Abstract: In this work, our goal is to optimize the nitriding treatment at a low-temperature of the steel 32CrMoV13 using gas mixtures of ammonia, nitrogen and hydrogen to improve the mechanical properties of the surface (good wear resistance, friction and corrosion), and of the diffusion layer of the nitrogen (good resistance to fatigue and good tenacity with heart). By limiting our work to the pure iron and to the alloys iron-chromium and iron-chromium-carbon, we have studied the various parameters which manage the nitriding: flow rate and composition of the gaseous phase, the interaction chromium-nitrogen and chromium-carbon by the help of experiments of nitriding realized in the laboratory by thermogravimetry. The acquired knowledge has been applied by the mastery of the growth of the γ' combination layer on the α diffusion layer in the case of the industrial steel 32CrMoV13.
Abstract: Biochar can be produced from the waste matter and its
application has been associated with returning of carbon in large
amounts into the soil. The impacts of this material on physical and
chemical properties of soil have been described. The biggest part of
the research work is dedicated to the hypothesis of this material’s
toxic effects on the soil life regarding its effect on the soil biological
component. At present, it has been worked on methods which could
eliminate these undesirable properties of biochar. One of the
possibilities is to mix biochar with organic material, such as compost,
or focusing on the natural processes acceleration in the soil. In the
experiment has been used as the addition of compost as well as the
elimination of toxic substances by promoting microbial activity in
aerated water environment. Biochar was aerated for 7 days in a
container with a volume of 20 l. This way modified biochar had six
times higher biomass production and reduce mineral nitrogen
leaching. Better results have been achieved by mixing biochar with
compost.
Abstract: A model to predict the plastic zone size for material
under plane stress condition has been developed and verified
experimentally. The developed model is a function of crack size,
crack angle and material property (dislocation density). Simulation
and validation results show that the model developed show good
agreement with experimental results. Samples of low carbon steel
(0.035%C) with included surface crack angles of 45o, 50o, 60o, 70o
and 90o and crack depths of 2mm and 4mm were subjected to low
strain rate between 0.48 x 10-3 s-1 – 2.38 x 10-3 s-1. The mechanical
properties studied were ductility, tensile strength, modulus of
elasticity, yield strength, yield strain, stress at fracture and fracture
toughness. The experimental study shows that strain rate has no
appreciable effect on the size of plastic zone while crack depth and
crack angle plays an imperative role in determining the size of the
plastic zone of mild steel materials.
Abstract: Selenium is an-antioxidant which is important for
human health enters food chain through crops. In Kenya Zea mays is
consumed by 96% of population hence is a cheap and convenient
method to provide selenium to large number of population. Several
soil factors are known to have antagonistic effects on selenium
speciation hence the uptake by Zea mays. There are no studies in
Kenya that has been done to determine the effects of soil
characteristics (pH, Tcarbon, CEC, Eh) affect accumulation of
selenium in Zea mays grains in Maize Belt in Kenya. About 100 Zea mays grain samples together with 100 soil samples
were collected from the study site put in separate labeled Ziplocs and
were transported to laboratories at room temperature for analysis.
Maize grains were analyzed for selenium while soil samples were
analyzed for pH, Cat Ion Exchange Capacity, total carbon, and
electrical conductivity. The mean selenium in Zea mays grains varied from 1.82 ± 0.76
mg/Kg to 11±0.86 mg/Kg. There was no significant difference
between selenium levels between different grain batches {χ (Df =76)
= 26.04 P= 1.00} The pH levels varied from 5.43± 0.58 to 5.85±
0.32. No significant correlations between selenium in grains and soil
pH (Pearson’s correlations = - 0.143), and between selenium levels in
grains and the four (pH, Tcarbon, CEC, Eh) soil chemical
characteristics {F (4,91) = 0.721 p = 0.579} was observed. It can be concluded that the soil chemical characteristics in the
study site did not significantly affect the accumulation of native
selenium in Zea mays grains.
Abstract: In this study, the time-dependent behavior of damaged
reinforced concrete shear wall structures strengthened with composite
plates having variable fibers spacing was investigated to analyze their
seismic response. In the analytical formulation, the adherent and the
adhesive layers are all modeled as shear walls, using the mixed Finite
Element Method (FEM). The anisotropic damage model is adopted to
describe the damage extent of the Reinforced Concrete shear walls.
