Abstract: In this study, we demonstrate the production of natural gas hydrates from permeable marine sediments with simultaneous mechanisms for methane recovery and methane-air or methane-air/carbon dioxide replacement. The simultaneous melting happens until the chemical potentials become equal in both phases as natural gas hydrate depletion continues and self-regulated methane-air replacement occurs over an arbitrary point. We observed certain point between dissociation and replacement mechanisms in the natural gas hydrate reservoir, and we call this boundary as critical methane concentration. By the way, when carbon dioxide was added, the process of chemical exchange of methane by air/carbon dioxide was observed in the natural gas hydrate. The suggested process will operate well for most global natural gas hydrate reservoirs, regardless of the operating conditions or geometrical constraints.
Abstract: Stress of slaughter animals starting long before until at the time of process of slaughtering which cause misery and decrease of meat quality. Meanwhile, determination of animal stress using hormonal such as cortisol is expensive and less practical so that portable stress indicator for cows based on Fourier Transform Infrared Spectroscopy (FTIR) must be provided. The aims of this research are to find out the comparison process of slaughter between Rope Casting Local (RCL) and Restraining Box Method (RBM) by measuring of cortisol and wavelength in FTIR methods. Thirty two of male Ongole crossbred cattle were used in this experiment. Blood sampling was taken from jugular vein when they were rested and repeated when slaughtered. All of blood samples were centrifuged at 3000 rpm for 20 minutes to get serum, and then divided into two parts for cortisol assayed using ELISA and for measuring the wavelength using FTIR. The serum then measured at the wavelength between 4000-400 cm-1 using MB3000 FTIR. Band data absorption in wavelength of FTIR is analyzed descriptively by using FTIR Horizon MBTM. For RCL, average of serum cortisol when the animals rested were 11.47 ± 4.88 ng/mL, when the time of slaughter were 23.27 ± 7.84 ng/mL. For RBM, level of cortisol when rested animals were 13.67 ± 3.41 ng/mL and 53.47 ± 20.25 ng/mL during the slaughter. Based on student t-Test, there were significantly different between RBM and RCL methods when beef cattle were slaughtered (P0.05). Result of FTIR with the various of wavelength such as methyl group (=CH3 ) 2986cm-1, methylene (=CH2 ) 2827 cm-1, hydroxyl (- OH) 3371 cm-1, carbonyl (ketones) (C=O) 1636 cm-1, carboxyl (COO-1) 1408 cm-1, glucosa 1057 cm-1, urea 1011 cm-1have been obtained. It can be concluded that the RCL slaughtered method is better than the RBM method based on the increase of cortisol as an indicator of stress in beef cattle (P
Abstract: This study examines the feasibility of indirect solar
desalination in oil producing countries in the Middle East and North
Africa (MENA) region. It relies on value engineering (VE) and costbenefit
with sensitivity analyses to identify optimal coupling
configurations of desalination and solar energy technologies. A
comparative return on investment was assessed as a function of water
costs for varied plant capacities (25,000 to 75,000 m3/day), project
lifetimes (15 to 25 years), and discount rates (5 to 15%) taking into
consideration water and energy subsidies, land cost as well as
environmental externalities in the form of carbon credit related to
greenhouse gas (GHG) emissions reduction. The results showed
reverse osmosis (RO) coupled with photovoltaic technologies (PVs)
as the most promising configuration, robust across different prices for
Brent oil, discount rates, as well as different project lifetimes.
Environmental externalities and subsidies analysis revealed that a
16% reduction in existing subsidy on water tariffs would ensure
economic viability. Additionally, while land costs affect investment
attractiveness, the viability of RO coupled with PV remains possible
for a land purchase cost
Abstract: To mitigate the urban heat island effect has become a
global issue when we are faced with the challenge of climate change.
Through literature review, plant photosynthesis can reduce the carbon
dioxide and mitigate the urban heat island effect to a degree. Because
there are not enough open space and parks, green roof has become an
important policy in Taiwan.
