Removal of Tartrazine Dye form Aqueous Solutions by Adsorption on the Surface of Polyaniline/Iron Oxide Composite
In this work, a polyaniline/Iron oxide (PANI/Fe2O3)
composite was chemically prepared by oxidative polymerization of
aniline in acid medium, in presence of ammonium persulphate as an
oxidant and amount of Fe2O3. The composite was characterized by a
scanning electron microscopy (SEM). The prepared composite has
been used as adsorbent to remove Tartrazine dye form aqueous
solutions.
The effects of initial dye concentration and temperature on the
adsorption capacity of PANI/Fe2O3 for Tartrazine dye have been
studied in this paper.
The Langmuir and Freundlich adsorption models have been used
for the mathematical description of adsorption equilibrium data. The
best fit is obtained using the Freundlich isotherm with an R2 value of
0.998. The change of Gibbs energy, enthalpy, and entropy of
adsorption has been also evaluated for the adsorption of Tartrazine
onto PANI/ Fe2O3. It has been proved according the results that the
adsorption process is endothermic in nature.
[1] J. Huang, S Virji, R. B. Kaner." Polyaniline nanofibers facile synthesis
and Chemical sensors”. J. Am chem Soc, vol.125, pp. 314-5, 2003.
[2] A. Gemeay, I. Mansour, R. G. “ El-Sharkawy, A. B Zaki, Catalytic
activity of polyaniline/MO2 Composites towords the oxidative
decolorization of organic dyes ”, j,applied Catalysis, vol. 80, PP. 106-
15, 2008.
[3] D. Sazou, kourouzidou, E. pavlidou, “potentodynamic and potentiostatic
deposition of polyaniline onstainless steel : electrochemical and
structural studies for a potential application to corrosion control
Electrochim”. Acta, vol. 13, PP. 4385-97, 2007.
[4] J.L.Camalet, J.C Lacroix, S.Aeiyach, Chane-ching, K, P.C. Lacaze,
“Electrosynthesis of adherent polyaniline films on iron and mild steel in
aqueous oxalic acid medium”, Synth. Met.,vol.93,pp 133–142 1998.
[5] M. Debajyoti, M.G. irdhar, S. Radhakrishnan, and P. Satish,
“Adsorpation of Sulfonated Dyes by poly anilnie Emeradine Salt and Its
Kinetes”, J. Phys.Chem, vol.112,PP. 10153- 10157, 2008.
[6] J. Molina, A. I. del Rio, J.Bonastre, F. Cases. “Electrochemical
polymerization of aniline on Conducting textiles of polyester covered
with polypyrrole/AQA” J.Europen polymer, PP 11-003, 2008.
[7] K. arthikeyan, M.. Kumar, K. K. S.; Elango, K. P. “Conducting polymer/
alumina composites as viable adsorbents for the removal of fluoride ions
from aqueous solution”. J. Fluorine Chem vol, 130,PP, 894–901 2009.
[8] A. Mohamed, Salem, F.Ahmed, Al-Ghonemiy, Ahmed B. Zaki.
“photocatalytic degradation of Allura red Quinoline yellow with
polyaniline/ TiO2 nanoComposite”, J applied Catalysis B,
Environmental, vol, 91,PP. 59-66, 2009.
[9] A. Gemeay, I. A. Mansour, R., G. El-Sharkawy, A. B Zaki, “preparation
and Characterization of polyaniline/ manganese dioxide Composites and
their Catalytic activity”, J. Collod Interface-Sci. 308,PP. 385-394,2007.
[10] S. Sathianaryanan, S. Syed Azim, G. Ve. Katachaxi, “preparation and
Characterization of polyaniline/ manganese dioxide Composites and its
anticorrsion performance”J. Synthetic Metals,,157, PP.751 – 757, 2007.
[11] S. Seshadri, Bishop, P. L.; Agha, A. M. “Anaerobic/aerobic treatment of
selected azo dyes in wastewater”. Waste Manage. vol 15,PP 127–
137,1994.
[12] G.Renmin, S. Yingzhi, C; Huijun, L.; Chao, Y. “Effect of chemical
modification on dye adsorption capacity of peanut hull”. Dyes Pigm.vol,
67, PP. 175–181, 2005.
[13] Z. Aksu, Z.; Tezer, S. “Equilibrium and kinetics modeling of biosorption
of remazol black B by rhizopus arrhizus in a batch system: effect of
Temperature”, Process Biochem,vol, 36, PP. 431–439,2000.
