The Evaluation of Heavy Metal Pollution Degree in the Soils around the Zangezur Copper and Molybdenum Combine

The heavy metal pollution degree in the soils around
the Zangezur copper and molybdenum combine in Syunik Marz,
Armenia was assessed. The results of the study showed that heavy
metal pollution degree in the soils mainly decreased with increasing
distance from the open mine and the ore enrichment combine which
indicated that the open mine and the ore enrichment combine were
the main sources of heavy metal pollution. The only exception was
observed in the northern part of the open mine where pollution
degree in the sites (along the open mine) situated 600 meters far from
the mine was higher than that in the sites located 300 meters far from
the mine. This can be explained by the characteristics of relief and air
currents as well as the weak vegetation cover of these sites and the
characteristics of soil structure. According to geo-accumulation index
(I-geo), contamination factor (Cf), contamination degree (Cd) and
pollution load index (PLI) values, the pollution degree in the soils
around the open mine and the ore enrichment combine was higher
than that in the soils around the tailing dumps which was due to the
proper and accurate operation of the Artsvanik tailing damp and the
recultivation of the Voghji tailing dump.
The high Cu and Mo pollution of the soils was conditioned by the
character of industrial activities, the moving direction of air currents
as well as the physicochemical peculiarities of the soils.





References:
[1] S. Davydova, “Heavy metals as toxicants in big cities,” Microchemical
Journal, vol. 79, no. 1-2, pp. 133–136, 2005.
[2] ISO 19258:2005, Soil quality - Guidance on the determination of
background values, 2005.
[3] M. Friedlova, “The Influence of heavy metals on soil biological and
chemical properties,” Soil and Water Research, vol. 5, no. 1, pp. 21–27,
2010.
[4] O. Mikanova, “Effects of heavy metals on some soil biological
parameters,” Journal of Geochemical Exploration, vol. 88, pp. 220–223,
2006.
[5] Toxic metals in soil–plant systems, Ross S. M., Ed. John Wiley & Sons,
Chichester, 1994.
[6] M. P. Benavides, S. M. Gallego, M. L. Tomaro, “Cadmium toxicity in
plants,” Brazilian Journal of Plant Physiology, vol. 17, pp. 21-34, 2005.
[7] K. E. Giller, E. Witter, S. P. McGrath, “Toxicity of heavy metals to
microorganisms and microbial processes in agricultural soils,” Soil
Biology and Biochemistry, vol. 30, pp. 1389–1414, 1998.
[8] A. Waoo, S. Khare, S. Ganguly, “Unconventional plant-based
remediation technologies for soil pollution at contaminated sites in
Bhopal,” International Journal of Engineering and Advanced
Technology, vol. 1, no. 1, pp. 41-44, 2011.
[9] Yu M., Tsunoda H., Tsunoda M. Environmental Toxicology: Biological
and Health Effects of Pollutants, Third Edition. CRC Press, 2011.
[10] K. Ghazaryan, G. Gevorgyan, K. Grigoryan, “Evaluation of pollution
level of soils of ecologically vulnerable areas around Agarak town and
suggestion of improvement ways,” in Proc. 4th Int. Cong. EUROSOIL
2012 – Soil Science for the Benefit of Mankind and Environment, Bari,
2012, p. 2351.
[11] S. Caeiro, M. H. Costa, T. B. Ramos, “Assessing Heavy Metal
Contamination in Sado Estuary Sediment: An Index Analysis
Approach,” Ecological Indicators, vol. 5, pp. 151–169, 2005.
[12] J. L. Cheng, Z. Shi, Y. W. Zhu, “Assessment and Mapping of
Environmental Quality in Agricultural Soils of Zhejiang Province,
China,” Journal of Environmental Sciences, vol. 19, pp. 50–54, 2007.
[13] R. A. Edilyan, Atlas of Soils of the Republic of Armenia. Yerevan, 1990
(in Russian).
[14] L. Hakanson, “An Ecological Risk Index for Aquatic Pollution Control:
A Sedimentological Approach,” Water Research, vol. 14, pp. 975–1001,
1980.
[15] D. C. Thomilson, D. J. Wilson, C. R. Harris, D. W. Jeffrey, “Problem in
heavy metals in estuaries and the formation of pollution index,” Helgol.
Wiss. Meeresunlter., vol. 33 no. 1–4, pp. 566–575, 1980.
[16] G. Muller, “Index of geoaccumulation in sediments of the Rhine River,”
Geol. J., vol. 2 no. 3, pp. 108–118, 1969.
[17] K. O. Adebowale, F. O. Agunbide, B. Olu-Owolabi, “Trace metal
concentration, site variations and partitioning pattern in water and
bottom sediments from coastal area: A case study of Ondo Coast,
Nigeria,” Environmental Research Journal, vol. 3, no. 2, pp. 46-59,
2009.