We selected elementary school buildings in northern New Taipei
City as research subjects since elementary schools are asked with
priority to build green roof and important educational place to promote
green roof concept. Testo175-H1 recording device was used to record
the temperature and humidity differences between roof surface and
interior space below roof with and without green roof in the long-term.
We also use questionnaires to investigate the awareness of comfort
level of green roof and sensation of teachers and students of the
elementary schools.
The results indicated that the temperature of roof without greening
was higher than that with greening by about 2°C. But sometimes
during noontime, the temperature of green roof was higher than that of
non-green roof probably because of the character of the accumulation
and dissipation of heat of greening. The temperature of the interior
space below green roof was normally lower than that without green
roof by about 1°C, showing that green roof could lower the
temperature. The humidity of the green roof was higher than the one
without greening also indicated that green roof retained water better.
Teachers liked to combine green roof concept in the curriculum,
and students wished all classes can take turns to maintain the green
roof. Teachers and students whose school had integrated green roof
concept in the curriculum were more willing to participate in the
maintenance work of green roof. Teachers and students who may have
access to and touch the green roof can be more aware of the green roof
benefit. We suggest architects to increase the accessibility and
visibility of green roof, such as use it as a part of the activity space.
This idea can be a reference to the green roof curriculum design.
Abstract: Atmospheric carbon dioxide emissions are considered
as the greatest environmental challenge the world is facing today.
The tasks to control the emissions include the recovery of CO2 from
flue gas. This concern has been improved due to recent advances in
materials process engineering resulting in the development of
inorganic gas separation membranes with excellent thermal and
mechanical stability required for most gas separations. This paper,
therefore, evaluates the performance of a highly selective inorganic
membrane for CO2 recovery applications. Analysis of results
obtained is in agreement with experimental literature data. Further
results show the prediction performance of the membranes for gas
separation and the future direction of research. The materials
selection and the membrane preparation techniques are discussed.
Method of improving the interface defects in the membrane and its
effect on the separation performance has also been reviewed and in
addition advances to totally exploit the potential usage of this
innovative membrane.
Abstract: Computational fluid dynamics analysis of the burning
of syngas fuels derived from biomass and plastic solid waste mixture
through gasification process is presented in this paper. The syngas
fuel is burned in gas turbine can combustor. Gas turbine can
combustor with swirl is designed to burn the fuel efficiently and
reduce the emissions. The main objective is to test the impact of the
alternative syngas fuel compositions and lower heating value on the
combustion performance and emissions. The syngas fuel is produced
by blending palm kernel shell (PKS) with polyethylene (PE) waste
via catalytic steam gasification (fluidized bed reactor). High
hydrogen content syngas fuel was obtained by mixing 30% PE waste
with PKS. The syngas composition obtained through the gasification
process is 76.2% H2, 8.53% CO, 4.39% CO2 and 10.90% CH4. The
lower heating value of the syngas fuel is LHV = 15.98 MJ/m3. Three
fuels were tested in this study natural gas (100%CH4), syngas fuel
and pure hydrogen (100% H2). The power from the combustor was
kept constant for all the fuels tested in this study. The effect of syngas
fuel composition and lower heating value on the flame shape, gas
temperature, mass of carbon dioxide (CO2) and nitrogen oxides
(NOX) per unit of energy generation is presented in this paper. The
results show an increase of the peak flame temperature and NO mass
fractions for the syngas and hydrogen fuels compared to natural gas
fuel combustion. Lower average CO2 emissions at the exit of the
combustor are obtained for the syngas compared to the natural gas
fuel.
Abstract: This study focuses on a novel method for dispersion
and distribution of reinforcement under high intensive shear stress to
produce metal composites. The polyacrylonitrile (PAN)-based short
carbon fiber (Csf) and Nextel 610 alumina fiber were dispersed under
high intensive shearing at mushy zone in semi-solid of A356 by a
novel method. The bundles and clusters were embedded by
infiltration of slurry into the clusters, thus leading to a uniform
microstructure. The fibers were embedded homogenously into the
aluminum around 576-580°C with around 46% of solid fraction.
