Abstract: The adsorption efficiency of fired clayey pellets of 5
and 8 mm diameter size for Cu(II) and Zn(II) ion removal from a
waste printing developer was studied. In order to investigate the
influence of contact time, adsorbent mass and pellet size on the
adsorption efficiency the batch mode was carried out. Faster uptake
of copper ion was obtained with the fired clay pellets of 5 mm
diameter size within 30 minutes. The pellets of 8 mm diameter size
showed the higher equilibrium time (60 to 75 minutes) for copper and
zinc ion. The results pointed out that adsorption efficiency increases
with the increase of adsorbent mass. The maximal efficiency is
different for Cu(II) and Zn(II) ion due to the pellet size. Therefore,
the fired clay pellets of 5 mm diameter size present an effective
adsorbent for Cu(II) ion removal (adsorption efficiency is 63.6%),
whereas the fired clay pellets of 8 mm diameter size are the best
alternative for Zn(II) ion removal (adsorption efficiency is 92.8%)
from a waste printing developer.
Abstract: In this study, composites were fabricated from oil
palm empty fruit bunch fiber and poly(lactic) acid by extrusion
followed by injection moulding. Surface of the fiber was pre-treated
by ultrasound in an alkali medium and treatment efficiency was
investigated by scanning electron microscopy (SEM) analysis and
Fourier transforms infrared spectrometer (FTIR). Effect of fiber
treatment on composite was characterized by tensile strength (TS),
tensile modulus (TM) and impact strength (IS). Furthermore,
biostrong impact modifier was incorporated into the treated fiber
composite to improve its impact properties. Mechanical testing
showed an improvement of up to 23.5% and 33.6% respectively for
TS and TM of treated fiber composite above untreated fiber
composite. On the other hand incorporation of impact modifier led to
enhancement of about 20% above the initial IS of the treated fiber
composite.
Abstract: This paper presents a novel fractal antenna structure
proposed for UWB (Ultra – Wideband) applications. The frequency
band 3.1-10.6GHz released by FCC (Federal Communication
Commission) as the commercial operation of UWB has been chosen
as frequency range for this antenna based on coplanar waveguide
(CPW) feed and circular shapes fulfilled according to fractal
geometry. The proposed antenna is validated and designed by using
an FR4 substrate with overall area of 34x43 mm2. The simulated
results performed by CST-Microwave Studio and compared by ADS
(Advanced Design System) show good matching input impedance
with return loss less than -10dB between 2.9 GHz and 11 GHz.
Abstract: The development, operation and maintenance of
Integrated Waste Management Systems (IWMS) affects essentially
the sustainable concern of every region. The features of such systems
have great influence on all of the components of sustainability. In
order to reach the optimal way of processes, a comprehensive
mapping of the variables affecting the future efficiency of the system
is needed such as analysis of the interconnections among the
components and modeling of their interactions. The planning of a
IWMS is based fundamentally on technical and economical
opportunities and the legal framework. Modeling the sustainability
and operation effectiveness of a certain IWMS is not in the scope of
the present research. The complexity of the systems and the large
number of the variables require the utilization of a complex approach
to model the outcomes and future risks. This complex method should
be able to evaluate the logical framework of the factors composing
the system and the interconnections between them. The authors of
this paper studied the usability of the Fuzzy Cognitive Map (FCM)
approach modeling the future operation of IWMS’s. The approach
requires two input data set. One is the connection matrix containing
all the factors affecting the system in focus with all the
interconnections. The other input data set is the time series, a
retrospective reconstruction of the weights and roles of the factors.
This paper introduces a novel method to develop time series by
content analysis.
Abstract: Equal channel angular pressing (ECAP) of
commercial Al-Mg-Si alloy was conducted using two strain rates.
