Relationship of Reaction Temperature on Phosphate Oligomers Reactivity to Properties of Soy-Polyurethane
Polyurethane foam (PUF) were prepared by
reacting polyols synthesized from soy-oil into mixture of 2,4-
Toluene diisocyanate (TDI) with 4,4--Methylene Diamine
Isocyanate (MDI) with ratio of 70:30. The polyols obtained
via esterification reaction were categorize into different
temperature of reaction and by used of varied concentration
of phosphoric acid catalyst. The purpose of catalysts is to
shifting selectivity to a desired and value added of product.
The effect of stoichiometric balance (molar ratio of
epoxide/ethylene glycol) to the concentration of the catalyst
on the final properties was evaluated.
[1] R. Herrington, K. Hock, Flexible Foams. The Dow Chemical Company,
Midland, MI, 1997.
[2] U. Biermann et.al, Angewandte Chemie International Edition, 39, 2206
(2000).
[3] Y.-C. Tu, G. J. Suppes, F.H.-Hsieh, Journal of Applied Polymer
Science, 105, 453 (2007).
[4] H. Baumann et. Al., J. Natural Fats and OilsÔÇöRenewable Raw Materials
for the Chemical Industry. Angew. Chem. Int. Ed. Engl. 1988, 27, 41-
62.
[5] U.Biermann et. al. New Syntheses with Oils and Fats as Renewable Raw
Materials for the Chemical Industry. Angew. Chem. Int. Ed. 2000, 39,
2206-2224.
[6] V. Sharma, Kundu, P.P. Addition Polymers from Natural OilsÔÇöA
Review. Prog. Polym. Sci. 2006, 31, 983-1008.
[7] Y Guo ; Hardesty, J.H.; Mannari, V.M.; Massingill, J.J.L. Hydrolysis of
Epoxidized Soybean Oil in the Presence of Phosphoric Acid. J. Am. Oil
Chem. Soc. 2007, 84, 929-935.
[8] H.P Zhao, Zhang, J.F.; Susan S.X.; Hua, D.H. Synthesis and Properties
of Crosslinked Polymers from Functionalized Triglycerides. J. Appl.
Polym. Sci. 2008, 110, 647-656.
[9] S. Gryglewicz; Piechocki, W.; Gryglewicz, G. Preparation of Polyol
Esters Based on Vegetable and Animal Fats. Bior. Tech. 2003, 87, 35-
39.
[10] A. Campanella .; Bonnaillie, L.M.; Wool, R.P. Polyurethane Foams
from Soyoil-based Polyols. J. Appl. Polym. Sci. 2009, 112, 2567-2578.
[11] S.S. Narine,; Tue, J.; Kong, X. Production of Polyols from Canola Oil
and their Chemical Identification and Physical Properties. J. Am. Oil
Chem. Soc. 2007, 84, 173-179.
[12] X. Kong ; Narine, S.S. Physical Properties of Canola Oil Based
Polyurethane Networks. Biomacromolecules 2007, 8, 3584-3589.
[13] L. Hojabri ; Kong, X.; Narine, S.S. Functional Thermoplastics from
Linear Diols and Diisocyanates Produced Entirely from Renewable
Lipid Sources. Biomacromolecules 2010, 11, 911-918.
[14] Xu, Y.; Petrovic, Z.S.; Das, S.; Wilkes, G.L. Morphology and Properties
of Thermoplastic Polyurethanes with Dangling Chains in Ricinoleatebased
Soft Segments. Polymer 2008, 49, 4248-4258.
[15] A. Guo, W. Zhang, Z. S. Petrovic, Journal of Materials Science, 41,
4914 (2006).
[16] http://www.greendaily.com/2008/03/21/cargills-bioh-polyols-makecomfy-
more-earth-friendly/.
[17] http://www.biobasedpolyol.com/.
[1] R. Herrington, K. Hock, Flexible Foams. The Dow Chemical Company,
Midland, MI, 1997.