Other experiments at 615°C and 568°C which are contained 0% and
90% solid respectively were not successful for dispersion and
infiltration of aluminum into bundles of Csf. The alumina fiber has
been cracked by high shearing load. The morphologies and
crystalline phase were evaluated by SEM and XRD. The adopted
thixo-process effectively improved the adherence and distribution of
Csf into Al that can be developed to produce various composites by
thixomixing.
Abstract: In contrast with literal meaning of nano, researchers
have been achieved mega adventures in this area and every day more
nanomaterials are being introduced to the market. After long time
application of fossil-based plastics, nowadays accumulation of their
waste seems to be a big problem to the environment. On the other
hand, mankind has more attention to safety and living environment.
Replacing common plastic packaging materials with degradable ones
that degrade faster and convert to non-dangerous components like
water and carbon dioxide have more attractions; these new materials
are based on renewable and inexpensive sources of starch and
cellulose. However, the functional properties of them do not suitable
for packaging. At this point, nanotechnology has an important role.
Utilizing of nanomaterials in polymer structure will improve
mechanical and physical properties of them; nanocrystalline cellulose
(NCC) has this ability. This work has employed a chemical method to
produce NCC and starch bio nanocomposite containing NCC. X-Ray
Diffraction technique has characterized the obtained materials.
Results showed that applied method is a suitable one as well as
applicable one to NCC production.
Abstract: Through use of novel modern/rapid processing
techniques such as screen printing and Near-Infrared (NIR) radiative
curing, process time for the sintering of sintered nickel plaques,
applicable to alkaline nickel battery chemistries, has been drastically
reduced from in excess of 200 minutes with conventional convection
methods to below 2 minutes using NIR curing methods. Steps have
also been taken to remove the need for forming gas as a reducing
agent by implementing carbon as an in-situ reducing agent, within the
ink formulation.
Abstract: Microstructural and electrical properties of
Cu-chromium alloy (Cu-Cr) dispersed with vapor-grown carbon fiber
(VGCF) prepared by powder metallurgy (P/M) process have been
investigated. Cu-0.7 mass% Cr pre-alloyed powder (Cu-Cr) made by
water atomization process was used as raw materials, which contained
solid solute Cr elements in Cu matrix. The alloy powder coated with
un-bundled VGCF by using oil coating process was consolidated at
1223 K in vacuum by spark plasma sintering, and then extruded at
1073 K. The extruded Cu-Cr alloy (monolithic alloy) had 209.3 MPa
YS and 80.4 IACS% conductivity. The extruded Cu-Cr with 0.1
mass% VGCF composites revealed a small decrease of YS compared
to the monolithic Cu-Cr alloy. On the other hand, the composite had a
higher electrical conductivity than that of the monolithic alloy. For
example, Cu-Cr with 0.1 mass% VGCF composite sintered for 5 h
showed 182.7 MPa YS and 89.7 IACS% conductivity. In the case of
Cu-Cr with VGCFs composites, the Cr concentration was observed
around VGCF by SEM-EDS analysis, where Cr23C6 compounds were
detected by TEM observation. The amount of Cr solid solution in the
matrix of the Cu-Cr composites alloy was about 50% compared to the
monolithic Cu-Cr sintered alloy, and resulted in the remarkable
increment of the electrical conductivity.
Abstract: Removal of the widespread used drug paracetamol
from water was investigated using activated carbon originated from
dende coconut mesocarp and babassu coconut mesocarp. Kinetic and
equilibrium data were obtained at different values of pH. Both
activated carbons showed high efficiency when pH ≤ pHPZC as the
carbonil group of paracetamol molecule are adsorbed due to
positively charged carbon surface. Microporosity also played an
important role in such process. Pseudo-second order model was better
adjusted to the kinetic results. Equilibrium data may be represented
by Langmuir equation.
Abstract: Non-crimp 3D orthogonal fabric composite is one of
the textile-based composite materials that are rapidly developing
light-weight engineering materials. The present paper focuses on
geometric and micromechanical modeling of non-crimp 3D
orthogonal carbon fabric and composites reinforced with it for
aerospace applications. In this research meso-finite element (FE)
modeling employs for stress analysis in different load conditions.
