Abstract: The influence of three different types of halloysite
nanotubes (HNTs) with different dimensions, namely as camel lake
(CLA), Jarrahdale (JA) and Matauri Bay (MB), on their reinforcing
ability of ethylene propylene dine monomer (EPDM) were
investigated by varying the HNTs loading (from 0-15 phr).
Mechanical properties of the nanocomposites improved with addition
of all three HNTs, but CLA based nanocomposites exhibited a
significant enhancement compared to the other HNTs. For instance,
tensile properties of EPDM nanocomposites increased by 120%,
256% and 340% for MB, JA and CLA, respectively, with addition of
15 phr of HNTs. This could be due to the higher aspect ratio and
higher surface area of CLA compared to others. Scanning electron
microscopy (SEM) of nanocomposites at 15 phr of HNT loadings
showed low amounts of pulled-out nanotubes which confirmed the
presence of more embedded nanotubes inside the EPDM matrix, as
well as aggregates within the fracture surface of EPDM/HNT
nanocomposites
Abstract: The biosynthesis of nanoparticles by microorganisms,
on the contrary to chemical synthesis, is an environmentally-friendly
process which has low energy requirements. In this investigation, we
used the microorganism Geobacillus wiegelii, strain GWE1, an
aerobic thermophile belonging to genus Geobacillus, isolated from a
drying oven. This microorganism has the ability to reduce selenite
evidenced by the change of color from colorless to red in the culture.
Elemental analysis and composition of the particles were verified
using transmission electron microscopy and energy-dispersive X-ray
analysis. The nanoparticles have a defined spherical shape and a
selenium elemental state. Previous experiments showed that the
presence of the whole microorganism for the reduction of selenite
was not necessary. The results strongly suggested that an intracellular
NADPH/NADH-dependent reductase mediates selenium
nanoparticles synthesis under aerobic conditions. The enzyme was
purified and identified by mass spectroscopy MALDI-TOF TOF
technique. The enzyme is a 1-pyrroline-5-carboxylate dehydrogenase.
Histograms of nanoparticles sizes were obtained. Size distribution
ranged from 40-160 nm, where 70% of nanoparticles have less than
100 nm in size. Spectroscopic analysis showed that the nanoparticles
are composed of elemental selenium. To analyse the effect of pH in
size and morphology of nanoparticles, the synthesis of them was
carried out at different pHs (4.0, 5.0, 6.0, 7.0, 8.0). For
thermostability studies samples were incubated at different
temperatures (60, 80 and 100 ºC) for 1 h and 3 h. The size of all
nanoparticles was less than 100 nm at pH 4.0; over 50% of
nanoparticles have less than 100 nm at pH 5.0; at pH 6.0 and 8.0 over
90% of nanoparticles have less than 100 nm in size. At neutral pH
(7.0) nanoparticles reach a size around 120 nm and only 20% of them
were less than 100 nm. When looking at temperature effect,
nanoparticles did not show a significant difference in size when they
were incubated between 0 and 3 h at 60 ºC. Meanwhile at 80 °C the
nanoparticles suspension lost its homogeneity. A change in size was
observed from 0 h of incubation at 80ºC, observing a size range
between 40-160 nm, with 20% of them over 100 nm. Meanwhile
after 3 h of incubation at size range changed to 60-180 nm with 50%
of them over 100 nm. At 100 °C the nanoparticles aggregate forming
nanorod structures. In conclusion, these results indicate that is
possible to modulate size and shape of biologically synthesized
nanoparticles by modulating pH and temperature.
Abstract: A series of polystyrene (PS) nanoparticles were
prepared by grafting polystyrene from both aggregated silica and
colloidally dispersed silica nanoparticles using atom-transfer radical
polymerisation (ATRP). Cross-linking and macroscopic gelation
were minimised by using a miniemulsion system. The thermal and
mechanical behaviour of the nanocomposites have been examined by
differential scanning calorimetry (DSC) and dynamic mechanical
thermal analysis (DMTA).