The ECAP processing was conducted at room temperature and at
250°C. Route A was adopted up to a total number of four passes in
the present work. Structural evolution of the aluminum alloy discs
was investigated before and after ECAP processing using optical
microscopy (OM). Following ECAP, simple compression tests and
Vicker’s hardness were performed. OM micrographs showed that, the
average grain size of the as-received Al-Mg-Si disc tends to be larger
than the size of the ECAP processed discs. Moreover, significant
difference in the grain morphologies of the as-received and processed
discs was observed. Intensity of deformation was observed via the
alignment of the Al-Mg-Si consolidated particles (grains) in the
direction of shear, which increased with increasing the number of
passes via ECAP. Increasing the number of passes up to 4 resulted in
increasing the grains aspect ratio up to ~5. It was found that the
pressing temperature has a significant influence on the
microstructure, Hv-values, and compressive strength of the processed
discs. Hardness measurements demonstrated that 1-pass resulted in
increase of Hv-value by 42% compared to that of the as-received
alloy. 4-passes of ECAP processing resulted in additional increase in
the Hv-value. A similar trend was observed for the yield and
compressive strength. Experimental data of the Hv-values
demonstrated that there is a lack of any significant dependence on the
processing strain rate.
Abstract: Compositions of different molar ratios of
polymethylmethacrylate-co-methacrylic acid (PMMA-co-MAA)
were synthesized via free-radical polymerization. Polymer coated
surfaces have been produced on silicon wafers. Coated samples were
analyzed by atomic force microscopy (AFM). The results have shown
that the roughness of the surfaces have increased by increasing the
molar ratio of monomer methacrylic acid (MAA). This study reveals
that the gradual increase in surface roughness is due to the fact that
carboxylic functional groups have been generated by MAA segments.
Such surfaces can be desirable platforms for fabrication of the
biosensors for detection of the viruses and diseases.
Abstract: The thyroid gland is the largest classic endocrine
organ that effects many organs of the body and plays a significant
role in the process of Metabolism in animals. The aim of this study
was to investigate the prevalence of thyroid disorders diagnosed by
ultrasound and microscopic Lesions of the thyroid during the
slaughter of apparently healthy One Humped Camels (Camelus
dromedarius) in Iran. Randomly, 520 male camels (With an age
range of 4 to 8 years), were studied in 2012 to 2013. The Camels’
thyroid glands were evaluated by sonographic examination. In both
longitudinal and transverse view and then tissue sections were
provide and stained with H & E and finally examined by light
microscopy. The results obtained indicated the following:
hyperplastic goiter (21%), degenerative changes (12%), follicular
cysts (8%), follicular atrophy (4%), nodular hyperplasia (3%),
adenoma (1%), carcinoma (1%) and simple goiter colloid (1%).
Ultrasound evaluation of thyroid gland in adenoma and carcinoma
showed enlargement and irregular of the gland, decreased
echogenicity, and the heterogeneous thyroid parenchyma. Also, in
follicular cysts were observed in the enlarged gland with no echo
structures of different sizes and decreased echogenicity as a local or
general. In nodular hyperplasia, increase echogenicity and
heterogeneous parenchymal were seen. These findings suggest the
use of sonography and pathology as a screening test in the diagnosis
of complications of thyroid disorders.
Abstract: Complexation of anthocyanins to mimic natural
copigmentation process was investigated. Cyanidin-rich extracts from
Zea mays L. ceritina Kulesh. and delphinidin-rich extracts from
Clitoria ternatea L. were used to form 4 anthocyanin complexes,
AC1, AC2, AC3 and AC4, in the presence of several polyphenols and
a trace metal. Characterizations of the ACs were conducted by UV,
FTIR, DSC/TGA and morphological observations. Bathochromic
shifts of the UV spectra of 4 formulas of ACs were observed at peak
wavelengths of about 510-620 nm by 10 nm suggesting complex
formation. FTIR spectra of the ACs indicate shifts of peaks from
1,733 cm-1 to 1,696 cm-1 indicating interactions and a decrease in the
peak areas within the wavenumber of 3,400-3,500 cm-1 indicating
changes in hydrogen bonding. Thermal analysis of all of the ACs
suggests increases in melting temperature after complexation. AC
with the highest melting temperature was morphologically observed
by SEM and TEM to be crystal-like particles within a range of 50 to
200 nm. Particle size analysis of the AC by laser diffraction gave a
range of 50-600 nm, indicating aggregation. This AC was shown to
have no cytotoxic effect on cultured HGEPp0.5 and HGF (all p>
0.05) by MTT. Therefore, complexation of anthocyanins was simple
and self-assembly process, potentially resulting in nanosized particles
of anthocyanin complex.
