Abstract: This study presents synthesis of novel block
copolymers of thienyl end capped ethoxylated nonyl phenol and
pyrrole via chemical oxidative polymerization. Ethoxylated nonyl
phenol (ENP) was reacted with 2-thiophenecarbonyl chloride in order
to synthesize a macromonomer containing thienyl end-group (ENPThC).
Then copolymers of ENP-ThC and pyrrole were synthesized
by chemical oxidative polymerization using iron (III) chloride as an
oxidant. ENP-ThC served both as a macromonomer and an emulsifier
for pyrrole with poor solubility in water.
The synthesized block copolymers (ENP-ThC-b-PPy) were
characterized by spectroscopic analysis and the electrical
conductivities were investigated with 4-point probe technique.
Abstract: Lightweight design represents an important key to
successful implementation of energy-saving, fuel-efficient and
environmentally friendly means of transport in the aerospace and
automotive industry. In this context the use of carbon fibre reinforced
plastics (CFRP) which are distinguished by their outstanding
mechanical properties at relatively low weight, promise significant
improvements. Due to the reduction of the total mass, with the
resulting lowered fuel or energy consumption and CO2 emissions
during the operational phase, commercial aircraft will increasingly be
made of CFRP. An auspicious technology for the efficient and
economic production of high performance thermoset composites and
hybrid structures for future lightweight applications is the
combination of carbon fibre sheet moulding compound, tailored
continuous carbon fibre reinforcements and metallic components in a
one-shot pressing and curing process. This paper deals with a hybrid
composite technology for aerospace industries, which was developed
with the help of a special innovation and development system.
Abstract: In the scope of application of technical textiles, Non-
Crimp Fabrics are increasingly used. In general, NCF exhibit
excellent load bearing properties, but caused by the manufacturing
process, there are some remaining disadvantages which have to be
reduced. Regarding to this, a novel technique of processing NCF was
developed substituting the binding-thread by an adhesive. This stitchfree
method requires new manufacturing concept as well as new basic
methods to prove adhesion of glue at fibres and textiles. To improve
adhesion properties and the wettability of carbon-fibres by the
adhesive, oxy-fluorination was used. The modification of carbonfibres
by oxy-fluorination was investigated via scanning electron
microscope, X-ray photoelectron spectroscopy and single fibre
tensiometry. Special tensile tests were developed to determine the
maximum force required for detachment.
Abstract: In this paper, extract of papaya leaves are used as a
natural dye and combined by variations of solvent concentration
applied on DSSC (Dye-Sensitized Solar Cell). Indonesian geographic
located on the equator line occasions the magnitude of the potential
to develop organic solar cells made from extracts of chlorophyll as a
substitute for inorganic materials or synthetic dye on DSSC material.
Dye serves as absorbing photons which are then converted into
electrical energy. A conductive coated glass layer called TCO
(Transparent Conductive Oxide) is used as a substrate of electrode.
TiO2 nanoparticles as binding dye molecules, redox couple iodide/
tri-iodide as the electrolyte and carbon as the counter electrode in the
DSSC are used. TiO2 nanoparticles, organic dyes, electrolytes, and
counter electrode are arranged and combined with the layered
structure of the photo-catalyst absorption layer. Dye absorption
measurements using a spectrophotometer at 400-800 nm light
spectrum produces a total amount of chlorophyll 80.076 mg/l. The
test cell at 7 watt LED light with 5000 lux luminescence was
obtained Voc and Isc of 235.5 mV and 14 μA, respectively.
Abstract: Carbon fiber reinforced polymersarewidely used to strengthen steel structural elements. These structural elements are normally subjected to static, dynamic and fatigue loadings during their life-time. CFRP laminate is commonly used to strengthen these structures under the subjected loads. A number of studies have focused on the characteristics of CFRP sheets bonded to steel members under static, dynamic and fatigue loadings. However, there is a gap in understanding the bonding behavior between CFRP laminates and steel members under impact loading. This paper shows the effect of high load rates on this bond. CFRP laminate CFK 150/2000 was used to strengthen steel joints using Araldite 420 epoxy. The results show that applying a high load rate significantly affects the bond strength but has little influence on the effective bond length.
