Abstract: Landfill leachates contain a number of persistent pollutants, including heavy metals. They have the ability to spread in ecosystems and accumulate in fish which most of them are classified as top-consumers of trophic chains. Fish are freely swimming organisms; but perhaps, due to their species-specific ecological and behavioral properties, they often prefer the most suitable biotopes and therefore, did not avoid harmful substances or environments. That is why it is necessary to evaluate the persistent pollutant dispersion in hydroecosystem using fish tissue metal concentration. In hydroecosystems of hybrid type (e.g. river-pond-river) the distance from the pollution source could be a perfect indicator of such a kind of metal distribution. The studies were carried out in the Kairiai landfill neighboring hybrid-type ecosystem which is located 5 km east of the Šiauliai City. Fish tissue (gills, liver, and muscle) metal concentration measurements were performed on two types of ecologically-different fishes according to their feeding characteristics: benthophagous (Gibel carp, roach) and predatory (Northern pike, perch). A number of mathematical models (linear, non-linear, using log and other transformations) have been applied in order to identify the most satisfactorily description of the interdependence between fish tissue metal concentration and the distance from the pollution source. However, the only one log-multiple regression model revealed the pattern that the distance from the pollution source is closely and positively correlated with metal concentration in all predatory fish tissues studied (gills, liver, and muscle).
Abstract: The present study investigates the effectiveness of
newly designed clayey pellets (fired clay pellets diameter sizes of 5
and 8 mm, and unfired clay pellets with the diameter size of 15 mm)
as the beds in the column adsorption process. The adsorption
experiments in the batch mode were performed before the column
experiment with the purpose to determine the order of adsorbent
package in the column which was to be designed in the investigation.
The column experiment was performed by using a known mass of the
clayey beds and the volume of the waste printing developer, which
was purified. The column was filled in the following order: fired clay
pellets of the diameter size of 5 mm, fired clay pellets of the diameter
size of 8 mm, and unfired clay pellets of the diameter size of 15 mm.
The selected order of the adsorbents showed a high removal
efficiency for zinc (97.8%) and copper (81.5%) ions. These
efficiencies were better than those in the case of the already existing
mode adsorption. The obtained experimental data present a good
basis for the selection of an appropriate column fill, but further
testing is necessary in order to obtain more accurate results.
Abstract: Landfill waste is a common problem as it has an
economic and environmental impact even if it is closed. Landfill
waste contains a high density of various persistent compounds such
as heavy metals, organic and inorganic materials. As persistent
compounds are slowly-degradable or even non-degradable in the
environment, they often produce sublethal or even lethal effects on
aquatic organisms. The aims of the present study were to estimate
sublethal effects of the Kairiai landfill (WGS: 55°55‘46.74“,
23°23‘28.4“) leachate on the locomotor activity of rainbow trout
Oncorhynchus mykiss juveniles using the original system package
developed in our laboratory for automated monitoring, recording and
analysis of aquatic organisms’ activity, and to determine patterns of
fish behavioral response to sublethal effects of leachate. Four
different concentrations of leachate were chosen: 0.125; 0.25; 0.5 and
1.0 mL/L (0.0025; 0.005; 0.01 and 0.002 as part of 96-hour LC50,
respectively). Locomotor activity was measured after 5, 10 and 30
minutes of exposure during 1-minute test-periods of each fish (7 fish
per treatment). The threshold-effect-concentration amounted to 0.18
mL/L (0.0036 parts of 96-hour LC50). This concentration was found
to be even 2.8-fold lower than the concentration generally assumed to
be “safe” for fish. At higher concentrations, the landfill leachate
solution elicited behavioral response of test fish to sublethal levels of
pollutants. The ability of the rainbow trout to detect and avoid
contaminants occurred after 5 minutes of exposure. The intensity of
locomotor activity reached a peak within 10 minutes, evidently
decreasing after 30 minutes. This could be explained by the
physiological and biochemical adaptation of fish to altered
environmental conditions. It has been established that the locomotor
activity of juvenile trout depends on leachate concentration and
exposure duration. Modeling of these parameters showed that the
activity of juveniles increased at higher leachate concentrations, but
slightly decreased with the increasing exposure duration. Experiment
results confirm that the behavior of rainbow trout juveniles is a
sensitive and rapid biomarker that can be used in combination with
the system for fish behavior monitoring, registration and analysis to
determine sublethal concentrations of pollutants in ambient water.
Further research should be focused on software improvement aimed
to include more parameters of aquatic organisms’ behavior and to
investigate the most rapid and appropriate behavioral responses in
different species. In practice, this study could be the basis for the
development and creation of biological early-warning systems
(BEWS).
