Abstract: A nanocrystalline thin film of ZnSe was successfully
electrodeposited on copper substrate using a non-aqueous solution
and subsequently annealed in air at 400°C. XRD analysis indicates
the polycrystalline deposit of (111) plane in both the cases. The
sharpness of the peak increases due to annealing of the film and
average grain size increases to 20 nm to 27nm. SEM photograph
indicate that grains are uniform and densely distributed over the
surface. Annealing increases the average grain size by 20%. The EDS
spectroscopy shows the ratio of Zn & Se is 1.1 in case of annealed
film. AFM analysis indicates the average roughness of the film
reduces from 181nm to 165nm due to annealing of the film. The
bandgap also decreases from 2.71eV to 2.62eV.
Abstract: In this research (using induction furnace process)
nodular iron with three different percentages of copper (residual,
0.5% and 1,2%) was obtained. Chemical analysis was performed by
mass spectrometry and microstructures were characterized by Optical
Microscopy (ASTM E3) and Scanning Electron Microscopy (SEM).
The study of mechanical behavior was carried out in a mechanical
test machine (ASTM E8) and a Pin on disk tribometer (ASTM G99)
was used to assess wear resistance. It is observed that the dissolution
of copper in crystal lattice increases the pearlite structure improving
the wear and hardness behavior, but producing a contrary effect on
the energy absorption.
Abstract: Doxorubicin, also known as Adriamycin, is an
anthracycline class of drug used in cancer chemotherapy. It is used in
the treatment of non-Hodgkin’s lymphoma, multiple myeloma, acute
leukemia, breast cancer, lung cancer, endometrium cancer and ovary
cancers. It functions via intercalating DNA and ultimately killing
cancer cells. The major side effects of doxorubicin are hair loss,
myelosuppression, nausea & vomiting, oesophagitis, diarrhea, heart
damage and liver dysfunction. The minor modifications in the
structure of compound exhibit large variation in the biological
activity, has prompted us to carry out the synthesis of sulfonamide
derivatives. Sulfonamide is an important feature with broad spectrum
of biological activity such as antiviral, antifungal, diuretics, antiinflammatory,
antibacterial and anticancer activities. Structure of the
synthesized compound N-(1-methyl-2-oxo-2-N-methyl anilinoethyl)
benzene sulfonamide confirmed by proton nuclear magnetic
resonance (1H NMR),13C NMR, Mass and FTIR spectroscopic tools
to assure the position of all protons and hence stereochemistry of the
molecule. Further we have reported the binding potential of
synthesized sulfonamide analogues in comparison to doxorubicin
drug using Auto Dock 4.2 software. Computational binding energy
(B.E.) and inhibitory constant (Ki) has been evaluated for the
synthesized compound in comparison of doxorubicin against Poly
(dA-dT).Poly (dA-dT) and Poly (dG-dC).Poly (dG-dC) sequences.
The in vitro cytotoxic study against human breast cancer cell lines
confirms the better anticancer activity of the synthesized compound
over currently in use anticancer drug doxorubicin. The IC50 value of
the synthesized compound is 7.12 μM whereas for doxorubicin is 7.2
μM.
Abstract: The Blue Nile Basin is the most important tributary of
the Nile River. Egypt and Sudan are almost dependent on water
originated from the Blue Nile. This multi-dependency creates
conflicts among the three countries Egypt, Sudan, and Ethiopia
making the management of these conflicts as an international issue.
Good assessment of the water resources of the Blue Nile is an
important to help in managing such conflicts. Hydrological models
are good tool for such assessment. This paper presents a critical
review of the nature and variability of the climate and hydrology of
the Blue Nile Basin as a first step of using hydrological modeling to
assess the water resources of the Blue Nile. Many several attempts
are done to develop basin-scale hydrological modeling on the Blue
Nile. Lumped and semi distributed models used averages of
meteorological inputs and watershed characteristics in hydrological
simulation, to analyze runoff for flood control and water resource
management. Distributed models include the temporal and spatial
variability of catchment conditions and meteorological inputs to
allow better representation of the hydrological process. The main
challenge of all used models was to assess the water resources of the
basin is the shortage of the data needed for models calibration and
validation. It is recommended to use distributed model for their
higher accuracy to cope with the great variability and complexity of
the Blue Nile basin and to collect sufficient data to have more
sophisticated and accurate hydrological modeling.