[14] G. Walker,. M.; Hansen, L.; Hana, J. A.; Allen, S. “Kinetics of a reactive
dye adsorption onto dolomite sorbent ”. J, Water Res., vol37, PP. 2081–
2089, 2003.
[15] M. Karthikeyan, Kumar, K.. S.; Elango, K. P. “Conducting polymer/
alumina composites as viable ions from aqueous solution adsorbents for
the removal of fluoride”. J. Fluorine Chem. vol 130, PP.894–901, 2009.
[16] P. S Kumar, S. Ramalingam, C. Senthamarai, M.Niranjanaa, P
Vijayalakshmi, et al. “ Adsorption of dye from aqueous solution by
cashew nut shell: Studies on equilibrium isotherm kinetics and
thermodynamics of interactions ”. Desalination, PP. 261: 52-60, 2010.
[17] H. Freundlich, Over the adsorption in solution. Z Phys Chem A 57,
1906, PP.385-470.
[18] N.K Amin “Removal of direct blue-106 dye from aqueous solution using
new activated carbons developed from pomegranate peel: adsorption
equilibrium and kinetics”. J,Hazard Mater, vol 165: pp 52-62,2009.
[19] I. Langmuir “The adsorption of gases on plane surfaces of glass, mica
and platinum. ”, J Am Chem Soc, vol 40, PP 1361-1403,1918
[20] M. A. Salem “ the role of polyaniline salts in the removal of direct blue
78 from aqueous solution A kinetic study”, J.Reaactive & Functional
polymers,vol 70, pp707-714, 2010.
[21] C.L.Mack, B,Wilhelmi,J.R. Duncan, J.E.Burgess, “ Akinetic study of the
recovery of platinum ions from an artifical aqueous solution by
immobilized Saccharomyces biomass ”, Minerals Eng, vol 21, pp 31-37,
2008.
[22] S.V. Mohan, Rajkumar, P.N.Sarma, “Removal of Fluoride form aqueous
phase by biosorpation onto algal biosorbent spirogyra sp-102; sorption
mechanism elucidation”, Hazard. Mater,vol 141,pp 465-474, 2007
[1] J. Huang, S Virji, R. B. Kaner." Polyaniline nanofibers facile synthesis
and Chemical sensors”. J. Am chem Soc, vol.125, pp. 314-5, 2003.
[2] A. Gemeay, I. Mansour, R. G. “ El-Sharkawy, A. B Zaki, Catalytic
activity of polyaniline/MO2 Composites towords the oxidative
decolorization of organic dyes ”, j,applied Catalysis, vol. 80, PP. 106-
15, 2008.
[3] D. Sazou, kourouzidou, E. pavlidou, “potentodynamic and potentiostatic
deposition of polyaniline onstainless steel : electrochemical and
structural studies for a potential application to corrosion control
Electrochim”. Acta, vol. 13, PP. 4385-97, 2007.
[4] J.L.Camalet, J.C Lacroix, S.Aeiyach, Chane-ching, K, P.C. Lacaze,
“Electrosynthesis of adherent polyaniline films on iron and mild steel in
aqueous oxalic acid medium”, Synth. Met.,vol.93,pp 133–142 1998.
[5] M. Debajyoti, M.G. irdhar, S. Radhakrishnan, and P. Satish,
“Adsorpation of Sulfonated Dyes by poly anilnie Emeradine Salt and Its
Kinetes”, J. Phys.Chem, vol.112,PP. 10153- 10157, 2008.
[6] J. Molina, A. I. del Rio, J.Bonastre, F. Cases. “Electrochemical
polymerization of aniline on Conducting textiles of polyester covered
with polypyrrole/AQA” J.Europen polymer, PP 11-003, 2008.
[7] K. arthikeyan, M.. Kumar, K. K. S.; Elango, K. P. “Conducting polymer/
alumina composites as viable adsorbents for the removal of fluoride ions
from aqueous solution”. J. Fluorine Chem vol, 130,PP, 894–901 2009.
[8] A. Mohamed, Salem, F.Ahmed, Al-Ghonemiy, Ahmed B. Zaki.
“photocatalytic degradation of Allura red Quinoline yellow with
polyaniline/ TiO2 nanoComposite”, J applied Catalysis B,
Environmental, vol, 91,PP. 59-66, 2009.
[9] A. Gemeay, I. A. Mansour, R., G. El-Sharkawy, A. B Zaki, “preparation
and Characterization of polyaniline/ manganese dioxide Composites and
their Catalytic activity”, J. Collod Interface-Sci. 308,PP. 385-394,2007.