The phenomenon of creep and shrinkage of concrete has been
determined by Eurocode 2. Large earthquakes recorded in Algeria
(El-Asnam and Boumerdes) have been tested to demonstrate the
accuracy of the proposed method. Numerical results are obtained for non-uniform distributions of
carbon fibers in epoxy matrices. The effects of damage extent and the
delay mechanism creep and shrinkage of concrete are highlighted.
Prospects are being studied.
Abstract: In the vicinity of red sea about 15 fungi species were
isolated from oil contaminated sites. On the basis of aptitude to
degrade the crude oil and DCPIP assay, two fungal isolates were
selected amongst 15 oil degrading strains. Analysis of ITS-1, ITS-2
and amplicon pyrosequencing studies of fungal diversity revealed
that these strains belong to Penicillium and Aspergillus species. Two
strains that proved to be the most efficient in degrading crude oil was
Aspergillus niger (54%) and Penicillium commune (48%) Subsequent
to two weeks of cultivation in BHS medium the degradation rate
were recorded by using spectrophotometer and GC-MS. Hence, it is
cleared that these fungal strains has capability of degradation and can
be utilize for cleaning the Saudi Arabian environment.
Abstract: This paper describes the development of a DNA-based
nanobiosensor to detect the dengue virus in mosquito using
electrically active magnetic (EAM) nanoparticles as concentrator and
electrochemical transducer. The biosensor detection encompasses
two sets of oligonucleotide probes that are specific to the dengue
virus: the detector probe labeled with the EAM nanoparticles and the
biotinylated capture probe. The DNA targets are double hybridized to
the detector and the capture probes and concentrated from
nonspecific DNA fragments by applying a magnetic field.
Subsequently, the DNA sandwiched targets (EAM-detector probe–
DNA target–capture probe-biotin) are captured on streptavidin
modified screen printed carbon electrodes through the biotinylated
capture probes. Detection is achieved electrochemically by measuring
the oxidation–reduction signal of the EAM nanoparticles. Results
indicate that the biosensor is able to detect the redox signal of the
EAM nanoparticles at dengue DNA concentrations as low as 10
ng/μl.
Abstract: The paper discusses the problem of load transport
using farm tractors and road tractor units. This type of carriage of
goods is often done with farm vehicles. The tests were performed
with the PEMS equipment (Portable Emission Measurement System)
under actual traffic conditions. The vehicles carried a load of 20000
kg. This research method is one of the most desired because it
provides reliable information on the actual vehicle emissions and fuel
consumption (carbon balance method). For the tests, a route was
selected that simulated a trip from a small town to a food-processing
facility located in a city. The analysis of the obtained results gave a
clear answer as to what vehicles need to be used for carriage of this
type of cargo in terms of exhaust emissions and fuel consumption.
Abstract: The main cause of Alzheimer disease (AD) was
believed to be mainly due to the accumulation of free radicals owing
to oxidative stress (OS) in brain tissue. The mechanism of the
neurotoxicity of Aluminum chloride (AlCl3) induced AD in
hippocampus Albino wister rat brain tissue, the curative & the
protective effects of Lipidium sativum group (LS) water extract were
assessed after 8 weeks by attenuated total reflection spectroscopy
ATR-IR and histologically by light microscope. ATR-IR results
revealed that the membrane phospholipid undergo free radical
attacks, mediated by AlCl3, primary affects the polyunsaturated fatty
acids indicated by the increased of the olefinic -C=CH sub-band area
around 3012 cm-1 from the curve fitting analysis. The narrowing in
the half band width (HBW) of the sνCH2 sub-band around 2852 cm-1
due to Al intoxication indicates the presence of trans form fatty acids
rather than gauch rotomer. The degradation of hydrocarbon chain to
shorter chain length, increasing in membrane fluidity, disorder, and
decreasing in lipid polarity in AlCl3 group indicated by the detected
changes in certain calculated area ratios compared to the control.