Abstract: In this article a comparison was made between Cu and
TiO2 supported catalysts on activated carbon for ozone
decomposition reaction. The activated carbon support in the case of
TiO2/AC sample was prepared by physicochemical pyrolysis and for
Cu/AC samples the supports are chemically modified carbons. The
prepared catalysts were synthesized by impregnation method. The
samples were annealed in two different regimes- in air and under
vacuum. To examine adsorption efficiency of the samples BET
method was used. All investigated catalysts supported on chemically
modified carbons have higher specific surface area compared to the
specific surface area of TiO2 supported catalysts, varying in the range
590÷620 m2/g. The method of synthesis of the precursors had
influenced catalytic activity.
Abstract: In recent years, the hair building fiber has become
popular, in other words, it is an effective method which helps people
who suffer hair loss or sparse hair since the hair building fiber is
capable to create a natural look of simulated hair rapidly. In the
markets, there are a lot of hair fiber brands that have been designed to
formulate an intense bond with hair strands and make the hair appear
more voluminous instantly. However, those products have their own
set of properties. Thus, in this report, some measurement techniques
are proposed to identify those products. Up to five different brands of
hair fiber are tested. The electrostatic and dielectric properties of the
hair fibers are macroscopically tested using design DC and high
frequency microwave techniques. Besides, the hair fibers are
microscopically analysis by magnifying the structures of the fiber
using scanning electron microscope (SEM). From the SEM photos,
the comparison of the uniformly shaped and broken rate of the hair
fibers in the different bulk samples can be observed respectively.
Abstract: For centuries humans have used the antimicrobial
properties of copper to their advantage. Yet, after all these years the
underlying mechanisms of copper mediated cell death in various
microbes remain unclear. We had explored the hypothesis that copper
mediated increased levels of lipid peroxidation in the membrane fatty
acids is responsible for increased killing in Escherichia coli. In this
study we show that in both gram positive (Staphylococcus aureus)
and gram negative (Pseudomonas aeruginosa) bacteria there is a
strong correlation between copper mediated cell death and increased
levels of lipid peroxidation. Interestingly, the non-spore forming
gram positive bacteria as well as gram negative bacteria show similar
patterns of cell death, increased levels of lipid peroxidation, as well
as genomic DNA degradation, however there is some difference in
loss in membrane integrity upon exposure to copper alloy surface.
Abstract: Microbial fuel cells (MFCs) represent a promising
technology for simultaneous bioelectricity generation and wastewater
treatment. Catalysts are significant portions of the cost of microbial
fuel cell cathodes. Many materials have been tested as aqueous
cathodes, but air-cathodes are needed to avoid energy demands for
water aeration. The sluggish oxygen reduction reaction (ORR) rate at
air cathode necessitates efficient electrocatalyst such as carbon
supported platinum catalyst (Pt/C) which is very costly. Manganese
oxide (MnO2) was a representative metal oxide which has been
studied as a promising alternative electrocatalyst for ORR and has
been tested in air-cathode MFCs. However the single MnO2 has poor
electric conductivity and low stability. In the present work, the MnO2
catalyst has been modified by doping Pt nanoparticle. The goal of the
work was to improve the performance of the MFC with minimum Pt
loading. MnO2 and Pt nanoparticles were prepared by hydrothermal
and sol gel methods, respectively. Wet impregnation method was
used to synthesize Pt/MnO2 catalyst. The catalysts were further used
as cathode catalysts in air-cathode cubic MFCs, in which anaerobic
sludge was inoculated as biocatalysts and palm oil mill effluent
(POME) was used as the substrate in the anode chamber. The asprepared
Pt/MnO2 was characterized comprehensively through field
emission scanning electron microscope (FESEM), X-Ray diffraction
(XRD), X-ray photoelectron spectroscopy (XPS), and cyclic
voltammetry (CV) where its surface morphology, crystallinity,
oxidation state and electrochemical activity were examined,
respectively. XPS revealed Mn (IV) oxidation state and Pt (0)
nanoparticle metal, indicating the presence of MnO2 and Pt.
Morphology of Pt/MnO2 observed from FESEM shows that the
doping of Pt did not cause change in needle-like shape of MnO2
which provides large contacting surface area. The electrochemical
active area of the Pt/MnO2 catalysts has been increased from 276 to
617 m2/g with the increase in Pt loading from 0.2 to 0.8 wt%. The
CV results in O2 saturated neutral Na2SO4 solution showed that
MnO2 and Pt/MnO2 catalysts could catalyze ORR with different
catalytic activities. MFC with Pt/MnO2 (0.4 wt% Pt) as air cathode
catalyst generates a maximum power density of 165 mW/m3, which
is higher than that of MFC with MnO2 catalyst (95 mW/m3). The
open circuit voltage (OCV) of the MFC operated with MnO2 cathode
gradually decreased during 14 days of operation, whereas the MFC
with Pt/MnO2 cathode remained almost constant throughout the
operation suggesting the higher stability of the Pt/MnO2 catalyst.