Abstract: In this study, we aim to demonstrate a microgrid
system experimental simulation for an easy understanding of a
large-scale microgrid system. This model is required for industrial
training and learning environments. However, in order to create an
exact representation of a microgrid system, the laboratory-scale
system must fulfill the requirements of a grid-connected inverter, in
which power values are assigned to the system to cope with the
intermittent output from renewable energy sources. Aside from that,
during fluctuations in load capacity, the grid-connected system must
be able to supply power from the utility grid side and microgrid side in
a balanced manner. Therefore, droop control is installed in the
inverter’s control board to maintain a balanced power sharing in both
sides. This power control in a stand-alone condition and droop control
in a grid-connected condition must be implemented in order to
maintain a stabilized system. Based on the experimental results, power
control and droop control can both be applied in the system by
comparing the experimental and reference values.
Abstract: Hydrogenated amorphous carbon (a-C:H) films have
been synthesized by a radio frequency plasma enhanced chemical
vapor deposition (rf-PECVD) technique with different bias voltage
from 0.0 to -0.5 kV. The Raman spectra displayed the polymer-like
hydrogenated amorphous carbon (PLCH) film with 0.0 to -0.1 and
a-C:H films with -0.2 to -0.5 kV of bias voltages. The surface chemical
information of all films were studied by X-ray photoelectron
spectroscopy (XPS) technique, presented to C-C (sp2 and sp3) and C-O
bonds, and relative carbon (C) and oxygen (O) atomics contents. The
O contamination had affected on structure and optical properties. The
true density of PLCH and a-C:H films were characterized by X-ray
refractivity (XRR) method, showed the result as in the range of
1.16-1.73 g/cm3 that depending on an increasing of bias voltage. The
hardness was proportional to the true density of films. In addition, the
optical properties i.e. refractive index (n) and extinction coefficient (k)
of these films were determined by a spectroscopic ellipsometry (SE)
method that give formation to in 1.62-2.10 (n) and 0.04-0.15 (k)
respectively. These results indicated that the optical properties
confirmed the Raman results as presenting the structure changed with
applied bias voltage increased.
Abstract: One of the biggest challenges facing Theological/
Religious Education in Nigeria is access to quality learning materials.
For instance at the Trinity (Union) Theological College, Umuahia, it
was difficult for lecturers to access suitable and qualitative materials
for instruction especially the ones that would suit the African context
and stimulate a deep rooted interest among the students. Some
textbooks written by foreign authors were readily available in the
School Library, but were lacking in the College bookshops for
students to own copies. Even when the College was able to order
some of the books from abroad, it did not usher in the needed
enthusiasm expected from the students because they were either very
expensive or very difficult to understand during private studies. So it
became necessary to develop contextual materials which were
affordable and understandable, though with little success. The
National Open University of Nigeria (NOUN)’s innovation in the
development and sharing of learning resources through its Open
Courseware is a welcome development and of great assistance to
students. Apart from NOUN students who could easily access the
materials, many others from various theological/religious institutes
across the nation have benefited immensely. So, the thesis of this
paper is that the promotion of open educational resources in
theological/religious education in Nigeria would facilitate a better
informed/equipped religious leadership, which would in turn impact
its adherents for a healthier society and national development.
Adopting a narrative and historical approach within the context of
Nigeria’s educational system, the paper discusses: educational
traditions in Nigeria; challenges facing theological/religious
education in Nigeria; and benefits of open educational resources. The
study goes further to making recommendations on how OER could
positively influence theological/religious education in Nigeria. It is
expected that theologians, religious educators, and ODL practitioners
would find this work very useful.