Abstract: In this research, waterglass based aerogel powder was
prepared by sol–gel process and ambient pressure drying. Inspired by
limited dust releasing, aerogel powder was introduced to the PET
electrospinning solution in an attempt to create required bulk and
surface structure for the nanofibers to improve their hydrophobic and
insulation properties. The samples evaluation was carried out by
measuring density, porosity, contact angle, heat transfer, FTIR, BET,
and SEM. According to the results, porous silica aerogel powder was
fabricated with mean pore diameter of 24 nm and contact angle of
145.9º. The results indicated the usefulness of the aerogel powder
confined into nanofibers to control surface roughness for
manipulating superhydrophobic nanowebs with water contact angle
of 147º. It can be due to a multi-scale surface roughness which was
created by nanowebs structure itself and nanofibers surface
irregularity in presence of the aerogels while a layer of fluorocarbon
created low surface energy. The wettability of a solid substrate is an
important property that is controlled by both the chemical
composition and geometry of the surface. Also, a decreasing trend in
the heat transfer was observed from 22% for the nanofibers without
any aerogel powder to 8% for the nanofibers with 4% aerogel
powder. The development of thermal insulating materials has become
increasingly more important than ever in view of the fossil energy
depletion and global warming that call for more demanding energysaving
practices.
Abstract: This paper investigates the viability of using carbon
fiber reinforced epoxy composites modified with carbon nanotubes to
strengthening reinforced concrete (RC) columns. Six RC columns
was designed and constructed according to ASCE standards. The
columns were wrapped using carbon fiber sheets impregnated with
either neat epoxy or CNTs modified epoxy. These columns were then
tested under concentric axial loading. Test results show that;
compared to the unwrapped specimens; wrapping concrete columns
with carbon fiber sheet embedded in CNTs modified epoxy resulted
in an increase in its axial load resistance, maximum displacement,
and toughness values by 24%, 109% and 232%, respectively. These
results reveal that adding CNTs into epoxy resin enhanced the
confinement effect, specifically, increased the axial load resistance,
maximum displacement, and toughness values by 11%, 6%, and
19%, respectively compared with columns strengthening with carbon
fiber sheet embedded in neat epoxy.
Abstract: This work was one of the tasks of the
Manufacturing2Client project, whose objective was to develop a
frontal deflector to be commercialized in the automotive industry,
using new project and manufacturing methods. In this task, in
particular, it was proposed to develop the ability to predict
computationally the aerodynamic influence of flow in vehicles, in an
effort to reduce fuel consumption in vehicles from class 3 to 8. With
this aim, two deflector models were developed and their aerodynamic
performance analyzed. The aerodynamic study was done using the
Computational Fluid Dynamics (CFD) software Ansys CFX and
allowed the calculation of the drag coefficient caused by the vehicle
motion for the different configurations considered. Moreover, the
reduction of diesel consumption and carbon dioxide (CO2) emissions
associated with the optimized deflector geometry could be assessed.
Abstract: The study is devoted to define the optimal conditions
for the nitriding of pure iron at atmospheric pressure by using NH3-
Ar-C3H8 gas mixtures. After studying the mechanisms of phase
formation and mass transfer at the gas-solid interface, a mathematical
model is developed in order to predict the nitrogen transfer rate in the
solid, the ε-carbonitride layer growth rate and the nitrogen and
carbon concentration profiles. In order to validate the model and to
show its possibilities, it is compared with thermogravimetric
experiments, analyses and metallurgical observations (X-ray
diffraction, optical microscopy and electron microprobe analysis).
Results obtained allow us to demonstrate the sound correlation
between the experimental results and the theoretical predictions.
Abstract: Reburning is a useful technology in reducing nitric
oxide through injection of a secondary hydrocarbon fuel. In this paper,
an experimental study has been conducted to evaluate the effect of fuel
lean reburning on NOx/CO reduction in LNG flame. Experiments
were performed in flames stabilized by a co-flow swirl burner, which
was mounted at the bottom of the furnace. Tests were conducted using
LNG gas as the reburn fuel as well as the main fuel. The effects of
reburn fuel fraction and injection manner of the reburn fuel were
studied when the fuel lean reburning system was applied. The paper
reports data on flue gas emissions and temperature distribution in the
furnace for a wide range of experimental conditions. At steady state,
temperature distribution and emission formation in the furnace have
been measured and compared. This paper makes clear that in order to
decrease both NOx and CO concentrations in the exhaust when the
pulsated fuel lean reburning system was adapted, it is important that
the control of some factors such as frequency and duty ratio. Also it
shows the fuel lean reburning is also effective method to reduce NOx
as much as reburning.