Therefore, Pt/MnO2 with 0.4 wt% Pt successfully demonstrated as an
efficient and low cost electrocatalyst for ORR in air cathode MFC with higher electrochemical activity, stability and hence enhanced
performance.
Abstract: A large amount of data is typically stored in relational
databases (DB). The latter can efficiently handle user queries which
intend to elicit the appropriate information from data sources.
However, direct access and use of this data requires the end users to
have an adequate technical background, while they should also cope
with the internal data structure and values presented. Consequently
the information retrieval is a quite difficult process even for IT or DB
experts, taking into account the limited contributions of relational
databases from the conceptual point of view. Ontologies enable users
to formally describe a domain of knowledge in terms of concepts and
relations among them and hence they can be used for unambiguously
specifying the information captured by the relational database.
However, accessing information residing in a database using
ontologies is feasible, provided that the users are keen on using
semantic web technologies. For enabling users form different
disciplines to retrieve the appropriate data, the design of a Graphical
User Interface is necessary. In this work, we will present an
interactive, ontology-based, semantically enable web tool that can be
used for information retrieval purposes. The tool is totally based on
the ontological representation of underlying database schema while it
provides a user friendly environment through which the users can
graphically form and execute their queries.
Abstract: The wear measuring and wear modelling are
fundamental issues in the industrial field, mainly correlated to the
economy and safety. Therefore, there is a need to study the wear
measurements and wear estimation. Pin-on-disc test is the most
common test which is used to study the wear behaviour. In this paper,
the pin-on-disc (AEROTECH UNIDEX 11) is used for the
investigation of the effects of normal load and hardness of material on
the wear under dry and sliding conditions. In the pin-on-disc rig, two
specimens were used; one, a pin is made of steel with a tip, positioned
perpendicular to the disc, where the disc is made of aluminium. The
pin wear and disc wear were measured by using the following
instruments: The Talysurf instrument, a digital microscope, and the
alicona instrument. The Talysurf profilometer was used to measure
the pin/disc wear scar depth, digital microscope was used to measure
the diameter and width of wear scar, and the alicona was used to
measure the pin wear and disc wear. After that, the Archard model,
American Society for Testing and Materials model (ASTM), and
neural network model were used for pin/disc wear modelling.
Simulation results were implemented by using the Matlab program.
This paper focuses on how the alicona can be used for wear
measurements and how the neural network can be used for wear
estimation.
Abstract: The air transport impact on environment is more than
ever a limitative obstacle to the aeronautical industry continuous
growth. Over the last decades, considerable effort has been carried
out in order to obtain quieter aircraft solutions, whether by changing
the original design or investigating more silent maneuvers. The
noise propagated by rotating surfaces is one of the most important
sources of annoyance, being present in most aerial vehicles. Bearing
this is mind, CEIIA developed a new computational chain for
noise prediction with in-house software tools to obtain solutions in
relatively short time without using excessive computer resources. This
work is based on the new acoustic tool, which aims to predict the
rotor noise generated during steady and maneuvering flight, making
use of the flexibility of the C language and the advantages of GPU
programming in terms of velocity. The acoustic tool is based in the
Formulation 1A of Farassat, capable of predicting two important
types of noise: the loading and thickness noise. The present work
describes the most important features of the acoustic tool, presenting
its most relevant results and framework analyses for helicopters and
UAV quadrotors.
Abstract: Near-infrared spectroscopy (NIRS) has been widely
used as a non-invasive method to measure brain activity, but it is
corrupted by baseline drift noise. Here we present a method to measure
regional cerebral blood flow as a derivative of NIRS output. We
investigate whether, when listening to languages, blood flow can
reasonably localize and represent regional brain activity or not. The
prefrontal blood flow distribution pattern when advanced
second-language listeners listened to a second language (L2) was most
similar to that when listening to their first language (L1) among the
patterns of mean and standard deviation. In experiments with 25
healthy subjects, the maximum blood flow was localized to the left
BA46 of advanced listeners. The blood flow presented is robust to
baseline drift and stably localizes regional brain activity.