Since mechanical testing of expensive textile carbon composites with
specific application isn't affordable, simulation composite in a virtual
environment is a helpful way to investigate its mechanical properties
in different conditions.
Abstract: Brass terminal, one of the several crude oil and
petroleum products storage/handling facilities in the Niger Delta was
built in the 1980s. Activities at this site, over the years, released
crude oil into this 3 m-deep, 1500 m-long canal lying adjacent to the
terminal with oil floating on it and its sediment heavily polluted. To
ensure effective clean-up, three major activities were planned: site
characterization, bioremediation pilot plant construction and testing
and full-scale bioremediation of contaminated sediment / bank soil by
land farming. The canal was delineated into 12 lots and each
characterized, with reference to the floating oily phase, contaminated
sediment and canal bank soil. As a result of site characterization, a
pilot plant for on-site bioremediation was designed and a treatment
basin constructed for carrying out pilot bioremediation test.
Following a designed sampling protocol, samples from this pilot
plant were collected for analysis at two laboratories as a quality
assurance / quality control check. Results showed that Brass Canal
upstream is contaminated with dark, thick and viscous oily film with
characteristic hydrocarbon smell while downstream, thin oily film
interspersed with water was observed. Sediments were observed to be
dark with mixture of brownish sandy soil with TPH ranging from
17,800 mg/kg in Lot 1 to 88,500 mg/kg in Lot 12 samples. Brass
Canal bank soil was observed to be sandy from ground surface to 3m,
below ground surface (bgs) it was silty-sandy and brownish while
subsurface soil (4-10m bgs) was sandy-clayey and whitish/grayish
with typical hydrocarbon smell. Preliminary results obtained so far
have been very promising but were proprietary. This project is
considered, to the best of technical literature knowledge, the first
large-scale on-site bioremediation project in the Niger Delta region,
Nigeria.
Abstract: The article presents a plasma chemical technology for
processing solid fuels, using examples of bituminous and brown
coals. Thermodynamic and experimental investigation of the
technology was made. The technology allows producing synthesis
gas from the coal organic mass and valuable components (technical
silicon, ferrosilicon, aluminum, and carbon silicon, as well as
microelements of rare metals, such as uranium, molybdenum,
vanadium, etc.) from the mineral mass. The thusly produced highcalorific
synthesis gas can be used for synthesis of methanol, as a
high-calorific reducing gas instead of blast-furnace coke as well as
power gas for thermal power plants.
Abstract: Prosperity of electronic equipment in photocopying
environment not only has improved work efficiency, but also has
changed indoor air quality. Considering the number of photocopying
employed, indoor air quality might be worse than in general office
environments. Determining the contribution from any type of
equipment to indoor air pollution is a complex matter. Non-methane
hydrocarbons are known to have an important role on air quality due
to their high reactivity. The presence of hazardous pollutants in
indoor air has been detected in one photocopying shop in Novi Sad,
Serbia. Air samples were collected and analyzed for five days, during
8-hr working time in three time intervals, whereas three different
sampling points were determined. Using multiple linear regression
model and software package STATISTICA 10 the concentrations of
occupational hazards and microclimates parameters were mutually
correlated. Based on the obtained multiple coefficients of
determination (0.3751, 0.2389 and 0.1975), a weak positive
correlation between the observed variables was determined. Small
values of parameter F indicated that there was no statistically
significant difference between the concentration levels of nonmethane
hydrocarbons and microclimates parameters. The results
showed that variable could be presented by the general regression
model: y = b0 + b1xi1+ b2xi2. Obtained regression equations allow to
measure the quantitative agreement between the variables and thus
obtain more accurate knowledge of their mutual relations.