Abstract: The paper presents an additive manufacturing process for the production of metal and composite parts. It is termed as composite metal foil manufacturing and is a combination of laminated object manufacturing and brazing techniques. The process has been described in detail and is being used to produce dissimilar aluminum to copper foil single lap joints. A three dimensional finite element model has been developed to study the thermo-mechanical characteristics of the dissimilar Al/Cu single lap joint. The effects of thermal stress and strain have been analyzed by carrying out transient thermal analysis on the heated plates used to join the two 0.1mm thin metal foils. Tensile test has been carried out on the foils before joining and after the single Al/Cu lap joints are made, they are subjected to tensile lap-shear test to analyze the effect of heat on the foils. The analyses are designed to assess the mechanical integrity of the foils after the brazing process and understand whether or not the heat treatment has an effect on the fracture modes of the produced specimens.
Abstract: The study assessed the effectiveness of Pawpaw
(Carica papaya) wood in reducing the concentrations of heavy
metals in wastewater acting as a bio-sorbent. The following heavy
metals were considered; Zinc, Cadmium, Lead, Copper, Iron,
Selenium, Nickel and Manganese. The physiochemical properties of
Carica papaya stem were studied. The experimental sample was
sourced from the trunk of a felled matured pawpaw tree. Wastewater
for experimental use was prepared by dissolving soil samples
collected from a dump site at Owerri, Imo state of Nigeria in water.
The concentration of each metal remaining in solution as residual
metal after bio-sorption was determined using Atomic absorption
Spectrometer. The effects of pH and initial heavy metal concentration
were studied in a batch reactor. The results of Spectrometer test
showed that there were different functional groups detected in the
Carica papaya stem biomass. There was increase in metal removal as
the pH increased for all the metals considered except for Nickel and
Manganese. Optimum bio-sorption occurred at pH 5.9 with 5g/100ml
solution of bio-sorbent. The results of the study showed that the
treated wastewater is fit for irrigation purpose based on Canada
wastewater quality guideline for the protection of Agricultural
standard. This approach thus provides a cost effective and
environmentally friendly option for treating wastewater.
Abstract: In the present work, forming limit diagrams and strain
distribution profile diagrams for extra deep drawing steel at room and
elevated temperatures have been determined experimentally by
conducting stretch forming experiments by using designed and
fabricated warm stretchforming tooling setup. With the help of
forming Limit Diagrams (FLDs) and strain, distribution profile
diagrams the formability of Extra Deep Drawing steel has been
analyzed and co-related with mechanical properties like strain
hardening COEFFICIENT (n) and normal anisotropy (r−). Mechanical
properties of EDD steel from room temperature to 4500C were
determined and discussed the impact of temperature on the properties
like work hardening exponent (n) anisotropy (r-) and strength
coefficient of the material. In addition, the fractured surfaces after
stretching have undergone the some metallurgical investigations and
attempt has been made to co-relate with the formability of EDD steel
sheets. They are co-related and good agreement with FLDs at various
temperatures.
Abstract: This paper focuses on the mathematical modeling for
solidification of Al alloy in a cube mold cavity to study the
solidification behavior of casting process. The parametric
investigation of solidification process inside the cavity was
performed by using computational solidification/melting model
coupled with Volume of fluid (VOF) model. The implicit filling
algorithm is used in this study to understand the overall process from
the filling stage to solidification in a model metal casting process.
The model is validated with past studied at same conditions. The
solidification process is analyzed by including the effect of pouring
velocity as well as natural convection from the wall and geometry of
the cavity. These studies show the possibility of various defects
during solidification process.
Abstract: In the present study, feasibility of the selective surface
hydrophilization of polyvinyl chloride (PVC) by microwave treatment
was evaluated to facilitate the separation from automotive shredder
residue (ASR), by the froth flotation. The combination of 60 sec
microwave treatment with PAC, a sharp and significant decrease about
16.5° contact angle of PVC was observed in ASR plastic compared
with other plastics. The microwave treatment with the addition of PAC
resulted in a synergetic effect for the froth flotation, which may be a
result of the 90% selective separation of PVC from ASR plastics, with
82% purity. While, simple mixing with a nanometallic Ca/CaO/PO4
dispersion mixture immobilized 95-100% of heavy metals in ASR
soil/residues. The quantity of heavy metals leached from thermal
residues after treatment by nanometallic Ca/CaO/PO4 was lower than
the Korean standard regulatory limit for hazardous waste landfills.
Microwave treatment can be a simple and effective method for PVC
separation from ASR plastics.