Abstract: The aim of this paper is to perform experimental
modal analysis (EMA) of reinforced concrete (RC) square slabs.
EMA is the process of determining the modal parameters (Natural
Frequencies, damping factors, modal vectors) of a structure from a
set of frequency response functions FRFs (curve fitting). Although,
experimental modal analysis (or modal testing) has grown steadily in
popularity since the advent of the digital FFT spectrum analyzer in
the early 1970’s, studying all types of members and materials using
such method have not yet been well documented. Therefore, in this
work, experimental tests were conducted on RC square slab
specimens of dimensions 600mm x 600mmx 40mm. Experimental
analysis was based on freely supported boundary condition.
Moreover, impact testing as a fast and economical means of finding
the modes of vibration of a structure was used during the
experiments. In addition, Pico Scope 6 device and MATLAB
software were used to acquire data, analyze and plot Frequency
Response Function (FRF). The experimental natural frequencies
which were extracted from measurements exhibit good agreement
with analytical predictions. It is showed that EMA method can be
usefully employed to investigate the dynamic behavior of RC slabs.
Abstract: Thin ZnO films are deposited on glass substrates via
sol–gel method and dip-coating. The films are prepared from zinc
acetate dehydrate as a starting reagent. After that the as-prepared
ZnO sol is aged for different periods (0, 1, 3, 5, 10, 15 and 30 days).
Nanocrystalline thin films are deposited from various sols. The
effect ZnO sols aging time on the structural and photocatalytic
properties of the films is studied. The films surface is studied by
Scanning Electron Microscopy. The effect of the aging time of the
starting solution is studied in the photocatalytic degradation of
Reactive Black 5 (RB5) by UV-vis spectroscopy. The experiments
are conducted upon UV-light illumination and in complete darkness.
The variation of the absorption spectra shows the degradation of RB5
dissolved in water, as a result of the reaction, occurring on the surface
of the films and promoted by UV irradiation. The initial
concentrations of dye (5, 10 and 20 ppm) and the effect of the aging
time are varied during the experiments. The results show, that the
increasing aging time of starting solution with respect to ZnO
generally promotes photocatalytic activity. The thin films obtained
from ZnO sol, which is aged 30 days have best photocatalytic
degradation of the dye (97,22%) in comparison with the freshly
prepared ones (65,92%). The samples and photocatalytic
experimental results are reproducible. Nevertheless, all films exhibit
a substantial activity in both UV light and darkness, which is
promising for the development of new ZnO photocatalysts by sol-gel
method.
Abstract: Verification and Validation of Simulated Process
Model is the most important phase of the simulator life cycle.
Evaluation of simulated process models based on Verification and
Validation techniques checks the closeness of each component model
(in a simulated network) with the real system/process with respect to
dynamic behaviour under steady state and transient conditions. The
process of Verification and Validation helps in qualifying the process
simulator for the intended purpose whether it is for providing
comprehensive training or design verification. In general, model
verification is carried out by comparison of simulated component
characteristics with the original requirement to ensure that each step
in the model development process completely incorporates all the
design requirements. Validation testing is performed by comparing
the simulated process parameters to the actual plant process
parameters either in standalone mode or integrated mode.
A Full Scope Replica Operator Training Simulator for PFBR -
Prototype Fast Breeder Reactor has been developed at IGCAR,
Kalpakkam, INDIA named KALBR-SIM (Kalpakkam Breeder
Reactor Simulator) where in the main participants are
engineers/experts belonging to Modeling Team, Process Design and
Instrumentation & Control design team. This paper discusses about
the Verification and Validation process in general, the evaluation
procedure adopted for PFBR operator training Simulator, the
methodology followed for verifying the models, the reference
documents and standards used etc. It details out the importance of
internal validation by design experts, subsequent validation by
external agency consisting of experts from various fields, model
improvement by tuning based on expert’s comments, final
qualification of the simulator for the intended purpose and the
difficulties faced while co-coordinating various activities.
Abstract: Malaysia is rich with historic buildings, particularly in
Penang and Malacca states. Restoration activities are increasingly
important as these states are recognized under UNESCO World
Heritage Sites. Restoration activities help to maintain the uniqueness
and value of a heritage building. However, increasing in restoration
activities has resulted in large quantities of waste. To cope with this
problem, the 3R concept (reduce, reuse and recycle) is introduced.
The 3R concept is one of the waste management hierarchies. This
concept is still yet to apply in the building restoration industry
compared to the construction industry. Therefore, this study aims to
promote the 3R concept in the heritage building restoration industry.
