Abstract: Power law approximation was used in this study to evaluate the reaction orders of calcium oxide, CaO catalyzed transesterification of refined cottonseed oil and methanol. The kinetics study was carried out at temperatures of 45, 55 and 65 oC. The kinetic parameters such as reaction order 2.02 and rate constant 2.8 hr-1g-1cat, obtained at the temperature of 65 oC best fitted the kinetic model. The activation energy, Ea obtained was 127.744 KJ/mol. The results indicate that the transesterification reaction of the refined cottonseed oil using calcium oxide catalyst is approximately second order reaction.
Abstract: The knowledge of biodiesel density over large ranges
of temperature and pressure is important for predicting the behavior
of fuel injection and combustion systems in diesel engines, and for
the optimization of such systems. In this study, cottonseed oil was
transesterified into biodiesel and its density was measured at
temperatures between 288 K and 358 K and pressures between 0.1
MPa and 30 MPa, with expanded uncertainty estimated as ±1.6 kg⋅m-
3. Experimental pressure-volume-temperature (pVT) cottonseed data
was used along with literature data relative to other 18 biodiesels, in
order to build a database used to test the correlation of density with
temperarure and pressure using the Goharshadi–Morsali–Abbaspour
equation of state (GMA EoS). To our knowledge, this is the first that
density measurements are presented for cottonseed biodiesel under
such high pressures, and the GMA EoS used to model biodiesel
density. The new tested EoS allowed correlations within 0.2 kg·m-3
corresponding to average relative deviations within 0.02%. The built
database was used to develop and test a new full predictive model
derived from the observed linear relation between density and degree
of unsaturation (DU), which depended from biodiesel FAMEs
profile. The average density deviation of this method was only about
3 kg.m-3 within the temperature and pressure limits of application.
These results represent appreciable improvements in the context of
density prediction at high pressure when compared with other
equations of state.
Abstract: The aim of this study is to develop mathematical
relationships for the performance parameter brake thermal efficiency
(BTE) and emission parameter nitrogen oxides (NOx) for the various
esters of vegetable oils used as CI engine fuel. The BTE is an
important performance parameter defining the ability of engine to
utilize the energy supplied and power developed similarly it is
indication of efficiency of fuels used. The esters of cottonseed oil,
soybean oil, jatropha oil and hingan oil are prepared using
transesterification process and characterized for their physical and
main fuel properties including viscosity, density, flash point and
higher heating value using standard test methods. These esters are
tried as CI engine fuel to analyze the performance and emission
parameters in comparison to diesel. The results of the study indicate
that esters as a fuel does not differ greatly with that of diesel in
properties. The CI engine performance with esters as fuel is in line
with the diesel where as the emission parameters are reduced with the
use of esters.
The correlation developed between BTE and brake power(BP),
gross calorific value(CV), air-fuel ratio(A/F), heat carried away by
cooling water(HCW). Another equation is developed between the
NOx emission and CO, HC, smoke density (SD), exhaust gas
temperature (EGT). The equations are verified by comparing the
observed and calculated values which gives the coefficient of
correlation of 0.99 and 0.96 for the BTE and NOx equations
respectively.
Abstract: The seeds of cotton (Gossypium hirsutum) fall among the lesser known oil seeds. Cottonseeds are not normally consumed in their natural state due to their gossypol content, an antinutrient. The effect of processing on the sensory characteristics and chemical composition of cottonseed and its extract was studied by subjecting the cottonseed extract to heat treatment (boiling) and the cottonseed to fermentation. The cottonseed extract was boiled using the open pot and the pressure pot for 30 minutes respectively. The fermentation of the cottonseed was carried out for 6 days with samples withdrawn at intervals of 2 days. The extract and fermented samples were subjected to chemical analysis and sensory evaluated for colour, aroma, taste, mouth feel, appearance and overallacceptability. The open pot sample was more preferred. Fermentation for 6 days resulted into a significant reduction in gossypol level of the cottonseed; however, sample fermented for 2 days was most preferred.