Abstract: Lead being a toxic heavy metal that mankind is
exposed to the highest levels of this metal. There are different sources
of environmental pollution with lead as lead alkyl additives in petrol
and manufacturing processes. The contaminated atmosphere in urban
and industrial areas by lead in Egypt may lead to the contamination
of foods beside the other different sources. The present investigation
studied the risk assessment of lead in some Egyptian edible
vegetables and fruits collected from different environments in Greater
Cairo Governorate, i.e. industrial, heavy traffic and rural areas. A
total of 325 leafy and fruity vegetables and fruits samples belonging
to 11, 6 and 4 different species, respectively were randomly collected
from markets of the three main models. Data indicated the variation
of lead levels in different three areas. The highest levels of lead were
detected in the samples collected from industrial and traffic areas.
However, the lowest levels were found in the rural areas. It could be
concluded that determination of lead levels in foods from different
localities and environments at regularly is very important.
Abstract: The photovoltaic and the semiconductor industries are
in growth and it is necessary to supply a large amount of silicon to
maintain this growth. Since silicon is still the best material for the
manufacturing of solar cells and semiconductor components so the
pure silicon like solar grade and semiconductor grade materials are
demanded. There are two main routes for silicon production:
metallurgical and chemical. In this article, we reviewed the
electrotecnological installations and systems for semiconductor
manufacturing. The main task is to design the installation which can
produce SOG Silicon from river sand by one work unit.
Abstract: In this paper, we calculate the two-photon ionization
(TPI) cross-section for pump-probe scheme in Ag neutral cluster. The
pump photon energy is assumed to be close to the surface plasmon
(SP) energy of cluster in dielectric media. Due to this choice, the
pump wave excites collective oscillations of electrons-SP and the
probe wave causes ionization of the cluster. Since the interband
transition energy in Ag exceeds the SP resonance energy, the main
contribution into the TPI comes from the latter. The advantage of Ag
clusters as compared to the other noble metals is that the SP
resonance in silver cluster is much sharper because of peculiarities of
its dielectric function. The calculations are performed by separating
the coordinates of electrons corresponding to the collective
oscillations and the individual motion that allows taking into account
the resonance contribution of excited SP oscillations. It is shown that
the ionization cross section increases by two orders of magnitude if
the energy of the pump photon matches the surface plasmon energy
in the cluster.
Abstract: The research on thermoelectric has been a blooming field of research for the latest decade, owing to large amount of heat source available to be harvested, being eco-friendly and static in operation. This paper provides the performance of thermoelectric generator (TEG) with bulk material of bismuth telluride, Bi2Te3. Later, the performance of the TEGs is evaluated by considering attaching the TEGs on a plastic (polyethylene sheet) in contrast to the common method of attaching the TEGs on the metal surface.
Abstract: This research paper portrays a comparative analysis of
thermomechanical behaviour of Shielded Metal Arc Welding
(SMAW) and Gas Tungsten Arc Welding (GTAW) of low carbon
steel of AISI 1020 grade butt joints. The thermal history has been
obtained by experimental work. We have focused on temperature
dependent cooling rate as depicted by Adam’s two-dimensional
model. The effect of moving point heat source of SMAW and GTAW
on mechanical properties has been judged by optical and scanning
electron micrographs of different regions in weld joints. The
microhardness study has been carried to visualize the joint strength
due to formation of different phases.
Abstract: The plastic industry plays very important role in the
economy of any country. It is generally among the leading share of
the economy of the country. Since metals and their alloys are very
rarely available on the earth. Therefore, to produce plastic products
and components, which finds application in many industrial as well
as household consumer products is beneficial. Since 50% plastic
products are manufactured by injection moulding process. For
production of better quality product, we have to control quality
characteristics and performance of the product. The process
parameters plays a significant role in production of plastic, hence the
control of process parameter is essential. In this paper the effect of
the parameters selection on injection moulding process has been
described. It is to define suitable parameters in producing plastic
product. Selecting the process parameter by trial and error is neither
desirable nor acceptable, as it is often tends to increase the cost and
time. Hence, optimization of processing parameter of injection
moulding process is essential. The experiments were designed with
Taguchi’s orthogonal array to achieve the result with least number of
experiments. Plastic material polypropylene is studied. Tensile
strength test of material is done on universal testing machine, which
is produced by injection moulding machine. By using Taguchi
technique with the help of MiniTab-14 software the best value of
injection pressure, melt temperature, packing pressure and packing
time is obtained. We found that process parameter packing pressure
contribute more in production of good tensile plastic product.
Abstract: The fundamental issue in understanding the origin and
growth mechanism of nanomaterials, from a fundamental unit is a big
challenging problem to the scientists. Recently, an immense attention
is generated to the researchers for prediction of exceptionally stable
atomic cluster units as the building units for future smart materials.