This study aims to examine the importance of 3R concept and to
identify challenges in applying the 3R concept in the heritage
building restoration industry. This study focused on contractors and
consultants who are involved in heritage restoration projects in
Penang. Literature review and interviews helps to reach the research
objective. Data that obtained is analyzed by using content analysis.
For the research, application of 3R concept is important to conserve
natural resources and reduce pollution problems. However, limited
space to organise waste is the obstruction during the implementation
of this concept. In conclusion, the 3R concept plays an important role
in promoting environmental conservation and helping in reducing the
construction waste.
Abstract: This work presents synthesis of α,ω-dithienyl
terminated poly(ethylene glycol) (PEGTh) capable for further chain
extension by either chemical or electrochemical polymeriztion.
PEGTh was characterized by FTIR and 1H-NMR. Further
copolymerization of PEGTh and pyrrole (Py) was performed by
chemical oxidative polymerization using ceric (IV) salt as an oxidant
(PPy-PEGTh). PEG without end group modification was used
directly to prepare copolymers with Py by Ce (IV) salt (PPy-PEG).
Block copolymers with mole ratio of pyrrole to PEGTh (PEG) 50:1
and 10:1 were synthesized. The electrical conductivities of
copolymers PPy-PEGTh and PPy-PEG were determined by four
point probe technique. Influence of the synthetic route and content of
the insulating segment on conductivity and yield of the copolymers
were investigated.
Abstract: Bio-composites derived from plant fiber and/or bioderived
polymer, are likely more ecofriendly and demonstrate
competitive performance with petroleum based composites. In this
research, the bio phenol-formaldehyde (bio-PF) was used as a matrix
and oil palm empty fruit bunch fiber (EFB) as reinforcement. The
matrix was synthesized via liquefaction and condensation to enhance
the combination of phenol and formaldehyde, during the process.
Then, the bio-PF was mixed with different percentage of EFB (5%,
10%, 15% and 20%) and molded at 180oC. The samples that viewed
under scanning electron microscopy (SEM) showed an excellent
wettability and interaction between EFB and matrix. Samples of 10%
EFB gave the optimum properties of impact and hardness meanwhile
sample 15% of EFB gave the highest reading of flexural modulus
(MOE) and flexural strength (MOR). For thermal stability analysis, it
was found that the weight loss and the activation energy (Ea) of the
bio-composites samples were decreased as the filler content
increased.
Abstract: Water contamination by toxic compound is one of the serious environmental problems today. These toxic compounds mostly originated from industrial effluents, agriculture, natural sources and human waste. These studies focus on modification of multiwalled carbon nanotube (MWCNTs) with nanoparticle of calixarene and explore the possibility of using this modification for the remediation of cadmium in water. The nanocomposites were prepared by dissolving calixarene in chloroform solution as solvent, followed by additional multiwalled carbon nanotube (MWCNTs) then sonication process for 3 hour and fabricated the nanocomposites on substrate by spin coating method. Finally, the nanocomposites were tested on cadmium ion (10 mg/ml). The morphology of nanocomposites was investigated by FESEM showing the formation of calixarene on the outer walls of carbon nanotube and cadmium ion also clearly seen from the micrograph. This formation was supported by using energy dispersive x-ray (EDX). The presence of cadmium ions in the films, leads to some changes in the surface potential and Fourier Transform Infrared spectroscopy (FTIR).The nanocomposites MWCNTs-calixarene have potential for development of sensor for pollutant monitoring and nanoelectronics devices applications.
Abstract: The present work aims to throw light on the effects of
arcing in air on the surface state of contact pastilles made of silvernickel
Ag-Ni (60/40). Also, the photoelectric emission from these
electrical contacts has been investigated in the spectral range of 196-
256 nm. In order to study the effects of arcing on the EWF, the
metallic samples were subjected to electrical arcs in air, at
atmospheric pressure and room temperature, after that, they have
been introduced into the vacuum chamber of an experimental UHV
set-up for EWF measurements. Both Fowler method of isothermal
curves and linearized Fowler plots were used for the measurement of
the EWF by the photoelectric effect.
It has been found that the EWF varies with the number of applied
arcs. Thus, after 500 arcs in air, the observed EWF increasing is
probably due to progressive inclusion of oxide on alloy surface.
Microscopic examination is necessary to get better understandings on
EWF of silver alloys, for both virgin and arced electrical contacts.