Abstract: Carbon nanotube is one of the most attractive materials
for the potential applications of nanotechnology due to its excellent
mechanical, thermal, electrical and optical properties. In this paper we
report a supercapacitor made of nickel foil electrodes, coated with
multiwall carbon nanotubes (MWCNTs) thin film using
electrophoretic deposition (EPD) method. Chemical vapor deposition
method was used for the growth of MWCNTs and ethanol was used as
a hydrocarbon source. High graphitic multiwall carbon nanotube was
found at 750oC analyzing by Raman spectroscopy. We observed the
electrochemical performance of supercapacitor by cyclic
voltammetry. The electrodes of supercapacitor fabricated from
MWCNTs exhibit considerably small equivalent series resistance
(ESR), and a high specific power density. Electrophoretic deposition
is an easy method in fabricating MWCNT electrodes for high
performance supercapacitor.
Abstract: Non-destructive testing and evaluation techniques for
assessing the integrity of composite structures are essential to both
reduce manufacturing costs and out of service time of transport means
due to maintenance. In this study, Analyze into non-destructive test
characterization of carbon fiber reinforced plastics (CFRP) internal
and external defects using thermo-graphic camera and transient
thermography method. non-destructive testing were characterized by
defect size (Ø8, Ø10, Ø12, Ø14) and depth (1.2mm, 2.4mm).
Abstract: In this study, epoxy composite specimens reinforced
with multi-walled carbon nanotube filler were fabricated using shear
mixer and ultra-sonication processor. The mechanical and thermal
properties of the fabricated specimens were measured and evaluated.
From the electron microscope images and the results from the
measurements of tensile strengths, the specimens having 0.6 wt%
nanotube content show better dispersion and higher strength than those
of the other specimens. The Young’s moduli of the specimens
increased as the contents of the nanotube filler in the matrix were
increased. The specimen having a 0.6 wt% nanotube filler content
showed higher thermal conductivity than that of the other specimens.
While, in the measurement of thermal expansion, specimens having
0.4 and 0.6 wt% filler contents showed a lower value of thermal
expansion than that of the other specimens. On the basis of the
measured and evaluated properties of the composites, we believe that
the simple and time-saving fabrication process used in this study was
sufficient to obtain improved properties of the specimens.
Abstract: The main purpose of this work was verify the
influence of the accelerated carbonation in the physical and
mechanical properties of the hybrid composites, reinforced with
micro and nanofibers and composites with microfibers. The
composites were produced by the slurry vacuum dewatering method,
followed by pressing. It was produced using two formulations: 8% of
eucalyptus pulp + 1% of the nanofibrillated cellulose and 9% of
eucalyptus pulp, both were subjected to accelerated carbonation. The
results showed that the accelerated carbonation contributed to
improve the physical and mechanical properties of the hybrid
composites and of the composites reinforced with microfibers
(eucalyptus pulp).
Abstract: In sheet metal forming process, raw material
mechanical properties are important parameters. This paper is to
compare the wall’s incline angle or formability of SS 400 steel and
SUS 304 stainless steel in single point incremental forming. The two
materials are ferrous base alloyed, which have the different unit cell,
mechanical property and chemical composition. They were forming
into cone shape specimens having 100 mm diameter with different
wall’s incline angle: 90o, 75o and 60o. The investigation was
continued until the specimens formed surface facture. The
experimental result showed that the smaller the wall incline angle
higher the formability with the both materials. The formability limit
of the ferrous base alloy was approx. 60o wall’s incline angle. By
nature, SS 400 has higher formability than SUS 304. This result can
be used as the initial data in designing the single point incremental
forming parts.
Abstract: This research work is concerned with the life cycle
assessment (LCA) of an expressway, as well as its infrastructure, in
Thailand. The life cycle of an expressway encompasses the raw
material acquisition phase, the construction phase, the use or service
phase, the rehabilitation phase, and finally the demolition and
disposal phase. The LCA in this research was carried out using CML
baseline 2000 and in accordance with the ISO 14040 standard. A
functional unit refers to transportation of one person over one
kilometer of a 3-lane expressway with a 50-year lifetime. This
research has revealed that the construction phase produced the largest
proportion of the environmental impact (81.46%), followed by the
service, rehabilitation, demolition and disposal phases and
transportation at 11.97%, 3.72% 0.33% and 2.52%, respectively. For
the expressway under study, the total carbon footprint over its
lifetime is equivalent to 245,639 tons CO2-eq per 1 kilometer
functional unit, with the phases of construction, service,
rehabilitation, demolition and disposal and transportation
contributing 153,690; 73,773; 3693, 755 and 13,728 tons CO2-eq,
respectively. The findings could be adopted as a benchmark against
which the environmental impacts of future similar projects can be
measured.
