Abstract: The main purpose of this work was verify the
influence of the accelerated carbonation in the physical and
mechanical properties of the hybrid composites, reinforced with
micro and nanofibers and composites with microfibers. The
composites were produced by the slurry vacuum dewatering method,
followed by pressing. It was produced using two formulations: 8% of
eucalyptus pulp + 1% of the nanofibrillated cellulose and 9% of
eucalyptus pulp, both were subjected to accelerated carbonation. The
results showed that the accelerated carbonation contributed to
improve the physical and mechanical properties of the hybrid
composites and of the composites reinforced with microfibers
(eucalyptus pulp).
Abstract: In this paper, a coupled damage effect in the
instability of a composite rotor is presented, under dynamic loading
response in the harmonic analysis condition. The analysis of the
stress which operates the rotor is done. Calculations of different
energies and the virtual work of the aerodynamic loads from the rotor
blade are developed. The use of the composite material for the rotor
offers a good stability.
Numerical calculations on the model developed prove that the
damage effect has a negative effect on the stability of the rotor.
The study of the composite rotor in transient system allowed
determining the vibratory responses due to various excitations.
Abstract: Particles are the most common and cheapest
reinforcement producing discontinuous reinforced composites with
isotropic properties. Conventional fabrication methods can be used to
produce a wide range of product forms, making them relatively
inexpensive. Optimising composite development must include
consideration of all the fundamental aspect of particles including
their size, shape, volume fraction, distribution and mechanical
properties. Research has shown that the challenges of low fracture
toughness, poor crack growth resistance and low thermal stability can
be overcome by reinforcement with particles. The unique properties
exhibited by micro particles reinforced ceramic composites have
made them to be highly attractive in a vast array of applications.
Abstract: In this work, a polyaniline/Iron oxide (PANI/Fe2O3)
composite was chemically prepared by oxidative polymerization of
aniline in acid medium, in presence of ammonium persulphate as an
oxidant and amount of Fe2O3. The composite was characterized by a
scanning electron microscopy (SEM). The prepared composite has
been used as adsorbent to remove Tartrazine dye form aqueous
solutions.
The effects of initial dye concentration and temperature on the
adsorption capacity of PANI/Fe2O3 for Tartrazine dye have been
studied in this paper.
The Langmuir and Freundlich adsorption models have been used
for the mathematical description of adsorption equilibrium data. The
best fit is obtained using the Freundlich isotherm with an R2 value of
0.998. The change of Gibbs energy, enthalpy, and entropy of
adsorption has been also evaluated for the adsorption of Tartrazine
onto PANI/ Fe2O3. It has been proved according the results that the
adsorption process is endothermic in nature.
Abstract: This paper illustrates the effect of nano Magnesium
Hydroxide (MH) loading on the thermal properties of Low Density
Polyethylene (LDPE)/Poly (ethylene-co vinyl acetate) (EVA) nano
composite. Thermal studies were conducted, as it understanding is
vital for preliminary development of new polymeric systems.
Thermal analysis of nanocomposite was conducted using thermo
gravimetric analysis (TGA), and differential scanning calorimetry
(DSC). Major finding of TGA indicated two main stages of
degradation process found at (350 ± 25oC) and (480 ± 25oC)
respectively. Nano metal filler expressed better fire resistance as it
stand over high degree of temperature. Furthermore, DSC analysis
provided a stable glass temperature around 51 (±1oC) and captured
double melting point at 84 (±2oC) and 108 (±2oC). This binary
melting point reflects the modification of nano filler to the polymer
matrix forming melting crystals of folded and extended chain. The
percent crystallinity of the samples grew vividly with increasing filler
content. Overall, increasing the filler loading improved the
degradation temperature and weight loss evidently and a better
process and phase stability was captured in DSC.
Abstract: Aluminum hybrid reinforcement technology is a
response to the dynamic ever increasing service requirements of such
industries as transportation, aerospace, automobile, marine, etc. It is
unique in that it offers a platform of almost unending combinations of
materials to produce various hybrid composites. This article reviews
the studies carried out on various combinations of aluminum hybrid
composite and the effects on mechanical, physical and chemical
properties. It is observed that the extent of enhancement of these
properties of hybrid composites is strongly dependent on the nature
of the reinforcement, its hardness, particle size, volume fraction,
uniformity of dispersion within the matrix and the method of hybrid
production.
