Abstract: This paper aims to study the effect of cold work
condition on the microstructure of Cu-1.5wt%Ti, and Cu-3.5wt%Ti
and hence mechanical properties. The samples under investigation
were machined, and solution heat treated. X-ray diffraction technique
is used to identify the different phases present after cold deformation
by compression and also different heat treatment and also measuring
the relative quantities of phases present. The metallographic
examination is used to study the microstructure of the samples. The
hardness measurements were used to indicate the change in
mechanical properties. The results are compared with the mechanical
properties obtained by previous workers. Experiments on cold
compression followed by aging of Cu-Ti alloys have indicated that
the most efficient hardening of the material results from continuous
precipitation of very fine particles within the matrix. These particles
were reported to be β`-type, Cu4Ti phase. The β`-β transformation
and particles coarsening within the matrix as well as long grain
boundaries were responsible for the overaging of Cu-1.5wt%Ti and
Cu-3.5wt%Ti alloys. It is well known that plate-like particles are β –
type, Cu3Ti phase. Discontinuous precipitation was found to start at
the grain boundaries and expand into grain interior. At the higher
aging temperature, a classic Widmanstätten morphology forms giving
rise to a coarse microstructure comprised of α and the equilibrium
phase β. Those results were confirmed by X-ray analysis, which
found that a few percent of Cu3Ti, β precipitates are formed during
aging at high temperature for long time for both Cu- Ti alloys (i.e.
Cu-1.5wt%Ti and Cu-3.5wt%Ti).
Abstract: In this work new macroporous Ni electrodes modified
with Au nanoparticles for hydrogen production have been developed.
The supporting macroporous Ni electrodes have been obtained by
means of the electrodeposition at high current densities. Then, the Au
nanoparticles were synthesized and added to the electrode surface.
The electrocatalytic behaviour of the developed electrocatalysts was
studied by means of pseudo-steady-state polarization curves,
electrochemical impedance spectroscopy (EIS) and hydrogen
discharge curves. The size of the Au synthetized nanoparticles shows
a monomodal distribution, with a very sharp band between 10 and 50
nm. The characteristic parameters d10, d50 and d90 were 14, 20 and
31 nm respectively. From Tafel polarization data has been concluded
that the Au nanoparticles improve the catalytic activity of the
developed electrodes towards the HER respect to the macroporous Ni
electrodes. EIS permits to obtain the electrochemically active area by
means of the roughness factor value. All the developed electrodes
show roughness factor values in the same order of magnitude. From
the activation energy results it can be concluded that the Au
nanoparticles improve the intrinsic catalytic activity of the
macroporous Ni electrodes.
Abstract: It is an established fact that polymers have several
physical limitations such as low stiffness and low resistance to
impact on loading. Hence, polymers do not usually have requisite
mechanical strength for application in various fields. The
reinforcement by high strength fibers provides the polymer
substantially enhanced mechanical properties and makes them more
suitable for a large number of diverse applications. This research
evaluates the effects of particulate Cow bone and Groundnut shell
additions on the mechanical properties and microstructure of cow
bone and groundnut shell reinforced epoxy composite in order to
assess the possibility of using it as a material for engineering
applications. Cow bone and groundnut shell particles reinforced with
epoxy (CBRPC and GSRPC) was prepared by varying the cow bone
and groundnut shell particles from 0-25 wt% with 5 wt% intervals. A
Hybrid of the Cow bone and Groundnut shell (HGSCB) reinforce
with epoxy was also prepared. The mechanical properties of the
developed composites were investigated. Optical microscopy was
used to examine the microstructure of the composites. The results
revealed that mechanical properties did not increase uniformly with
additions in filler but exhibited maximum properties at specific
percentages of filler additions. From the Microscopic evaluation, it
was discovered that homogeneity decreases with increase in % filler,
this could be due to poor interfacial bonding.