Abstract: The hydrogenated amorphous carbon films (α-C:H)
were deposited on p-type Si (100) substrates at different thicknesses by
radio frequency plasma enhanced chemical vapor deposition
technique (rf-PECVD). Raman spectra display asymmetric
diamond-like carbon (DLC) peaks, representative of the α-C:H films.
The decrease of intensity ID/IG ratios revealed the sp3 content arise at
different thicknesses of the α-C:H films. In terms of mechanical
properties, the high hardness and elastic modulus values showed the
elastic and plastic deformation behaviors related to sp3 content in
amorphous carbon films. Electrochemical properties showed that the
α-C:H films exhibited excellent corrosion resistance in air-saturated
3.5 wt.% NaCl solution for pH 2 at room temperature. Thickness
increasing affected the small sp2 clusters in matrix, restricting the
velocity transfer and exchange of electrons. The deposited α-C:H films
exhibited excellent mechanical properties and corrosion resistance.
Abstract: In this research article a comprehensive investigation
has been carried out to determine the effect of thermal cycle on
temperature dependent process parameters developed during gas
tungsten arc (GTA) welding of high carbon (AISI 1090) steel butt
joints. An experiment based thermal analysis has been performed to
obtain the thermal history. We have focused on different
thermophysical properties such as thermal conductivity, heat transfer
coefficient and cooling rate. Angular torch model has been utilized to
find out the surface heat flux and its variation along the fusion zone as
well as along the longitudinal direction from fusion boundary. After
welding and formation of weld pool, heat transfer coefficient varies
rapidly in the vicinity of molten weld bead and heat affected zone. To
evaluate the heat transfer coefficient near the fusion line and near the
rear end of the plate (low temperature region), established correlation
has been implemented and has been compared with empirical
correlation which is noted as coupled convective and radiation heat
transfer coefficient. Change in thermal conductivity has been
visualized by analytical model of moving point heat source. Rate of
cooling has been estimated by using 2-dimensional mathematical
expression of cooling rate and it has shown good agreement with
experimental temperature cycle. Thermophysical properties have been
varied randomly within 0 -10s time span.
Abstract: Magnetic powder of Sr-ferrite was prepared by
conventional and sol-gel auto-combustion methods. In conventional
method, strontium carbonate and ferric oxide powders were mixed
together and then mixture was calcined. In sol-gel auto-combustion
method, a solution containing strontium nitrate, ferric nitrate and
citric acid was heated until the combustion took place automatically;
then, as-burnt powder was calcined. Thermal behavior, phase
identification, morphology and magnetic properties of powders
obtained by these two methods were compared by DTA, XRD, SEM
and VSM techniques. According to the results of DTA analysis,
formation temperature of Sr-ferrite obtained by conventional and solgel
auto-combustion methods were 1300°C and 1000°C, respectively.
XRD results confirmed the formation of pure Sr-ferrite at the
mentioned temperatures. Plate and hexagonal-shape particles of Srferrite
were observed using SEM. The Sr-ferrite powder obtained by
sol-gel auto-combustion method had saturation magnetization of
66.03 emu/g and coercivity of 5731 Oe in comparison with values of
58.20 emu/g and 4378 Oe obtained by conventional method.
Abstract: Heightened concerns over the amount of carbon
emitted from coal-related processes are generating shifts to the
application of biomass. In co-gasification, where coal is gasified
along with biomass, the biomass may be fed together with coal (cofeeding)
or an independent biomass gasifier needs to be integrated
with the coal gasifier. The main aim of this work is to evaluate the
biomass introduction methods in coal co-gasification. This includes
the evaluation of biomass concentration input (B0 to B100) and its
gasification performance. A process model is developed and
simulated in Aspen HYSYS, where both coal and biomass are
modelled according to its ultimate analysis. It was found that the
syngas produced increased with increasing biomass content for both
co-feeding and independent schemes. However, the heating values
and heat duties decreases with biomass concentration as more CO2
are produced from complete combustion.