Abstract: The influence of three different types of halloysite
nanotubes (HNTs) with different dimensions, namely as camel lake
(CLA), Jarrahdale (JA) and Matauri Bay (MB), on their reinforcing
ability of ethylene propylene dine monomer (EPDM) were
investigated by varying the HNTs loading (from 0-15 phr).
Mechanical properties of the nanocomposites improved with addition
of all three HNTs, but CLA based nanocomposites exhibited a
significant enhancement compared to the other HNTs. For instance,
tensile properties of EPDM nanocomposites increased by 120%,
256% and 340% for MB, JA and CLA, respectively, with addition of
15 phr of HNTs. This could be due to the higher aspect ratio and
higher surface area of CLA compared to others. Scanning electron
microscopy (SEM) of nanocomposites at 15 phr of HNT loadings
showed low amounts of pulled-out nanotubes which confirmed the
presence of more embedded nanotubes inside the EPDM matrix, as
well as aggregates within the fracture surface of EPDM/HNT
nanocomposites
Abstract: Two micromechanical models for 3D smart composite
with embedded periodic or nearly periodic network of generally
orthotropic reinforcements and actuators are developed and applied to
cubic structures with unidirectional orientation of constituents.
Analytical formulas for the effective piezothermoelastic coefficients
are derived using the Asymptotic Homogenization Method (AHM).
Finite Element Analysis (FEA) is subsequently developed and used
to examine the aforementioned periodic 3D network reinforced smart
structures. The deformation responses from the FE simulations are
used to extract effective coefficients. The results from both
techniques are compared. This work considers piezoelectric materials
that respond linearly to changes in electric field, electric
displacement, mechanical stress and strain and thermal effects. This
combination of electric fields and thermo-mechanical response in
smart composite structures is characterized by piezoelectric and
thermal expansion coefficients. The problem is represented by unitcell
and the models are developed using the AHM and the FEA to
determine the effective piezoelectric and thermal expansion
coefficients. Each unit cell contains a number of orthotropic
inclusions in the form of structural reinforcements and actuators.
Using matrix representation of the coupled response of the unit cell,
the effective piezoelectric and thermal expansion coefficients are
calculated and compared with results of the asymptotic
homogenization method. A very good agreement is shown between
these two approaches.
Abstract: The purpose of this study was to investigate
perceptions of climate change risk to forest ecosystems and forestbased
communities as well as perceived effectiveness of adaptation
strategies for climate change as well as challenges for adaptation.
Data was gathered using a pre-tested semi-structured questionnaire.
Simple random selection technique was applied. For the majority of
issues, the responses were obtained on multi-point likert scales, and
the scores provided were, in turn, used to estimate the means and
other useful estimates. A composite knowledge index developed
using correct responses to a set of self-rated statements were used to
evaluate the issues. The mean of the knowledge index was 0.64. Also
all respondents recorded values of the knowledge index above 0.25.
Increase forest fire was perceived by respondents as the greatest risk
to forest eco-system. Decrease access to water supplies was perceived
as the greatest risk to livelihoods of forest based communities. The
most effective adaptation strategy relevant to climate change risks to
forest eco-systems and forest based communities livelihoods in
Kathmandu valley in Nepal as perceived by the respondents was
reforestation and afforestation. As well, lack of public awareness was
perceived as the major limitation for climate change adaptation.
However, perceived risks as well as effective adaptation strategies
showed an inconsistent association with knowledge indicators and
social-cultural variables. The results provide useful information to
any party who involve with climate change issues in Nepal, since
such attempts would be more effective once the people’s perceptions
on these aspects are taken into account.
Abstract: Composites depending on the nature of their
constituents and mode of production are regarded as one of the
advanced materials that drive today’s technology. This paper
attempts a short review of the subject matter with a general aim of
pushing to the next level the frontier of knowledge as it impacts the
technology of nano-particles manufacturing. The objectives entail an
effort to; aggregate recent research efforts in this field, analyse
research findings and observations, streamline research efforts and
support industry in taking decision on areas of fund deployment. It is
envisaged that this work will serve as a quick hand-on compendium
material for researchers in this field and a guide to relevant
government departments wishing to fund a research whose outcomes
have the potential of improving the nation’s GDP.