Administration of LS was greatly improved these parameters
compared to the AlCl3 group. Al influences the Aβ aggregation and
plaque formation, which in turn interferes to and disrupts the
membrane structure. The results also showed a marked increase in
the β-parallel and antiparallel structure, that characterize the Aβ
formation in Al-induced AD hippocampal brain tissue, indicated by
the detected increase in both amide I sub-bands around 1674, 1692
cm-1. This drastic increase in Aβ formation was greatly reduced in the
curative and protective groups compared to the AlCl3 group and
approached nearly the control values. These results supported too by
the light microscope. AlCl3 group showed significant marked
degenerative changes in hippocampal neurons. Most cells appeared
small, shrieked and deformed. Interestingly, the administration of LS
in curative and protective groups markedly decreases the amount of
degenerated cells compared to the non-treated group. In addition, the
intensity of congo red stained cells was decreased. Hippocampal
neurons looked more/or less similar to those of control. This study showed a promising therapeutic effect of Lipidium
sativum group (LS) on AD rat model that seriously overcome the
signs of oxidative stress on membrane lipid and restore the protein
misfolding.
Abstract: Noninvasive diagnostics of diseases via breath
analysis has attracted considerable scientific and clinical interest for
many years and become more and more promising with the rapid
advancements in nanotechnology and biotechnology. The volatile
organic compounds (VOCs) in exhaled breath, which are mainly
blood borne, particularly provide highly valuable information about
individuals’ physiological and pathophysiological conditions.
Additionally, breath analysis is noninvasive, real-time, painless, and
agreeable to patients. We have developed a wireless sensor array
based on single-stranded DNA (ssDNA)-functionalized single-walled
carbon nanotubes (SWNT) for the detection of a number of
physiological indicators in breath. Seven DNA sequences were used
to functionalize SWNT sensors to detect trace amount of methanol,
benzene, dimethyl sulfide, hydrogen sulfide, acetone, and ethanol,
which are indicators of heavy smoking, excessive drinking, and
diseases such as lung cancer, breast cancer, and diabetes. Our test
results indicated that DNA functionalized SWNT sensors exhibit
great selectivity, sensitivity, and repeatability; and different
molecules can be distinguished through pattern recognition enabled
by this sensor array. Furthermore, the experimental sensing results
are consistent with the Molecular Dynamics simulated ssDNAmolecular
target interaction rankings. Thus, the DNA-SWNT sensor
array has great potential to be applied in chemical or biomolecular
detection for the noninvasive diagnostics of diseases and personal
health monitoring.
Abstract: This research paper portrays a comparative analysis of
thermomechanical behaviour of Shielded Metal Arc Welding
(SMAW) and Gas Tungsten Arc Welding (GTAW) of low carbon
steel of AISI 1020 grade butt joints. The thermal history has been
obtained by experimental work. We have focused on temperature
dependent cooling rate as depicted by Adam’s two-dimensional
model. The effect of moving point heat source of SMAW and GTAW
on mechanical properties has been judged by optical and scanning
electron micrographs of different regions in weld joints. The
microhardness study has been carried to visualize the joint strength
due to formation of different phases.
Abstract: The effects of the contact ball-lens on the soda lime
glass in laser thermal cleavage with a cw Nd-YAG laser were
investigated in this study. A contact ball-lens was adopted to generate
a bending force on the crack formation of the soda-lime glass in the
laser cutting process. The Nd-YAG laser beam (wavelength of 1064
nm) was focused through the ball-lens and transmitted to the soda-lime
glass, which was coated with a carbon film on the surface with a
bending force from a ball-lens to generate a tensile stress state on the
surface cracking. The fracture was controlled by the contact ball-lens
and a straight cutting was tested to demonstrate the feasibility.
Experimental observations on the crack propagation from the leading
edge, main section and trailing edge of the glass sheet were compared
with various mechanical and thermal loadings. Further analyses on the
stress under various laser powers and contact ball loadings were made
to characterize the innovative technology. The results show that the distributions of the side crack at the
leading and trailing edges are mainly dependent on the boundary
condition, contact force, cutting speed and laser power. With the
increase of the mechanical and thermal loadings, the region of the side
cracks might be dramatically reduced with proper selection of the
geometrical constrains. Therefore the application of the contact
ball-lens is a possible way to control the fracture in laser cleavage with
improved cutting qualities.