Abstract: This study presents synthesis of novel block
copolymers of thienyl end capped ethoxylated nonyl phenol and
pyrrole via chemical oxidative polymerization. Ethoxylated nonyl
phenol (ENP) was reacted with 2-thiophenecarbonyl chloride in order
to synthesize a macromonomer containing thienyl end-group (ENPThC).
Then copolymers of ENP-ThC and pyrrole were synthesized
by chemical oxidative polymerization using iron (III) chloride as an
oxidant. ENP-ThC served both as a macromonomer and an emulsifier
for pyrrole with poor solubility in water.
The synthesized block copolymers (ENP-ThC-b-PPy) were
characterized by spectroscopic analysis and the electrical
conductivities were investigated with 4-point probe technique.
Abstract: Evaluating the performance of a simulator in the
CAVE has to be confirmed by encouraging people to live the
experience of virtual reality. In this paper, a detailed procedure of
recording video is presented. Limitations of the experimental device
are firstly exposed. Then, solutions for improving this idea are finally
described.
Abstract: Replacement of plastics used in the food industry
seems to be a serious issue to overcome mainly the environmental
problems in recent years. This study investigates the hydrophilicity
and permeability properties of starch biopolymer which ethylene
vinyl alcohol (EVOH) (0-10%) and nanocrystalline cellulose (NCC)
(1-15%) were used to enhance its properties. Starch -EVOH
nanocomposites were prepared by casting method in different
formulations. NCC production by acid hydrolysis was confirmed by
scanning electron microscopy. Solubility, water vapor permeability,
water vapor transmission rate and moisture absorbance were
measured on each of the nanocomposites. The results were analyzed
by SAS software. The lowest moisture absorbance was measured in
pure starch nanocomposite containing 8% NCC. The lowest
permeability to water vapor belongs to starch nanocomposite
containing 8% NCC and the sample containing 7.8% EVOH and 13%
NCC. Also the lowest solubility was observed in the composite
contains the highest amount of EVOH. Applied Process resulted in
production of bio films which have good resistance to water vapor
permeability and solubility in water. The use of NCC and EVOH
leads to reduced moisture absorbance property of the biofilms.
Abstract: In the scope of application of technical textiles, Non-
Crimp Fabrics are increasingly used. In general, NCF exhibit
excellent load bearing properties, but caused by the manufacturing
process, there are some remaining disadvantages which have to be
reduced. Regarding to this, a novel technique of processing NCF was
developed substituting the binding-thread by an adhesive. This stitchfree
method requires new manufacturing concept as well as new basic
methods to prove adhesion of glue at fibres and textiles. To improve
adhesion properties and the wettability of carbon-fibres by the
adhesive, oxy-fluorination was used. The modification of carbonfibres
by oxy-fluorination was investigated via scanning electron
microscope, X-ray photoelectron spectroscopy and single fibre
tensiometry. Special tensile tests were developed to determine the
maximum force required for detachment.
Abstract: An exploration of the related literature reveals that all
instruction methods aim at training autonomous learners. After the
turn of second language pedagogy toward learner-oriented strategies,
learners’ needs were more focused. Yet; the historical, social and
political aspects of learning were still neglected. The present study
investigates the notion of autonomous learning and explains its
various facets from a pedagogical point of view. Furthermore;
different elements, fields and scopes of autonomous learning will be
explored. After exploring different aspects of autonomy, it is
postulated that liberatory autonomy is highlighted since it not only
covers social autonomy but also reveals learners’ capabilities and
human potentials. It is also recommended that learners consider
different elements of autonomy such as motivation, knowledge,
confidence, and skills.