Abstract: In this work, two fermentations at different
temperatures (25 and 30ºC), with cell recycling, were accomplished
to produce ethanol, using a mix of commercial substrates, xylose
(70%) and glucose (30%), as organic source for Scheffersomyces
stipitis. Five consecutive fermentations of 80 g L-1 (1º, 2º and 3º
recycles), 96 g L-1 (4º recycle) and 120 g L-1 (5º recycle)reduced
sugars led to a final maximum ethanol concentration of 17.2 and 34.5
g L-1, at 25 and 30ºC, respectively. Glucose was the preferred
substrate; moreover xylose startup degradation was initiated after a
remaining glucose presence in the medium. Results showed that yeast
acid treatment, performed before each cycle, provided improvements
on cell viability, accompanied by ethanol productivity of 2.16 g L-1 h-
1 at 30ºC. A maximum 36% of xylose was retained in the
fermentation medium and after five-cycle fermentation an ethanol
yield of 0.43 g ethanol/g sugars was observed. S. stipitis fermentation
capacity and tolerance showed better results at 30ºC with 83.4% of
theoretical yield referenced on initial biomass.
Abstract: Ibeno, Nigeria hosts the operational base of Mobil
Producing Nigeria Unlimited (MPNU), a subsidiary of ExxonMobil
and the current highest oil & condensate producer in Nigeria. Besides
MPNU, other oil companies operate onshore, on the continental shelf
and deep offshore of the Atlantic Ocean in Ibeno, Nigeria. This study
was designed to delineate oil polluted sites in Ibeno, Nigeria using
geophysical methods of electrical resistivity (ER) and ground
penetrating radar (GPR). Results obtained revealed that there have
been hydrocarbon contaminations of this environment by past crude
oil spills as observed from high resistivity values and GPR profiles
which clearly show the distribution, thickness and lateral extent of
hydrocarbon contamination as represented on the radargram reflector
tones. Contaminations were of varying degrees, ranging from slight
to high, indicating levels of substantial attenuation of crude oil
contamination over time. Moreover, the display of relatively lower
resistivities of locations outside the impacted areas compared to
resistivity values within the impacted areas and the 3-D Cartesian
images of oil contaminant plume depicted by red, light brown and
magenta for high, low and very low oil impacted areas, respectively
confirmed significant recent pollution of the study area with crude
oil.
Abstract: An unconventional composite inorganic ceramic
membrane capable of enhancing carbon dioxide emission decline was
fabricated and tested at laboratory scale in conformism to various
environmental guidelines and also to mitigate the effect of global
warming. A review of the existing membrane technologies for carbon
capture including the relevant gas transport mechanisms is presented.
Single gas permeation experiments using silica modified ceramic
membrane with internal diameter 20mm, outside diameter 25mm and
length of 368mm deposited on a macro porous support was carried
out to investigate individual gas permeation behaviours at different
pressures at room temperature. Membrane fabrication was achieved
using after a dip coating method. Nitrogen, Carbon dioxide, Argon,
Oxygen and Methane pure gases were used to investigate their
individual permeation rates at various pressures. Results show that
the gas flow rate increases with pressure drop. However above a
pressure of 3bar, CO2 permeability ratio to that of the other gases
indicated control of a more selective surface adsorptive transport
mechanism.
Abstract: An experimental and analytical research on shear
buckling of a comparably large polymer composite I-section is
presented. It is known that shear buckling load of a large span
composite beam is difficult to determine experimentally. In order to
sensitively detect shear buckling of the tested I-section, twenty strain
rosettes and eight displacement sensors were applied and attached on
the web and flange surfaces. The tested specimen was a pultruded
composite beam made of vinylester resin, E-glass, carbon fibers and
micro-fillers. Various coupon tests were performed before the shear
buckling test to obtain fundamental material properties of the Isection.
An asymmetric four-point bending loading scheme was
utilized for the shear test. The loading scheme resulted in a high shear
and almost zero moment condition at the center of the web panel. The
shear buckling load was successfully determined after analyzing the
obtained test data from strain rosettes and displacement sensors. An
analytical approach was also performed to verify the experimental
results and to support the discussed experimental program.
Abstract: This paper proposes the application of the Smart
Security Concept in the East Mediterranean. Smart Security aims to
secure critical infrastructure, such as hydrocarbon platforms, against
asymmetrical threats. The concept is based on Anti Asymmetrical
Area Denial (A3D) which necessitates limiting freedom of action of
maritime terrorists and piracy by founding safe and secure maritime
areas through sea lines of communication using short range
capabilities.