Abstract: A series of polystyrene (PS) nanoparticles were
prepared by grafting polystyrene from both aggregated silica and
colloidally dispersed silica nanoparticles using atom-transfer radical
polymerisation (ATRP). Cross-linking and macroscopic gelation
were minimised by using a miniemulsion system. The thermal and
mechanical behaviour of the nanocomposites have been examined by
differential scanning calorimetry (DSC) and dynamic mechanical
thermal analysis (DMTA).
Abstract: Paper presents a study about dynamic effects obtained
from the dynamic load testing of the city highway bridges in Latvia
carried out from 2005 to 2012. 9 prestressed concrete bridges and 4
composite bridges were considered. 11 of 13 bridges were designed
according to the Eurocodes but two according to the previous
structural codes used in Latvia (SNIP 2.05.03-84). The dynamic
properties of the bridges were obtained by heavy vehicle passing the
bridge roadway with different driving speeds and with or without
even pavement. The obtained values of the Dynamic amplification
factor (DAF) and the bridge natural frequency were analyzed and
compared to the values of built-in traffic load models provided in
Eurocode 1. The actual DAF values for even bridge pavement in the
most cases are smaller than the value adopted in Eurocode 1. Vehicle
speed for uneven pavements significantly influence Dynamic
amplification factor values.
Abstract: In the present work, the finite element formulation for
the investigation of the effects of a localized interfacial degeneration
on the dynamic behavior of the [90°/0°] laminated composite plate
employing the state-space technique is performed. The stiffness of
the laminate is determined by assembling the stiffnesses of subelements.
This includes an introduction of an interface layer adopting
the virtually zero-thickness formulation to model the interfacial
degeneration. Also, the kinematically consistent mass matrix and
proportional damping have been formulated to complete the free
vibration governing expression. To simulate the interfacial
degeneration of the laminate, the degenerated areas are defined from
the center propagating outwards in a localized manner. It is found
that the natural frequency, damped frequency and damping ratio of
the plate decreases as the degenerated area of the interface increases.
On the contrary, the loss factor increases correspondingly.
Abstract: This paper presents the electromagnetic interference
(EMI) shielding effectiveness of rice husk and carbon nanotubes
(RHCNTs) composites in the X-band region (8.2-12.4 GHz). The
difference weight ratio of carbon nanotubes (CNTs) were mix with
the rice husk. The rectangular waveguide technique was used to
measure the complex permittivity of the RHCNTs composites
materials. The complex permittivity is represented in terms of both
the real and imaginary parts of permittivity in X-band frequency. The
conductivity of RHCNTs shows increasing when the ratio of CNTs
mixture increases. The composites materials were simulated using
Computer Simulation Technology (CST) Microwave Studio
simulation software. The shielding effectiveness of RHCNTs and
pure rice husk was compared. The highest EMI SE of 30 dB is
obtained for RHCNTs composites of 10 wt % CNTs with 10mm
thickness.
Abstract: In structures, stress concentration is a factor of fatigue
fracture. Basically, the stress concentration is a phenomenon that
should be avoided. However, it is difficult to avoid the stress
concentration. Therefore, relaxation of the stress concentration is
important. The stress concentration arises from notches and circular
holes. There is a relaxation method that a composite patch covers a
notch and a circular hole. This relaxation method is used to repair
aerial wings, but it is not systematized. Composites are more
expensive than single materials. Accordingly, we propose the
relaxation method that a single material patch covers a notch and a
circular hole, and aim to systematize this relaxation method.
We performed FEA (Finite Element Analysis) about an object by
using a three-dimensional FEA model. The object was that a patch
adheres to a plate with a circular hole. And, a uniaxial tensile load acts
on the patched plate with a circular hole. In the three-dimensional FEA
model, it is not easy to model the adhesion layer. Basically, the yield
stress of the adhesive is smaller than that of adherents. Accordingly,
the adhesion layer gets to plastic deformation earlier than the adherents
under the yield load of adherents. Therefore, we propose the
three-dimensional FEA model which is applied a nonlinear elastic
region to the adhesion layer. The nonlinear elastic region was
calculated by a bilinear approximation. We compared the analysis
results with the tensile test results to confirm whether the analysis
model has usefulness. As a result, the analysis results agreed with the
tensile test results. And, we confirmed that the analysis model has
usefulness.
