failure of RCpilessubjected to different magnitudes of soil
confinement were successfully reproduced in the proposed small-scale
experiments and numerically simulated as well. Analytical simulation
was applied to RC tunnel mockups under a wide variety of depth and
soil confinement conditions, and reasonable matching was confirmed.
Abstract: The interaction between wakes of bluff body and
airfoil have profound influences on system performance in many
industrial applications, e.g., turbo-machinery and cooling fan. The
present work investigates the effect of configuration include; airfoil-s
angle of attack, transverse and inline spacing of the models, on
frequency behavior of the cylinder-s near-wake. The experiments
carried on under subcritical flow regime, using the hot-wire
anemometry (HWA). The relationship between the Strouhal numbers
and arrangements provide an insight into the global physical
processes of wake interaction and vortex shedding.
Abstract: This paper focuses on assessment of air pollution in Umm-Alhyman, Kuwait, which is located south to oil refineries, power station, oil field, and highways. The measurements were made over a period of four days in March and July in 2001, 2004, and 2008. The measured pollutants included methanated and nonmethanated hydrocarbons (MHC, NMHC), CO, CO2, SO2, NOX, O3, and PM10. Also, meteorological parameters were measured, which includes temperature, wind speed and direction, and solar radiation. Over the study period, data analysis showed increase in measured SO2, NOX and CO by factors of 1.2, 5.5 and 2, respectively. This is explained in terms of increase in industrial activities, motor vehicle density, and power generation. Predictions of the measured data were made by the ISC-AERMOD software package and by using the ISCST3 model option. Finally, comparison was made between measured data against international standards.
Abstract: Among many different methods that are used for
optimizing different engineering problems mathematical (numerical)
optimization techniques are very important because they can easily
be used and are consistent with most of engineering problems. Many
studies and researches are done on stability analysis of three
dimensional (3D) slopes and the relating probable slip surfaces and
determination of factors of safety, but in most of them force
equilibrium equations, as in simplified 2D methods, are considered
only in two directions. In other words for decreasing mathematical
calculations and also for simplifying purposes the force equilibrium
equation in 3rd direction is omitted. This point is considered in just a
few numbers of previous studies and most of them have only given a
factor of safety and they haven-t made enough effort to find the most
probable slip surface. In this study shapes of the slip surfaces are
modeled, and safety factors are calculated considering the force
equilibrium equations in all three directions, and also the moment
equilibrium equation is satisfied in the slip direction, and using
nonlinear programming techniques the shape of the most probable
slip surface is determined. The model which is used in this study is a
3D model that is composed of three upper surfaces which can cover
all defined and probable slip surfaces. In this research the meshing
process is done in a way that all elements are prismatic with
quadrilateral cross sections, and the safety factor is defined on this
quadrilateral surface in the base of the element which is a part of the
whole slip surface. The method that is used in this study to find the
most probable slip surface is the non-linear programming method in
which the objective function that must get optimized is the factor of
safety that is a function of the soil properties and the coordinates of
the nodes on the probable slip surface. The main reason for using
non-linear programming method in this research is its quick
convergence to the desired responses. The final results show a good
compatibility with the previously used classical and 2D methods and
also show a reasonable convergence speed.
Abstract: This paper studied the synthesis of monoacylglycerol (monolaurin) by glycerolysis of coconut oil and crude glycerol, catalyzed by Carica papaya lipase. Coconut oil obtained from cold pressed extraction method and crude glycerol obtained from the biodiesel plant in Department of Chemistry, Uttaradit Rajabhat University, Thailand which used oils were used as raw materials for biodiesel production through transesterification process catalyzed by sodium hydroxide. The influences of the following variables were studied: (i) type of organic solvent, (ii) molar ratio of substrate, (iii) reaction temperature, (iv) reaction time, (v) lipase dosage, and (vi) initial water activity of enzyme. High yields in monoacylglycerol (58.35%) were obtained with molar ratio of glycerol to oil at 8:1 in ethanol, temperature was controlled at 45oC for 36 hours, the amount of enzyme used was 20 wt% of oil and initial water activity of enzyme at 0.53.
Abstract: In this research, natural canthaxanthin as one of the
most important carotenoids was extracted from Dietzia
natronolimnaea HS-1. The changes of canthaxanthin enriched in oilin-
water emulsions with vegetable oil (5 mg/ 100 mL), Arabic gum (5
mg/100 mL), and potassium sorbate (0.5 g/100 mL) was investigated.
The effects of different pH (3, 5 and 7), as well as, time treatment (3,
18 and 33 days) in the environmental temperature (24°C) on the
degradation were studied by response surface methodology (RSM).
The Hunter values (L*, a*, and b*) and the concentration of
canthaxanthin (C, mg/L) illustrated more degradation of this pigment
at low pHs (pH≤ 4) by passing the time (days≥10) with R² 97.00%,
91.31%, 97.60%, and 99.54% for C, L*, a*, and b* respectively. The
predicted model were found to be significant (p
Abstract: The measurements of 226Ra, 232Th and 40K using
gamma spectrometry and radon concentration and exhalation rates
measurements using solid state nuclear track (LR-115, Type-II
plastic) detectors are used to asses a first order exposure risk for the
persons residing in Fatehbad and Hissar districts of Western Haryana,
India. The concentration of Radium, Thorium and Potassium in the
soil samples varies from 13.37 Bq m-3 to 24.67 Bq m-3, 34.67 Bq m-3
to 67.34 Bq m-3 and 298.78 Bq m-3 to 405.67 Bq m-3 respectively
with average values of 18.78, 47.35 and 361.57 Bq m-3 respectively.
The radium equivalent activity (Raeq) calculated for the same soil
samples varies from 92.72 Bq m-3 to 140.6 Bq m-3 with an average
value of 111.80 Bq m-3. The values of absorbed dose and annual
effective dose (indoors and outdoors) are found to vary from 44.18
nGy h-1 to 65.23 nGy h-1, 0.22 mSv y-1 to 0.32 mSv y-1 and 0.05 mSv
y-1 to 0.08 mSv y-1 respectively. The radon concentration and
exhalation rates have also been reported. The radium equivalent
activities in all the soil samples were found to be lower than the limit
(370 Bq kg-1) set in the Organization for Economic Cooperation and
Development (OECD) report and the value of Hex in all the samples
is less than unity.