[2] U. Biermann et.al, Angewandte Chemie International Edition, 39, 2206
(2000).
[3] Y.-C. Tu, G. J. Suppes, F.H.-Hsieh, Journal of Applied Polymer
Science, 105, 453 (2007).
[4] H. Baumann et. Al., J. Natural Fats and OilsÔÇöRenewable Raw Materials
for the Chemical Industry. Angew. Chem. Int. Ed. Engl. 1988, 27, 41-
62.
[5] U.Biermann et. al. New Syntheses with Oils and Fats as Renewable Raw
Materials for the Chemical Industry. Angew. Chem. Int. Ed. 2000, 39,
2206-2224.
[6] V. Sharma, Kundu, P.P. Addition Polymers from Natural OilsÔÇöA
Review. Prog. Polym. Sci. 2006, 31, 983-1008.
[7] Y Guo ; Hardesty, J.H.; Mannari, V.M.; Massingill, J.J.L. Hydrolysis of
Epoxidized Soybean Oil in the Presence of Phosphoric Acid. J. Am. Oil
Chem. Soc. 2007, 84, 929-935.
[8] H.P Zhao, Zhang, J.F.; Susan S.X.; Hua, D.H. Synthesis and Properties
of Crosslinked Polymers from Functionalized Triglycerides. J. Appl.
Polym. Sci. 2008, 110, 647-656.
[9] S. Gryglewicz; Piechocki, W.; Gryglewicz, G. Preparation of Polyol
Esters Based on Vegetable and Animal Fats. Bior. Tech. 2003, 87, 35-
39.
[10] A. Campanella .; Bonnaillie, L.M.; Wool, R.P. Polyurethane Foams
from Soyoil-based Polyols. J. Appl. Polym. Sci. 2009, 112, 2567-2578.
[11] S.S. Narine,; Tue, J.; Kong, X. Production of Polyols from Canola Oil
and their Chemical Identification and Physical Properties. J. Am. Oil
Chem. Soc. 2007, 84, 173-179.
[12] X. Kong ; Narine, S.S. Physical Properties of Canola Oil Based
Polyurethane Networks. Biomacromolecules 2007, 8, 3584-3589.
[13] L. Hojabri ; Kong, X.; Narine, S.S. Functional Thermoplastics from
Linear Diols and Diisocyanates Produced Entirely from Renewable
Lipid Sources. Biomacromolecules 2010, 11, 911-918.
[14] Xu, Y.; Petrovic, Z.S.; Das, S.; Wilkes, G.L. Morphology and Properties
of Thermoplastic Polyurethanes with Dangling Chains in Ricinoleatebased
Soft Segments. Polymer 2008, 49, 4248-4258.
[15] A. Guo, W. Zhang, Z. S. Petrovic, Journal of Materials Science, 41,
4914 (2006).
[16] http://www.greendaily.com/2008/03/21/cargills-bioh-polyols-makecomfy-
more-earth-friendly/.
[17] http://www.biobasedpolyol.com/.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:49888", author = "Flora Elvistia Firdaus", title = "Relationship of Reaction Temperature on Phosphate Oligomers Reactivity to Properties of Soy-Polyurethane", abstract = "Polyurethane foam (PUF) were prepared by
reacting polyols synthesized from soy-oil into mixture of 2,4-
Toluene diisocyanate (TDI) with 4,4--Methylene Diamine
Isocyanate (MDI) with ratio of 70:30. The polyols obtained
via esterification reaction were categorize into different
temperature of reaction and by used of varied concentration
of phosphoric acid catalyst. The purpose of catalysts is to
shifting selectivity to a desired and value added of product.
The effect of stoichiometric balance (molar ratio of
epoxide/ethylene glycol) to the concentration of the catalyst
on the final properties was evaluated.", keywords = "temperature, phosphate, soy polyurethane", volume = "5", number = "4", pages = "251-5", }