The present study is a systematic investigation on the stability and
electronic properties of a series of bimetallic (semiconductor-alkaline
earth) clusters, viz., BxMg3 (x=1-5) is performed, in search for
exceptional and/ or unusual stable motifs. A very popular hybrid
exchange-correlation functional, B3LYP along with a higher basis
set, viz., 6-31+G[d,p] is employed for this purpose under the density
functional formalism. The magic stability among the concerned
clusters is explained using the jellium model. It is evident from the
present study that the magic stability of B4Mg3
cluster arises due to
the jellium shell closure.
Abstract: The laser-ultrasonic method is realized for
quantifying the influence of porosity on the local Young’s
modulus of isotropic composite materials. The method is based on
a laser thermooptical method of ultrasound generation combined
with measurement of the phase velocity of longitudinal and shear
acoustic waves in samples. The main advantage of this method
compared with traditional ultrasonic research methods is the
efficient generation of short and powerful probing acoustic pulses
required for reliable testing of ultrasound absorbing and
scattering heterogeneous materials. Using as an example samples
of a metal matrix composite with reinforcing microparticles of
silicon carbide in various concentrations, it is shown that to
provide an effective increase in Young’s modulus with increasing
concentration of microparticles, the porosity of the final sample
should not exceed 2%.
Abstract: Excessive fretting wear at the taper-trunnion junction
(trunnionosis) apparently contributes to the high failure rates of hip
implants. Implant wear and corrosion lead to the release of metal
particulate debris and subsequent release of metal ions at the tapertrunnion
surface. This results in a type of metal poisoning referred to
as metallosis. The consequences of metal poisoning include;
osteolysis (bone loss), osteoarthritis (pain), aseptic loosening of the
prosthesis and revision surgery. Follow up after revision surgery,
metal debris particles are commonly found in numerous locations. Background: A stable connection between the femoral ball head
(taper) and stem (trunnion) is necessary to prevent relative motions
and corrosion at the taper junction. Hence, the importance of
component assembly cannot be over-emphasized. Therefore, the aim
of this study is to determine the influence of head-stem junction
assembly by press fitting and the subsequent
disengagement/disassembly on the connection strength between the
taper ball head and stem. Methods: CoCr femoral heads were assembled with High stainless
hydrogen steel stem (trunnion) by Push-in i.e. press fit; and
disengaged by pull-out test. The strength and stability of the two
connections were evaluated by measuring the head pull-out forces
according to ISO 7206-10 standards. Findings: The head-stem junction strength linearly increases with
assembly forces.
Abstract: The wider growing Finite Element Method (FEM)
application is caused by its benefits of cost saving and environment
friendly. Also, by using FEM a deep understanding of certain
phenomenon can be achieved. This paper observed the role of
material properties and volumetric change when Solid State Phase
Transformation (SSPT) takes place in residual stress formation due to
a welding process of ferritic steels through coupled Thermo-
Metallurgy-Mechanical (TMM) analysis. The correctness of FEM residual stress prediction was validated by
experiment. From parametric study of the FEM model, it can be
concluded that the material properties change tend to over-predicts
residual stress in the weld center whilst volumetric change tend to
underestimates it. The best final result is the compromise of both by
incorporates them in the model which has a better result compared to
a model without SSPT.
Abstract: The objective of the paper is a numerical study of heat
transfer between perforated metal plates and the surrounding air
flows. Different perforation structures can nowadays be found in
various industrial products. Besides improving the mechanical
properties, the perforations can intensify the heat transfer as well. The
heat transfer coefficient depends on a wide range of parameters such
as type of perforation, size, shape, flow properties of the surrounding
air etc. The paper was focused on three different perforation
structures which have been investigated from the point of the view of
the production in the previous studies. To determine the heat
coefficients and the Nusselt numbers, the numerical simulation
approach was adopted. The calculations were performed using the
OpenFOAM software. The three-dimensional, unstable, turbulent and
incompressible air flow around the perforated surface metal plate was
considered.
Abstract: Here, we have shown the reaction of [Cr(ArN(CH2)3NAr)2Cl2] (1) where (Ar = 2,6-Pri
2C6H3) and in presence of NaCp (2) (Cp= C5H5 = cyclopentadien), with a center
coordination η5 interaction between Cp as co-ligand and chromium
metal center, for optimization we used density functional theory
(DFT), under methods, explicitly including electrons correlations, for
the final calculations as MB3LYP (Becke) (Lee–Yang–Parr) level of
theory we used to obtain more exact results. This complex was
calculated as electronic energy for molecular system, because the
calculation accounting all electrons correlations interactions. The
optimised of [Cr(ArN(CH2)3NAr)2(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp = C5H5) was found to be thermally stable. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis
and showed the highest occupied molecular orbital (HOMO) and
lowest occupied molecular orbital LUMO.