Abstract: Fibre cement plates, often used in construction,
generally are made using quartz as an inert material, cement as a
binder and cellulose as a fibre. This paper, first of all, investigates the
mechanical properties and durability of fibre cement plates when
quartz is both partly and fully replaced with diatomite. Diatomite
does not only have lower density compared to quartz but also has
high pozzolanic activity. The main objective of this paper is the
investigation of the effects of supplementary cementing materials
(SCMs) on the short and long term mechanical properties and
durability characteristics of fibre cement plates prepared using
diatomite. Supplementary cementing materials such as ground
granulated blast furnace slug (GGBS) and fly ash (FA) are used in
this study. Volume proportions of 10, 20, 30 and 40% of GGBS and
FA are used as partial replacement materials to cement. Short and
long term mechanical properties such as compressive and flexural
strengths as well as sorptivity characteristics and mass were
investigated. Consistency and setting time at each replacement levels
of SCMs were also recorded. The effects of using supplementary
cementing materials on the carbonation and sulphate resistance of
fibre cement plates were then experimented. The results, first of all,
show that the use of diatomite as a full or partial replacement to
quartz resulted in a systematic decrease in total mass of the fibre
cement plates. The reduction of mass was largely due to the lower
density and finer particle size of diatomite compared to quartz. The
use of diatomite did not only reduce the mass of these plates but also
increased the compressive strength significantly as a result of its high
pozzolanic activity. The replacement levels of both GGBS and FA
resulted in a systematic decrease in short term compressive strength
with increasing replacement levels. This was essentially expected as
the total rate of hydration is much lower in GGBS and FA than that
of cement. Long term results however, indicated that the compressive
strength of fibre cement plates prepared using both GGBS and FA
increases with time and hence the compressive strength of plates
prepared using SCMs is either equivalent or more than the
compressive strength of plates prepared using cement alone.
Durability characteristics of fibre cement plates prepared using SCMs
were enhanced significantly. Measurements of sopritivty
characteristics were also indicated that the plates prepared using
SCMs has much lower water absorption capacities compared to
plates prepared cement alone. Much higher resistance to carbonation
and sulphate attach were observed with plates prepared using SCMs.
The results presented in this paper show that the use of SCMs does
not only support the production of more sustainable construction
materials but also enhances the mechanical properties and durability
characteristics of fibre cement plates.
Abstract: This paper presents the performance of Integrated
Bacterial Foraging Optimization and Particle Swarm Optimization
(IBFO_PSO) technique in MANET routing. The BFO is a bio-inspired
algorithm, which simulates the foraging behavior of bacteria.
It is effectively applied in improving the routing performance in
MANET. In results, it is proved that the PSO integrated with BFO
reduces routing delay, energy consumption and communication
overhead.
Abstract: This study, for its research subjects, uses patients who
had undergone total knee replacement surgery from the database of the
National Health Insurance Administration. Through the review of
literatures and the interviews with physicians, important factors are
selected after careful screening. Then using Cross Entropy Method,
Genetic Algorithm Logistic Regression, and Particle Swarm
Optimization, the weight of each factor is calculated and obtained. In
the meantime, Excel VBA and Case Based Reasoning are combined
and adopted to evaluate the system. Results show no significant
difference found through Genetic Algorithm Logistic Regression and
Particle Swarm Optimization with over 97% accuracy in both
methods. Both ROC areas are above 0.87. This study can provide
critical reference to medical personnel as clinical assessment to
effectively enhance medical care quality and efficiency, prevent
unnecessary waste, and provide practical advantages to resource
allocation to medical institutes.
Abstract: In recent years a new method of combination
treatment for cancer has been developed and studied that has led to
significant advancements in the field of cancer therapy. Hyperthermia
is a traditional therapy that, along with a creation of a medically
approved level of heat with the help of an alternating magnetic AC
current, results in the destruction of cancer cells by heat. This paper
gives details regarding the production of the spherical nanocomposite
PVA/γ-Fe2O3 in order to be used for medical purposes such as tumor
treatment by hyperthermia. To reach a suitable and evenly distributed
temperature, the nanocomposite with core-shell morphology and
spherical form within a 100 to 200 nanometer size was created using
phase separation emulsion, in which the magnetic nano-particles γ-
Fe2O3 with an average particle size of 20 nano-meters and with
different percentages of 0.2, 0.4, 0.5 and 0.6 were covered by
polyvinyl alcohol. The main concern in hyperthermia and heat
treatment is achieving desirable specific absorption rate (SAR) and
one of the most critical factors in SAR is particle size. In this project
all attempts has been done to reach minimal size and consequently
maximum SAR. The morphological analysis of the spherical
structure of the nanocomposite PVA/γ-Fe2O3 was achieved by SEM
analyses and the study of the chemical bonds created was made
possible by FTIR analysis. To investigate the manner of magnetic
nanocomposite particle size distribution a DLS experiment was
conducted. Moreover, to determine the magnetic behavior of the γ-
Fe2O3 particle and the nanocomposite PVA/γ-Fe2O3 in different
concentrations a VSM test was conducted. To sum up, creating
magnetic nanocomposites with a spherical morphology that would be
employed for drug loading opens doors to new approaches in
developing nanocomposites that provide efficient heat and a
controlled release of drug simultaneously inside the magnetic field,
which are among their positive characteristics that could significantly
improve the recovery process in patients.