Abstract: The increase of technogenic and natural accidents,
accompanied by air pollution, for example, by combustion products,
leads to the necessity of respiratory protection. This work is devoted to the development of a calorimetric method
and a device which allows investigating quickly the kinetics of
carbon dioxide sorption by chemisorbents on the base of potassium
superoxide in order to assess the protective properties of respiratory
protective closed circuit apparatus. The features of the traditional approach for determining the
sorption properties in a thin layer of chemisorbent are described, as
well as methods and devices, which can be used for the sorption
kinetics study. The authors developed an approach (as opposed to the traditional
approach) based on the power measurement of internal heat sources
in the chemisorbent layer. The emergence of the heat sources is a
result of exothermic reaction of carbon dioxide sorption. This
approach eliminates the necessity of chemical analysis of samples
and can significantly reduce the time and material expenses during
chemisorbents testing. Error of determining the volume fraction of adsorbed carbon
dioxide by the developed method does not exceed 12%. Taking into
account the efficiency of the method, we consider that it is a good
alternative to traditional methods of chemical analysis under the
assessment of the protection sorbents quality.
Abstract: Polycyclic Aromatic Hydrocarbons (PAHs) are
formed mainly because of incomplete combustion of organic
materials during industrial, domestic activities or natural occurrence.
Their toxicity and contamination of terrestrial and aquatic ecosystem
have been established. However, with limited validity index, previous
research has focused on PAHs isomer pair ratios of variable
physicochemical properties in source identification. The objective of
this investigation was to determine the empirical validity of Pearson
Correlation Coefficient (PCC) and Cluster Analysis (CA) in PAHs
source identification along soil samples of different land uses.
Therefore, 16 PAHs grouped, as Endocrine Disruption Substances
(EDSs) were determined in 10 sample stations in top and sub soils
seasonally. PAHs was determined the use of Varian 300 gas
chromatograph interfaced with flame ionization detector. Instruments
and reagents used are of standard and chromatographic grades
respectively. PCC and CA results showed that the classification of
PAHs along pyrolitic and petrogenic organics used in source
signature is about the predominance PAHs in environmental matrix.
Therefore, the distribution of PAHs in the studied stations revealed
the presence of trace quantities of the vast majority of the sixteen
PAHs, which may ultimately inhabit the actual source signature
authentication. Therefore, factors to be considered when evaluating
possible sources of PAHs could be; type and extent of bacterial
metabolism, transformation products/substrates, and environmental
factors such as salinity, pH, oxygen concentration, nutrients, light
intensity, temperature, co-substrates, and environmental medium are
hereby recommended as factors to be considered when evaluating
possible sources of PAHs.
Abstract: Novel wind-lens turbine designs can augment power
output. Vacuum-Assisted Resin Transfer Molding (VARTM) is used
to form large and complex structures from a Carbon Fiber Reinforced
Polymer (CFRP) composite. Typically, wind-lens turbine structures
are fabricated in segments, and then bonded to form the final structure.
This paper introduces five new adhesive joints, divided into two
groups: one is constructed between dry carbon and CFRP fabrics, and
the other is constructed with two dry carbon fibers. All joints and
CFRP fabrics were made in our laboratory using VARTM
manufacturing techniques. Specimens were prepared for tensile testing
to measure joint performance. The results showed that the second
group of joints achieved a higher tensile strength than the first group.
On the other hand, the tensile fracture behavior of the two groups
showed the same pattern of crack originating near the joint ends
followed by crack propagation until fracture.
Abstract: Well logging records can help to answer many
questions from a wide range of special interested information and
basic petrophysical properties to formation evaluation of oil and gas
reservoirs. The accurate calculations of porosity in carbonate
reservoirs are the most challenging aspects of the well logging
analysis. Many equations have been developed over the years based
on known physical principles or on empirically derived relationships,
which are used to calculate porosity, estimate lithology, and water
saturation; however these parameters are calculated from well logs by
using modern technique in a current study. Nasiriya oil field is one of
the giant oilfields in the Middle East, and the formation under study
is the Mishrif carbonate formation which is the shallowest
hydrocarbon bearing zone in this oilfield. Neurolog software was
used to digitize the scanned copies of the available logs.