Abstract: Alkylated silicon nanocrystals (C11-SiNCs) were
prepared successfully by galvanostatic etching of p-Si(100) wafers
followed by a thermal hydrosilation reaction of 1-undecene in
refluxing toluene in order to extract C11-SiNCs from porous silicon.
Erbium trichloride was added to alkylated SiNCs using a simple
mixing chemical route. To the best of our knowledge, this is the first
investigation on mixing SiNCs with erbium ions (III) by this
chemical method. The chemical characterization of C11-SiNCs and
their mixtures with Er3+(Er/C11-SiNCs) were carried out using X-ray
photoemission spectroscopy (XPS). The optical properties of C11-
SiNCs and their mixtures with Er3+ were investigated using Raman
spectroscopy and photoluminescence (PL). The erbium mixed
alkylated SiNCs shows an orange PL emission peak at around 595
nm that originates from radiative recombination of Si. Er/C11-SiNCs
mixture also exhibits a weak PL emission peak at 1536 nm that
originates from the intra-4f transition in erbium ions (Er3+). The PL
peak of Si in Er/C11-SiNCs mixture is increased in the intensity up to
three times as compared to pure C11-SiNCs. The collected data
suggest that this chemical mixing route leads instead to a transfer of
energy from erbium ions to alkylated SiNCs.
Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: Artificial Neural Network (ANN) can be trained using
back propagation (BP). It is the most widely used algorithm for
supervised learning with multi-layered feed-forward networks.
Efficient learning by the BP algorithm is required for many practical
applications. The BP algorithm calculates the weight changes of
artificial neural networks, and a common approach is to use a twoterm
algorithm consisting of a learning rate (LR) and a momentum
factor (MF). The major drawbacks of the two-term BP learning
algorithm are the problems of local minima and slow convergence
speeds, which limit the scope for real-time applications. Recently the
addition of an extra term, called a proportional factor (PF), to the
two-term BP algorithm was proposed. The third increases the speed
of the BP algorithm. However, the PF term also reduces the
convergence of the BP algorithm, and criteria for evaluating
convergence are required to facilitate the application of the three
terms BP algorithm. Although these two seem to be closely related,
as described later, we summarize various improvements to overcome
the drawbacks. Here we compare the different methods of
convergence of the new three-term BP algorithm.
Abstract: Developing young people’s employability is a key
policy issue for ensuring their successful transition to the labour
market and their access to career oriented employment. The youths of
today irrespective of their gender need to acquire the knowledge,
skills and attitudes that will enable them to create or find jobs as well
as cope with unpredictable labour market changes throughout their
working lives. In a study carried out to determine the influence of
gender on job-competencies requirements of chemical-based
industries and undergraduate-competencies acquisition by chemists
working in the industries, all chemistry graduates working in twenty
(20) chemical-based industries that were randomly selected from six
sectors of chemical-based industries in Lagos and Ogun States of
Nigeria were administered with Job-competencies required and
undergraduate-competencies acquired assessment questionnaire. The
data were analysed using means and independent sample t-test. The
findings revealed that the population of female chemists working in
chemical-based industries is low compared with the number of male
chemists; furthermore, job-competencies requirements are found not
to be gender biased while there is no significant difference in
undergraduate-competencies acquisition of male and female
chemists. This suggests that females should be given the same
opportunity of employment in chemical-based industries as their male
counterparts. The study also revealed the level of acquisition of
undergraduate competencies as related to the needs of chemicalbased
industries.