Abstract: Radial profiles of particle velocities were investigated
in a 6.1m high methanol-to-olefins cold model experimental device
using a TSI laser Doppler velocimeter. The effect of axial height on
flow development was not obvious in fully developed region under the
same operating condition. Superficial gas velocity and solid
circulating rate had significant influence on particle velocity in the
center region of the riser. Besides, comparisons among rising,
descending and average particle velocity were conducted. The particle
average velocity was similar to the rising particle velocity and higher
than the descending particle velocity in radial locations except the wall
region of riser.
Abstract: Tuberculosis (TB) remains a leading cause of
infectious mortality. It is primarily transmitted by the respiratory
route, individuals with active disease may infect others through
airborne particles which releases when they cough, talk, or sing and
subsequently inhale by others. In order to study the effect of the
Bacilli Calmette-Guerin (BCG) vaccine after vaccination of TB
patient, a Vaccinated Susceptible Infected and Recovered (VSIR)
mathematical model is being developed to achieve the desired
objectives. The mathematical model, so developed, shall be used to
quantify the effect of BCG Vaccine to protect the immigrant young
adult person. Moreover, equations are to be established for the
disease endemic and free equilibrium states and subsequently utilized
in disease stability analysis. The stability analysis will give a
complete picture of disease annihilation from the total population if
the total removal rate from the infectious group should be greater
than total number of dormant infections produced throughout
infectious period.
Abstract: This paper proposed the comparison made between
Multi-Carrier Pulse Width Modulation, Sinusoidal Pulse Width
Modulation and Selective Harmonic Elimination Pulse Width
Modulation technique for minimization of Total Harmonic Distortion
in Cascaded H-Bridge Multi-Level Inverter. In Multicarrier Pulse
Width Modulation method by using Alternate Position of Disposition
scheme for switching pulse generation to Multi-Level Inverter.
Another carrier based approach; Sinusoidal Pulse Width Modulation
method is also implemented to define the switching pulse generation
system in the multi-level inverter. In Selective Harmonic Elimination
method using Genetic Algorithm and Particle Swarm Optimization
algorithm for define the required switching angles to eliminate low
order harmonics from the inverter output voltage waveform and
reduce the total harmonic distortion value. So, the results validate that
the Selective Harmonic Elimination Pulse Width Modulation method
does capably eliminate a great number of precise harmonics and
minimize the Total Harmonic Distortion value in output voltage
waveform in compared with Multi-Carrier Pulse Width Modulation
method, Sinusoidal Pulse Width Modulation method. In this paper,
comparison of simulation results shows that the Selective Harmonic
Elimination method can attain optimal harmonic minimization
solution better than Multi-Carrier Pulse Width Modulation method,
Sinusoidal Pulse Width Modulation method.