Abstract: In the present study, we have synthesized Cr and Fe
doped zinc oxide (ZnO) nanostructures (Zn1-δCraFebO; where δ = a +
b = 20%, a = 5, 6, 8 & 10% and b = 15, 14, 12 & 10%) via sol-gel
method at different doping concentrations. The synthesized samples
were characterized for structural properties by X-ray diffractrometer
and field emission scanning electron microscope and the optical
properties were carried out through photoluminescence and UVvisible
spectroscopy. The particle size calculated through field
emission scanning electron microscope varies from 41 to 96 nm for
the samples synthesized at different doping concentrations. The
optical band gaps calculated through UV-visible spectroscopy are
found to be decreasing from 3.27 to 3.02 eV as the doping
concentration of Cr increases and Fe decreases.
Abstract: Multiwall carbon nanotubes, prepared by chemical
vapor deposition, have an average diameter of 60-100 nm as shown
by High Resolution Transmittance Electron Microscope, HR-TEM.
The Multiwall carbon nanotubes (MWCNTs) were further
characterized using X-ray Diffraction and Raman Spectroscopy.
Mercury uptake capacity of MWCNTs was studied using batch
adsorption method at different concentration ranges up to 150 ppm.
Mercury concentration (before and after the treatment) was measured
using cold vapor atomic absorption spectroscopy. The effect of time,
concentration, pH and adsorbent dose were studied. MWCNT were
found to perform complete absorption in the sub-ppm concentrations
(parts per billion levels) while for high concentrations, the adsorption
efficiency was 92% at the optimum conditions; 0.1 g of the adsorbent
at 150 ppm mercury (II) solution. The adsorption of mercury on
MWCNTs was found to follow the Freundlich adsorption isotherm
and the pseudo-second order kinetic model.
Abstract: In the present work, hydrogen gas sensor of modest
sensitivity utilizing functionalized multiwalled carbon nanotubes
partially decorated with tin oxide nanoparticles (F-MWCNTs/SnO2)
has been fabricated. This sensing material was characterized by
scanning electron microscopy (SEM). In addition, a remarkable
finding was that the F-MWCNTs/SnO2 sensor shows good sensitivity
as compared to F-MWCNTs for low concentration (0.05-1% by
volume) of H2 gas. The fabricated sensors show complete resistance
recovery and good repeatability when exposed to H2 gas at the room
temperature conditions.
Abstract: In this paper, snow samples containing dust particles
from several sampling points around the city of Ostrava were
analyzed. The pH values of sampled snow were measured and solid
particles analyzed. Particle size, zeta potential and content of selected
heavy metals were determined in solid particles. The pH values of
most samples lay in the slightly acid region. Mean values of particle
size ranged from 290.5 to 620.5 nm. Zeta potential values varied
between -5 and -26.5 mV. The following heavy metal concentration
ranges were found: copper 0.08-0.75 mg/g, lead 0.05-0.9 mg/g,
manganese 0.45-5.9 mg/g and iron 25.7-280.46 mg/g. The highest
values of copper and lead were found in the vicinity of busy
crossroads, and on the contrary, the highest levels of manganese and
iron were detected close to a large steelworks. The proportion
between pH values, zeta potentials, particle sizes and heavy metal
contents was established. Zeta potential decreased with rising pH
values and, simultaneously, heavy metal content in solid particles
increased. At the same time, higher metal content corresponded to
lower particle size.
Abstract: Metallic foams have good potential for lightweight
structures for impact and blast mitigation. Therefore it is important to
find out the optimized foam structure (i.e. cell size, shape, relative
density, and distribution) to maximise energy absorption. In this
paper, quasistatic compression and microstructural characterization
of closed-cell aluminium foams of different pore size and cell
distributions have been carried out. We present results for two
different aluminium metal foams of density 0.49-0.51 g/cc and 0.31-
0.34 g/cc respectively that have been tested in quasi-static
compression. The influence of cell geometry and cell topology on
quasistatic compression behaviour has been investigated using optical
microscope and computed tomography (micro-CT) analysis. It is
shown that the deformation is not uniform in the structure and
collapse begins at the weakest point.
