Iron Doped Biomaterial Calcium Borate: Synthesis and Characterization
Colemanite is the most common borate mineral, and the main source of the boron required by plants, human, and earth. Transition metals exhibit optical and physical properties such as; non-linear optical character, structural diversity, thermal stability, long cycle life and luminescent radiation. The doping of colemanite with a transition metal, bring it very interesting and attractive properties which make them applicable in industry. Iron doped calcium borate was synthesized by conventional solid state method at 1200 °C for 12 h with a systematic pathway. X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy/energy dispersive analyze (SEM/EDS) were used to characterize structural and morphological properties. Also, thermal properties were recorded by thermogravimetric-differential thermal analysis (TG/DTA).
[1] F. D. Kurtuluş, “Synthesis and characterization of metal containing borate, phosphate and borophosphate compounds by hydrothermal and microwave methods,” PhD thesis, 2003, Balıkesir University, Turkey
[2] B. Tekin, “Syntheses and structural characterization of certain compound of metal borates, phosphates and borophosphates,” PhD thesis, 2007, Balıkesir University, Turkey.
[3] R. A. Smith, R. B. Brom, “Boron compounds, oxides, acid, borates, Kirk-Othmer Encyclopedia of Chemical Technology, Wiley, New York, 1992.
[4] R. M. Adams, “Boron, metallo-boron compounds and boranes, Wiley-Interscience, New York, 1964.
[5] A. H. Silver, J. Chem. Phys., vol. 32, pp. 959, 1960.
[6] K. Goetzman, D. Karlheinz, N. H. Dieter, G. Ralf, Patent CA, C09K015, 1996.
[7] Y. Zhang, J. K. Liang, X. L. Chen, M. He, T. Xu, J. Alloys and Comp., vol. 327, pp. 96, 2001.
[8] Y. Zhang, X. L. Chen, J. K. Liang, T. Xu, J. Alloys and Comp., vol. 333, pp. 72, 2002.
[9] J. L. C., Rowsell, N. J. Taylor, L. F. Nazar, J. Solid State Chem., vol. 174, pp. 189, 2003.
[10] H. Huppertz, S. Altmonnshofer, and G. Heymann, “High-pressure preparation, crystal structure, and properties of the new rare-earth oxoborate β-Dy2B4O9,” J. Solid State Chem., vol. 170, no. 2, pp. 320‒329, Feb. 2003.
[11] G. Güzel, “Synthesis of some type of lithium and boron rich chemical compounds and analyzed theirs structural properties by XRD,” MSc. thesis, 2006, Balıkesir University, Turkey.
[12] G. Zhang, Y. Wu, P. Fu, G. Wang, H. Liu, G. Fan, and C. Chen, “A new sodium samarium borate Na3Sm2(BO3)3,” J. Phys. Chem. Solid, vol. 63, no. 1, pp. 145‒149, Jan. 2002.
[13] S. Lemanceau, G. C. Bertrand, R. Mahiou, M. El-Ghozzi, J. C. Cousseins, P. Conflnt, and R. N. Vannier, “Synthesis and characterization of H-LnBO3orthoborates (Ln=La, Nd, Sm, and Eu),” J. Solid State Chem., vol. 148, no. 2, pp. 229‒235, Dec. 1999.
[14] S. Somunkıranoglu, “The synthesis and characterization of oxide and vanadate types of compounds containing some double metals,” MSc thesis, 2014, Balıkesir University, Turkey.
[15] Y. Shi, J. Liang, H. Zhang, J. Yang, W. Zhuang, and G. Rao, “X-Ray powder diffraction and vibrational spectra studies of rare earth borophosphates, Ln7O6(BO3)(PO4)2(Ln=La, Nd, Gd, and Dy),” J. Solid State Chem.,vol. 129, no. 1, pp. 45‒52, Feb. 1997.
[16] M. Yerli, “The synthesis and characterization of some metal containing borate, phosphate and vanadate compounds,” MSc. thesis, 2009, Balıkesir University, Turkey.