Abstract: This paper represents the results of experimental work to investigate the suitability of a waste material (WM) for soft soil stabilisation. In addition, the effect of particle size distribution (PSD) of the waste material on its performance as a soil stabiliser was investigated. The WM used in this study is produced from the incineration processes in domestic energy power plant and it is available in two different grades of fineness (coarse waste material (CWM) and fine waste material (FWM)). An intermediate plasticity silty clayey soil with medium organic matter content has been used in this study. The suitability of the CWM and FWM to improve the physical and engineering properties of the selected soil was evaluated dependant on the results obtained from the consistency limits, compaction characteristics (optimum moisture content (OMC) and maximum dry density (MDD)); along with the unconfined compressive strength test (UCS). Different percentages of CWM were added to the soft soil (3, 6, 9, 12 and 15%) to produce various admixtures. Then the UCS test was carried out on specimens under different curing periods (zero, 7, 14, and 28 days) to find the optimum percentage of CWM. The optimum and other two percentages (either side of the optimum content) were used for FWM to evaluate the effect of the fineness of the WM on UCS of the stabilised soil. Results indicated that both types of the WM used in this study improved the physical properties of the soft soil where the index of plasticity (IP) was decreased significantly. IP was decreased from 21 to 13.64 and 13.10 with 12% of CWM and 15% of FWM respectively. The results of the unconfined compressive strength test indicated that 12% of CWM was the optimum and this percentage developed the UCS value from 202kPa to 500kPa for 28 days cured samples, which is equal, approximately 2.5 times the UCS value for untreated soil. Moreover, this percentage provided 1.4 times the value of UCS for stabilized soil-CWA by using FWM which recorded just under 700kPa after 28 days curing.
Abstract: The aim of this investigation is to elaborate nearinfrared
methods for testing and recognition of chemical components
and quality in “Pannon wheat” allied (i.e. true to variety or variety
identified) milling fractions as well as to develop spectroscopic
methods following the milling processes and evaluate the stability of
the milling technology by different types of milling products and
according to sampling times, respectively. These wheat categories
produced under industrial conditions where samples were collected
versus sampling time and maximum or minimum yields. The changes
of the main chemical components (such as starch, protein, lipid) and
physical properties of fractions (particle size) were analysed by
dispersive spectrophotometers using visible (VIS) and near-infrared
(NIR) regions of the electromagnetic radiation. Close correlation
were obtained between the data of spectroscopic measurement
techniques processed by various chemometric methods (e.g. principal
component analysis [PCA], cluster analysis [CA]) and operation
condition of milling technology. It is obvious that NIR methods are
able to detect the deviation of the yield parameters and differences of
the sampling times by a wide variety of fractions, respectively. NIR
technology can be used in the sensitive monitoring of milling
technology.
Abstract: In this study, the experiments were carried out to
determine the best coolant for the quenching process among waterbased
silica, alumina, titania and copper oxide nanofluids (0.1 vol%).
A sphere made up off brass material was used in the experiments.
When the spherical test specimen was heated at high temperatures, it
was suddenly immersed into the nanofluids. All experiments were
carried out at saturated conditions and under atmospheric pressure.
After the experiments, the cooling curves were obtained by using the
temperature-time data of the specimen. The experimental results
showed that the cooling performance of test specimen depended on
the type of nanofluids. The silica nanoparticles enhanced the
performance of boiling heat transfer and it is the best coolant for the
quenching among other nanoparticles.
Abstract: Doxorubicin (DOX) is an anthracycline drug used to treat many cancer diseases. Similarly to other cytostatic drugs, DOX has serious side effects; the biggest obstacle is the cardiotoxicity. With the aim of lowering the negative side effects and to target the DOX into the tumor tissue, the different nanoparticles (NPs) are studied. The aim of this work was to synthetized different NPs and conjugated them with DOX and determine the binding capacity of the NPs. For this experiment, carbon nanotubes (CNTs), graphene oxide (GO), fullerene (FUL) and liposomes (LIP) were used. The highest binding capacity was observed in GO (85%). Subsequently the toxicity of NPs and NPs-DOX conjugates was analyzed in in vivo system (chicken embryos). Some NPs (GO) can increase the toxicity of DOX, whereas other NPs (LIP, CNTs) decrease DOX toxicity.
Abstract: Copper (I) oxide microparticles with the morphology
of cubic and hollow sphere were synthesized with the assistance of
surfactant as the shape controller. Both particles were then subjected
to study the catalytic activity and observed the results of shape effects
of catalysts on rate of catalytic reaction. The decolorizing reaction of
crystal violet and sodium hydroxide was chosen and measured the
decreasing of reactant with respect to times using spectrophotometer.
The result revealed that morphology of crystal had no effect on the
catalytic activity for crystal violet reaction but contributed to total
surface area predominantly.