Abstract: In this paper, the effect of WC-12Co particle
temperature in HVOF thermal spraying process on the coating
thickness has been studied. The statistical results show that the spray
distance and oxygen-to-fuel ratio are effective factors on particle
characterization and thickness of HVOF thermal spraying coatings.
Spray Watch diagnostic system, scanning electron microscopy
(SEM), X-ray diffraction and thickness measuring system were used
for this purpose.
Abstract: This research aims to investigate callus induction,
somatic embryogenesis and indirect plant regeneration of Crassula
ovata (Mill.) Druce – the famous ornamental plant. Experiment no.1:
Callus induction was obtained from leaf and stem explants on
Murashige and Skoog (MS) medium supplemented with various plant
growth regulators (PGRs). Effects of different PGRs, plant
regeneration and subsequent plantlet conversion were also assessed.
Indirect plant regeneration was achieved from the callus of stem
explants by the addition of 1.5 mg/L Kinetin (KN) alone. Best shoot
induction was achieved (6.5 shoots/per explant) after 60 days. For
successful rooting, regenerated plantlets were sub-cultured on the
same MS media supplemented with 1.5 mg/L KN alone. The rooted
plantlets were acclimatized and the survival rate was 90%.
Experiment no.2: Results revealed that 0.5 mg/L 2,4-D alone and in
combination with 1.0 mg/L 6-Benzyladenine (BA) gave 89.8% callus
from the stem explants as compared to leaf explants. Callus
proliferation and somatic embryo formation were also evaluated by
‘Double Staining Method’ and different stages of somatic
embryogenesis were revealed by scanning electron microscope. Full
Strength MS medium produced the highest number (49.6%) of
cotyledonary stage somatic embryos (SEs). Mature cotyledonary
stage SEs developed into plantlets after 12 weeks of culture. Wellrooted
plantlets were successfully acclimatized at the survival rate of
85%. Indirectly regenerated plants did not show any detectable
variation in morphological and growth characteristics when
compared with the donor plant.
Abstract: The detection of environmental gases, 12CO2, 13CO2,
and CH4, using near-infrared semiconductor lasers with a short
laser path length is studied by means of wavelength-modulation
spectroscopy. The developed system is compact and has high
sensitivity enough to detect the absorption peaks of isotopic 13CO2
of a 3-% CO2 gas at 2 μm with a path length of 2.4 m, where
its peak size is two orders of magnitude smaller than that of the
ordinary 12CO2 peaks. In addition, the detection of 12CO2 peaks of
a 385-ppm (0.0385-%) CO2 gas in the air is made at 2 μm with a
path length of 1.4 m. Furthermore, in pursuing the detection of an
ancient environmental CH4 gas confined to a bubble in ice at the
polar regions, measurements of the absorption spectrum for a trace
gas of CH4 in a small area are attempted. For a 100-% CH4 gas
trapped in a ∼ 1 mm3 glass container, the absorption peaks of CH4
are obtained at 1.65 μm with a path length of 3 mm, and also the
gas pressure is extrapolated from the measured data.
Abstract: A wireless sensor network (WSN) is a collection of
sensor nodes organized into a cooperative network. These nodes
communicate through a wireless antenna. Reduction in physical size
and multiband operation is an important requirement of WSN
antenna. Fractal antenna is used for miniaturization and multiband
operation. The self-similar or self-affine and space filling property of
fractal geometry increases the effective electrical length of the
antenna, reduces the size and make them frequency independent. This
paper elaborates on Dual band fractal antenna with Coplanar
Waveguide (CPW) feed for WSN. The proposed antenna is designed
on a FR4 substrate with the dimension of 27mm x 28.5mm x 1.6mm,
resonates at 2.4GHz and 5.2GHz with a return loss less than -10dB.
The design and simulation process is carried out using IE3D
simulation software. The simulated and measured results are found in
good agreement.