Environmental corrections had been made as per Schlumberger charts
2005, which supplied in the Interactive Petrophysics software. Three
saturation models have been used to calculate water saturation of
carbonate formations, which are simple Archie equation, Dual water
model, and Indonesia model. Results indicate that the Mishrif
formation consists mainly of limestone, some dolomite, and shale.
The porosity interpretation shows that the logging tools have a good
quality after making the environmental corrections. The average
formation water saturation for Mishrif formation is around 0.4-
0.6.This study is provided accurate behavior of petrophysical
properties with depth for this formation by using modern software.
Abstract: In present study, a large deposit of oolitic iron ore of
Late Carboniferous-Permotriassic-Lower Jurassic age was discovered
in Wadi Halfa and Argein areas, North Sudan. It seems that the iron
ore mineralization exists in the west and east bank of the River Nile
of the study area that are found on the Egyptian-Sudanese border.
The Carboniferous-Lower Jurassic age strata were covered by 67
sections and each section has been examined and carefully described.
The iron-ore in Wadi Halfa occurs as oolitic ironstone and contained
two horizons: (A) horizon and (B) horizon. Only horizon (A) was
observed in southern Argein area. The texture of the ore is variable
depending on the volume of the component. In thin sections, the
average of the ooids was ranged between 90%-80%. The matrix
varies between 10%-20% by volume and detritus quartz in other
component my reach up to 30% by volume in sandy massive ore.
Ooids size ranges from 0.2mm-1.00 mm on average in very coarse
ooids may attend up to 1 mm in size. The matrix around the ooids is
dominated by iron hydroxide, carbonate, fine, and amorphous silica.
The probable ore reserve estimate of 1.234 billion at a head grade of
41.29% Fe for the Wadi Halfa Oolitic Ironstone Formation. The iron
ore shows higher content of phosphorus ranges from 6.15% to 0.16%,
with mean 1.45%. The new technology Hatch–Ironstone Chloride
Segregation (HICS) can be used to produce commercial-quality of
iron and reduce phosphorus and silica to acceptable levels for steel
industry. The presence of infrastructures in addition to the presence
of massive quantities of iron ore would make exploitation
economically.
Abstract: Hydraulic fracturing is one of the most important
stimulation techniques available to the petroleum engineer to extract
hydrocarbons in tight gas sandstones. It allows more oil and gas
production in tight reservoirs as compared to conventional means.
The main aim of the study is to optimize the hydraulic fracturing as
technique and for this purpose three multi-zones layer formation is
considered and fractured contemporaneously. The three zones are
named as Zone1 (upper zone), Zone2 (middle zone) and Zone3
(lower zone) respectively and they all occur in shale rock. Simulation was performed with Mfrac integrated software which
gives a variety of 3D fracture options. This simulation process
yielded an average fracture efficiency of 93.8%for the three
respective zones and an increase of the average permeability of the
rock system. An average fracture length of 909 ft with net height
(propped height) of 210 ft (average) was achieved. Optimum
fracturing results was also achieved with maximum fracture width of
0.379 inches at an injection rate of 13.01 bpm with 17995 Mscf of
gas production.
Abstract: In this work, repaired crack in 6061- T6 aluminum
plate with composite patches presented, firstly we determine the
displacement, strain and stress, also the first six mode shape of the
plate, secondly we took the same model adding central crack
initiation, which is located in the center of the plate, its seize vary
from 20 mm to 60 mm and we compare the first results with second.
Thirdly we repair various cracks with composite patch (carbon/
epoxy) and for (2 layers, 4 layers). Finally the comparison of stress,
strain, displacement and six first natural frequencies between un-cracked
specimen, crack propagation and composite patch repair.
Abstract: Cost overruns are a persistent problem in oil and gas
megaprojects. Whilst the extant literature is filled with studies on
incidents and causes of cost overruns, underlying theories to explain
their emergence in oil and gas megaprojects are few. Yet, a way to
contain the syndrome of cost overruns is to understand the bases of
‘how and why’ they occur. Such knowledge will also help to develop
pragmatic techniques for better overall management of oil and gas
megaprojects. The aim of this paper is to explain the development of
cost overruns in hydrocarbon megaprojects through the perspective of
chaos theory. The underlying principles of chaos theory and its
implications for cost overruns are examined and practical
recommendations proposed. In addition, directions for future research
in this fertile area provided.