Abstract: Image segmentation and color identification is an
important process used in various emerging fields like intelligent
robotics. A method is proposed for the manipulator to grasp and place
the color object into correct location. The existing methods such as
PSO, has problems like accelerating the convergence speed and
converging to a local minimum leading to sub optimal performance.
To improve the performance, we are using watershed algorithm and
for color identification, we are using EPSO. EPSO method is used to
reduce the probability of being stuck in the local minimum. The
proposed method offers the particles a more powerful global
exploration capability. EPSO methods can determine the particles
stuck in the local minimum and can also enhance learning speed as
the particle movement will be faster.
Abstract: To ensure targeting of apoferritin nanocarrier with
encapsulated doxorubicin drug, we used a peptide linker based on a
protein G with N-terminus affinity towards Fc region of antibodies.
To connect the peptide to the surface of apoferritin, the C-terminus of
peptide was made of cysteine with affinity to gold. The surface of
apoferritin with encapsulated doxorubicin (APODOX) was coated
either with gold nanoparticles (APODOX-Nano) or gold(III) chloride
hydrate reduced with sodium borohydride (APODOX-HAu). The
reduction with sodium borohydride caused a loss of doxorubicin
fluorescent properties and probably accompanied with the loss of its
biological activity. Fluorescent properties of APODOX-Nano were
similar to the unmodified APODOX; therefore it was more suited for
the intended use. To evaluate the specificity of apoferritin modified
with antibodies, ELISA-like method was used with the surface of
microtitration plate wells coated by the antigen (goat anti-human IgG
antibodies). To these wells, the nanocarrier was applied. APODOX
without the modification showed 5× lower affinity to the antigen than
APODOX-Nano modified gold and targeting antibodies (human IgG
antibodies).
Abstract: The novel 3D SnO cabbages self-assembled by
nanosheets were successfully synthesized via template-free
hydrothermal growth method under facile conditions. The XRD
results manifest that the as-prepared SnO is tetragonal phase. The
TEM and HRTEM results show that the cabbage nanosheets are
polycrystalline structure consisted of considerable single-crystalline
nanoparticles. Two typical Raman modes A1g=210 and Eg=112 cm-1
of SnO are observed by Raman spectroscopy. Moreover, galvanostatic
cycling tests has been performed using the SnO cabbages as anode
material of lithium ion battery and the electrochemical results suggest
that the synthesized SnO cabbage structures are a promising anode
material for lithium ion batteries.
Abstract: Development of new generation bio-tribological,
multilayer coatings opens an avenue for fabrication of future hightech
functional surfaces. In the presented work, nano-composite,
Cr/CrN+[Cr/ a-C:H implanted by metallic nanocrystals] multilayer
coatings have been developed for surface protection of medical tools.
Thin films were fabricated by a hybrid Pulsed Laser Deposition
technique. Complex microstructure analysis of nanomultilayer
coatings, subjected to mechanical and biological tests, were
performed by means of transmission electron microscopy (TEM).
Microstructure characterization revealed the layered arrangement of
Cr23C6 nanoparticles in multilayer structure. Influence of deposition
conditions on bio-tribological properties of the coatings was studied.
The bio-tests were used as a screening tool for the analyzed
nanomultilayer coatings before they could be deposited on medical
tools. Bio-medical tests were done using fibroblasts. The mechanical
properties of the coatings were investigated by means of a ball-ondisc
mechanical test. The micro hardness was done using Berkovich
indenter. The scratch adhesion test was done using Rockwell
indenter. From the bio-tribological point of view, the optimal
properties had the C106_1 material.
Abstract: We present a gas-liquid microfluidic system as a
reactor to obtain magnetite nanoparticles with an excellent degree of
control regarding their crystalline phase, shape and size. Several
types of microflow approaches were selected to prevent nanomaterial
aggregation and to promote homogenous size distribution. The
selected reactor consists of a mixer stage aided by ultrasound waves
and a reaction stage using a N2-liquid segmented flow to prevent
magnetite oxidation to non-magnetic phases. A milli-fluidic reactor
was developed to increase the production rate where a magnetite
throughput close to 450 mg/h in a continuous fashion was obtained.