Abstract: Novel bio-based polymer electrolyte was synthesized
with LiClO4 as the main source of charge carrier. Initially,
polyurethane-LiClO4 polymer electrolytes were synthesized via
prepolymerization method with different NCO/OH ratios and labelled
them as PU1, PU2, PU3 and PU4. Fourier transform infrared (FTIR)
analysis indicates the co-ordination between Li+ ion and polyurethane
in PU1. Differential scanning calorimetry (DSC) analysis indicates
PU1 has the highest glass transition temperature (Tg) corresponds to
the most abundant urethane group which is the hard segment in PU1.
Scanning electron microscopy (SEM) shows the good miscibility
between lithium salt and the polymer. The study found that PU1
possessed the greatest ionic conductivity and the lowest activation
energy, Ea. All the polyurethanes exhibited linear Arrhenius
variations indicating ion transport via simple lithium ion hopping in
polyurethane. This research proves the NCO content in polyurethane
plays an important role in affecting the ionic conductivity of this
polymer electrolyte.
Abstract: Theoretical optimization of a copper-water negative
inclination heat pipe with internal composite wick structure had been
performed, regarding a new introduced parameter: the ratio between
the coarse mesh wraps and the fine mesh wraps of the composite
wick. Since in many cases, the design of a heat pipe matches specific
thermal requirements and physical limitations, this work
demonstrates the optimization of a 1m length, 8mm internal diameter
heat pipe without an adiabatic section, at a negative inclination angle
of -10º. The optimization is based on a new introduced parameter, LR:
the ratio between the coarse mesh wraps and the fine mesh wraps.
Abstract: Polyethylene (PE), Polypropylene (PP), Polyethylene
(vinyl acetate) (EVA) and PE-ionomer nanocomposite samples were
prepared by mixing of the polymer with organofilized
montmorillonite fillers Cloisite 93A and Dellite 67G. The amount of
each modified montmorillonite (MMT) was fixed to 5% (w/w). The
twin-screw kneader was used for the compounding of polymer matrix
and chosen nanofillers. The level of MMT exfoliation was studied by
the transmission electron microscopy (TEM) observations. The
mechanical properties of prepared materials were evaluated by
dynamical mechanical analysis at 30°C and by the measurement of
tensile properties (stress and strain at break).
Abstract: This study was conducted to evaluate the manganese
removal from aqueous solution using Banana peels activated carbon
(BPAC). Batch experiments have been carried out to determine the
influence of parameters such as pH, biosorbent dose, initial metal ion
concentrations and contact times on the biosorption process. From
these investigations, a significant increase in percentage removal of
manganese 97.4% is observed at pH value 5.0, biosorbent dose 0.8 g,
initial concentration 20 ppm, temperature 25 ± 2°C, stirring rate 200
rpm and contact time 2h. The equilibrium concentration and the
adsorption capacity at equilibrium of the experimental results were
fitted to the Langmuir and Freundlich isotherm models; the Langmuir
isotherm was found to well represent the measured adsorption data
implying BPAC had heterogeneous surface. A raw groundwater
samples were collected from Baharmos groundwater treatment plant
network at Embaba and Manshiet Elkanater City/District-Giza,
Egypt, for treatment at the best conditions that reached at first phase
by BPAC. The treatment with BPAC could reduce iron and
manganese value of raw groundwater by 91.4% and 97.1%,
respectively and the effect of the treatment process on the
microbiological properties of groundwater sample showed decrease
of total bacterial count either at 22°C or at 37°C to 85.7% and 82.4%,
respectively. Also, BPAC was characterized using SEM and FTIR
spectroscopy.
Abstract: One- and two-dimensional carbon nanostructures with
sp2 hybridization of carbon atoms (single walled carbon nanotubes
and graphene) are promising materials in future electronic and
spintronics devices due to specific character of their electronic
structure. In this paper we present a comparative study of graphene
and single-wall carbon nanotubes by Raman spectro-microscopy in
strong magnetic field. This unique method allows to study changes in
electronic band structure of the two types of carbon nanostructures
induced by a strong magnetic field.