Abstract: In this study which has been conducted in Akçasu
Forest Range District of Devrek Forest Directorate; 3 methods (weed
control with labourer power, cover removal with Hitachi F20
Excavator, and weed control with agricultural equipment mounted on
a Ferguson 240S agriculture tractor) were utilized in weed control
efforts in regeneration of degraded oriental beech forests have been
compared. In this respect, 3 methods have been compared by
determining certain work hours and standard durations of unit areas
(1 hectare). For this purpose, evaluating the tasks made with human
and machine force from the aspects of duration, productivity and
costs, it has been aimed to determine the most productive method in
accordance with the actual ecological conditions of research field.
Within the scope of the study, the time studies have been conducted
for 3 methods used in weed control efforts. While carrying out those
studies, the performed implementations have been evaluated by
dividing them into business stages. Also, the actual data have been
used while calculating the cost accounts. In those calculations, the
latest formulas and equations which are also used in developed
countries have been utilized. The variance of analysis (ANOVA) was
used in order to determine whether there is any statistically
significant difference among obtained results, and the Duncan test
was used for grouping if there is significant difference. According to
the measurements and findings carried out within the scope of this
study, it has been found during living cover removal efforts in
regeneration efforts in demolished oriental beech forests that the
removal of weed layer in 1 hectare of field has taken 920 hours with
labourer force, 15.1 hours with excavator and 60 hours with an
equipment mounted on a tractor. On the other hand, it has been
determined that the cost of removal of living cover in unit area (1
hectare) was 3220.00 TL for labourer power, 1250 TL for excavator
and 1825 TL for equipment mounted on a tractor.
According to the obtained results, it has been found that the
utilization of excavator in weed control effort in regeneration of
degraded oriental beech regions under actual ecological conditions of
research field has been found to be more productive from both of
aspects of duration and costs. These determinations carried out
should be repeated in weed control efforts in degraded forest fields
with different ecological conditions, it is compulsory for finding the
most efficient weed control method. These findings will light the way
of technical staff of forestry directorate in determination of the most
effective and economic weed control method. Thus, the more actual
data will be used while preparing the weed control budgets, and there
will be significant contributions to national economy. Also the results of this and similar studies are very important for developing the policies for our forestry in short and long term.
Abstract: This paper provides a comparative study on the
performances of standard PID and adaptive PID controllers tested on
travel angle of a 3-Degree-of-Freedom (3-DOF) Quanser bench-top
helicopter. Quanser, a well-known manufacturer of educational
bench-top helicopter has developed Proportional Integration
Derivative (PID) controller with Linear Quadratic Regulator (LQR)
for all travel, pitch and yaw angle of the bench-top helicopter. The
performance of the PID controller is relatively good; however, its
performance could also be improved if the controller is combined
with adaptive element. The objective of this research is to design
adaptive PID controller and then compare the performances of the
adaptive PID with the standard PID. The controller design and test is
focused on travel angle control only. Adaptive method used in this
project is self-tuning controller, which controller’s parameters are
updated online. Two adaptive algorithms those are pole-placement
and deadbeat have been chosen as the method to achieve optimal
controller’s parameters. Performance comparisons have shown that
the adaptive (deadbeat) PID controller has produced more desirable
performance compared to standard PID and adaptive (poleplacement).
The adaptive (deadbeat) PID controller attained very fast
settling time (5 seconds) and very small percentage of overshoot (5%
to 7.5%) for 10° to 30° step change of travel angle.
Abstract: Near infrared (NIR) spectroscopy has always been of
great interest in the food and agriculture industries. The development
of prediction models has facilitated the estimation process in recent
years. In this study, 110 crude palm oil (CPO) samples were used to
build a free fatty acid (FFA) prediction model. 60% of the collected
data were used for training purposes and the remaining 40% used for
testing. The visible peaks on the NIR spectrum were at 1725 nm and
1760 nm, indicating the existence of the first overtone of C-H bands.
Principal component regression (PCR) was applied to the data in
order to build this mathematical prediction model. The optimal
number of principal components was 10. The results showed
R2=0.7147 for the training set and R2=0.6404 for the testing set.