[10] S. Sathianaryanan, S. Syed Azim, G. Ve. Katachaxi, “preparation and
Characterization of polyaniline/ manganese dioxide Composites and its
anticorrsion performance”J. Synthetic Metals,,157, PP.751 – 757, 2007.
[11] S. Seshadri, Bishop, P. L.; Agha, A. M. “Anaerobic/aerobic treatment of
selected azo dyes in wastewater”. Waste Manage. vol 15,PP 127–
137,1994.
[12] G.Renmin, S. Yingzhi, C; Huijun, L.; Chao, Y. “Effect of chemical
modification on dye adsorption capacity of peanut hull”. Dyes Pigm.vol,
67, PP. 175–181, 2005.
[13] Z. Aksu, Z.; Tezer, S. “Equilibrium and kinetics modeling of biosorption
of remazol black B by rhizopus arrhizus in a batch system: effect of
Temperature”, Process Biochem,vol, 36, PP. 431–439,2000.
[14] G. Walker,. M.; Hansen, L.; Hana, J. A.; Allen, S. “Kinetics of a reactive
dye adsorption onto dolomite sorbent ”. J, Water Res., vol37, PP. 2081–
2089, 2003.
[15] M. Karthikeyan, Kumar, K.. S.; Elango, K. P. “Conducting polymer/
alumina composites as viable ions from aqueous solution adsorbents for
the removal of fluoride”. J. Fluorine Chem. vol 130, PP.894–901, 2009.
[16] P. S Kumar, S. Ramalingam, C. Senthamarai, M.Niranjanaa, P
Vijayalakshmi, et al. “ Adsorption of dye from aqueous solution by
cashew nut shell: Studies on equilibrium isotherm kinetics and
thermodynamics of interactions ”. Desalination, PP. 261: 52-60, 2010.
[17] H. Freundlich, Over the adsorption in solution. Z Phys Chem A 57,
1906, PP.385-470.
[18] N.K Amin “Removal of direct blue-106 dye from aqueous solution using
new activated carbons developed from pomegranate peel: adsorption
equilibrium and kinetics”. J,Hazard Mater, vol 165: pp 52-62,2009.
[19] I. Langmuir “The adsorption of gases on plane surfaces of glass, mica
and platinum. ”, J Am Chem Soc, vol 40, PP 1361-1403,1918
[20] M. A. Salem “ the role of polyaniline salts in the removal of direct blue
78 from aqueous solution A kinetic study”, J.Reaactive & Functional
polymers,vol 70, pp707-714, 2010.
[21] C.L.Mack, B,Wilhelmi,J.R. Duncan, J.E.Burgess, “ Akinetic study of the
recovery of platinum ions from an artifical aqueous solution by
immobilized Saccharomyces biomass ”, Minerals Eng, vol 21, pp 31-37,
2008.
[22] S.V. Mohan, Rajkumar, P.N.Sarma, “Removal of Fluoride form aqueous
phase by biosorpation onto algal biosorbent spirogyra sp-102; sorption
mechanism elucidation”, Hazard. Mater,vol 141,pp 465-474, 2007
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:68602", author = "Salem Ali Jebreil", title = "Removal of Tartrazine Dye form Aqueous Solutions by Adsorption on the Surface of Polyaniline/Iron Oxide Composite", abstract = "In this work, a polyaniline/Iron oxide (PANI/Fe2O3)
composite was chemically prepared by oxidative polymerization of
aniline in acid medium, in presence of ammonium persulphate as an
oxidant and amount of Fe2O3. The composite was characterized by a
scanning electron microscopy (SEM). The prepared composite has
been used as adsorbent to remove Tartrazine dye form aqueous
solutions.
The effects of initial dye concentration and temperature on the
adsorption capacity of PANI/Fe2O3 for Tartrazine dye have been
studied in this paper.
The Langmuir and Freundlich adsorption models have been used
for the mathematical description of adsorption equilibrium data. The
best fit is obtained using the Freundlich isotherm with an R2 value of
0.998. The change of Gibbs energy, enthalpy, and entropy of
adsorption has been also evaluated for the adsorption of Tartrazine
onto PANI/ Fe2O3. It has been proved according the results that the
adsorption process is endothermic in nature.
", keywords = "Adsorption, Composite, dye, Polyaniline, Tartrazine.", volume = "8", number = "12", pages = "1433-6", }