As a result that the three-dimensional FEA model was used to the
analysis, it was confirmed that an out-of-plane deformation occurred
to the patched plate with a circular hole. The out-of-plane deformation
causes stress increase of the patched plate with a circular hole.
Therefore, we investigated that the out-of-plane deformation affects
relaxation of the stress concentration in the plate with a circular hole
on this relaxation method. As a result, it was confirmed that the
out-of-plane deformation inhibits relaxation of the stress concentration
on the plate with a circular hole.
Abstract: Nonstandard tests are necessary for analyses and
verification of new developed structural and technological solutions
with application of composite materials. One of the most critical
primary structural parts of a typical aerospace structure is T-joint.
This structural element is loaded mainly in shear, bending, peel and
tension. The paper is focused on the shear loading simulations. The
aim of the work is to obtain a representative uniform distribution of
shear loads along T-joint during the mechanical testing. A new
design of T-joint test procedure, numerical simulation and
optimization of representative boundary conditions are presented.
The different conditions and inaccuracies both in simulations and
experiments are discussed. The influence of different parameters on
stress and strain distributions is demonstrated on T-joint made of
CFRP (carbon fibre reinforced plastic). A special test rig designed by
VZLU (Aerospace Research and Test Establishment) for T-shear test
procedure is presented.
Abstract: Theoretical optimization of a copper-water negative
inclination heat pipe with internal composite wick structure had been
performed, regarding a new introduced parameter: the ratio between
the coarse mesh wraps and the fine mesh wraps of the composite
wick. Since in many cases, the design of a heat pipe matches specific
thermal requirements and physical limitations, this work
demonstrates the optimization of a 1m length, 8mm internal diameter
heat pipe without an adiabatic section, at a negative inclination angle
of -10º. The optimization is based on a new introduced parameter, LR:
the ratio between the coarse mesh wraps and the fine mesh wraps.
Abstract: Polyethylene (PE), Polypropylene (PP), Polyethylene
(vinyl acetate) (EVA) and PE-ionomer nanocomposite samples were
prepared by mixing of the polymer with organofilized
montmorillonite fillers Cloisite 93A and Dellite 67G. The amount of
each modified montmorillonite (MMT) was fixed to 5% (w/w). The
twin-screw kneader was used for the compounding of polymer matrix
and chosen nanofillers. The level of MMT exfoliation was studied by
the transmission electron microscopy (TEM) observations. The
mechanical properties of prepared materials were evaluated by
dynamical mechanical analysis at 30°C and by the measurement of
tensile properties (stress and strain at break).
Abstract: The paper deals with current issues in research of
advanced methods to increase reliability of traditional timber
structural elements. It analyses the issue of strengthening of bent
timber beams, such as ceiling beams in old (historical) buildings with
additional concrete slab in combination with externally bonded fibre -
reinforced polymer. The paper describes experimental testing of
composite timber-concrete beam with FRP reinforcement and
compares results with FEM analysis.
Abstract: This article presents summary on preparation and
characterization of zinc, copper, cadmium and cobalt chromite
nanocrystals, embedded in an amorphous silica matrix. The
ZnCr2O4/SiO2, CuCr2O4/SiO2, CdCr2O4/SiO2 and CoCr2O4/SiO2
nanocomposites were prepared by a conventional sol-gel method
under acid catalysis. Final heat treatment of the samples was carried
out at temperatures in the range of 900−1200 ◦C to adjust the
phase composition and the crystallite size, respectively. The resulting
samples were characterized by Powder X-ray diffraction (PXRD),
High Resolution Transmission Electron Microscopy (HRTEM),
Raman/FTIR spectroscopy and magnetic measurements. Formation
of the spinel phase was confirmed in all samples. The average size of
the nanocrystals was determined from the PXRD data and by direct
particle size observation on HRTEM; both results were correlated.
The mean particle size (reviewed by HRTEM) was in the range from
∼4 to 46 nm. The results showed that the sol-gel method can be
effectively used for preparation of the spinel chromite nanoparticles
embedded in the silica matrix and the particle size is driven by the
type of the cation A2+ in the spinel structure and the temperature
of the final heat treatment. Magnetic properties of the nanocrystals
were found to be just moderately modified in comparison to the bulk
phases.