Abstract: The present study investigates the effectiveness of
newly designed clayey pellets (fired clay pellets diameter sizes of 5
and 8 mm, and unfired clay pellets with the diameter size of 15 mm)
as the beds in the column adsorption process. The adsorption
experiments in the batch mode were performed before the column
experiment with the purpose to determine the order of adsorbent
package in the column which was to be designed in the investigation.
The column experiment was performed by using a known mass of the
clayey beds and the volume of the waste printing developer, which
was purified. The column was filled in the following order: fired clay
pellets of the diameter size of 5 mm, fired clay pellets of the diameter
size of 8 mm, and unfired clay pellets of the diameter size of 15 mm.
The selected order of the adsorbents showed a high removal
efficiency for zinc (97.8%) and copper (81.5%) ions. These
efficiencies were better than those in the case of the already existing
mode adsorption. The obtained experimental data present a good
basis for the selection of an appropriate column fill, but further
testing is necessary in order to obtain more accurate results.
Abstract: The adsorption efficiency of fired clayey pellets of 5
and 8 mm diameter size for Cu(II) and Zn(II) ion removal from a
waste printing developer was studied. In order to investigate the
influence of contact time, adsorbent mass and pellet size on the
adsorption efficiency the batch mode was carried out. Faster uptake
of copper ion was obtained with the fired clay pellets of 5 mm
diameter size within 30 minutes. The pellets of 8 mm diameter size
showed the higher equilibrium time (60 to 75 minutes) for copper and
zinc ion. The results pointed out that adsorption efficiency increases
with the increase of adsorbent mass. The maximal efficiency is
different for Cu(II) and Zn(II) ion due to the pellet size. Therefore,
the fired clay pellets of 5 mm diameter size present an effective
adsorbent for Cu(II) ion removal (adsorption efficiency is 63.6%),
whereas the fired clay pellets of 8 mm diameter size are the best
alternative for Zn(II) ion removal (adsorption efficiency is 92.8%)
from a waste printing developer.
Abstract: The adsorption efficiency of various adsorbents for the removal of Zn(II) ions from the waste printing developer was studied in laboratory batch mode. The maximum adsorption efficiency of 94.1% was achieved with unfired clay pellets size (d ≈ 15 mm). The obtained values of adsorption efficiency was subjected to the independent-samples t test in order to investigate the statistically significant differences of the investigated adsorbents for the effective removal of Zn(II) ions from the waste printing developer. The most statistically significant differences of adsorption efficiencies for Zn(II) ions removal were obtained between unfired clay pellets (size d ≈ 15 mm) and activated carbon (½t½=6.909), natural zeolite (½t½=10.380), mixture of activated carbon and natural zeolite (½t½=9.865), bentonite (½t½=6.159), fired clay (½t½=6.641), fired clay pellets (size d ≈ 5 mm) (½t½=6.678), fired clay pellets (size d ≈ 8 mm) (½t½=3.422), respectively.