[17] S. Sarıkaya Gacanoğlu, “The solid state chemical synthesis and characterization studies of some new type double metal orthoborate compounds,” PhD thesis, 2009, Balıkesir University, Turkey.
[18] Y. Zhang, X. L. Chen, J. K. Liang, and T. Xu, “Synthesis and structural study of new rare earth sodium borates Na3Ln(BO3)2 (Ln=Y, Gd),” J. Alloys and Comp., vol. 333, no. 1‒2, pp. 72‒75, Feb. 2002.
[19] M. Taşdemir, “Some theorical applications of Rietveld analysis via GSAS computer program on powder crystal systems,” MSc. thesis, 2008, Balıkesir University, Turkey.
[20] G. Gözel, A. Baykal, M. Kızılyallı, and R. Kniep, “Optimizing the dispersion on an alumina suspension using commercial polyvalent electrolyte dispersants,” J. Europ. Ceram. Soc., vol. 18, no. 14, pp. 2241‒2247, Dec. 1998.
[21] K. Nakomato, Infrared and Raman Spectra of Inorganic and Coordination Compounds, A Willey-Interscience Publication, John Wiley and Sons, 1986.
[22] A. Baykal, M. Kızılyallı, G. Gözel, and R. Kniep, “Synthesis of strontium borophosphate, SrBPO5 by solid state and hydrothermal methods and characterization,” Crys. Res. Technol., vol. 35, no. 3, pp. 247‒254, March 2000.
[23] A. Baykal, and M. Kızılyallı, “X-ray powder diffraction and IR study of NaMg(H2O)2(BP2O8)·H2O and NH4Mg(H2O)2(BP2O8)·H2O,” J. Mater. Science, vol. 35, no. 18, pp. 4621‒4626, Sep. 2000.
[1] F. D. Kurtuluş, “Synthesis and characterization of metal containing borate, phosphate and borophosphate compounds by hydrothermal and microwave methods,” PhD thesis, 2003, Balıkesir University, Turkey
[2] B. Tekin, “Syntheses and structural characterization of certain compound of metal borates, phosphates and borophosphates,” PhD thesis, 2007, Balıkesir University, Turkey.
[3] R. A. Smith, R. B. Brom, “Boron compounds, oxides, acid, borates, Kirk-Othmer Encyclopedia of Chemical Technology, Wiley, New York, 1992.
[4] R. M. Adams, “Boron, metallo-boron compounds and boranes, Wiley-Interscience, New York, 1964.
[5] A. H. Silver, J. Chem. Phys., vol. 32, pp. 959, 1960.
[6] K. Goetzman, D. Karlheinz, N. H. Dieter, G. Ralf, Patent CA, C09K015, 1996.
[7] Y. Zhang, J. K. Liang, X. L. Chen, M. He, T. Xu, J. Alloys and Comp., vol. 327, pp. 96, 2001.
[8] Y. Zhang, X. L. Chen, J. K. Liang, T. Xu, J. Alloys and Comp., vol. 333, pp. 72, 2002.
[9] J. L. C., Rowsell, N. J. Taylor, L. F. Nazar, J. Solid State Chem., vol. 174, pp. 189, 2003.
[10] H. Huppertz, S. Altmonnshofer, and G. Heymann, “High-pressure preparation, crystal structure, and properties of the new rare-earth oxoborate β-Dy2B4O9,” J. Solid State Chem., vol. 170, no. 2, pp. 320‒329, Feb. 2003.
[11] G. Güzel, “Synthesis of some type of lithium and boron rich chemical compounds and analyzed theirs structural properties by XRD,” MSc. thesis, 2006, Balıkesir University, Turkey.
[12] G. Zhang, Y. Wu, P. Fu, G. Wang, H. Liu, G. Fan, and C. Chen, “A new sodium samarium borate Na3Sm2(BO3)3,” J. Phys. Chem. Solid, vol. 63, no. 1, pp. 145‒149, Jan. 2002.
[13] S. Lemanceau, G. C. Bertrand, R. Mahiou, M. El-Ghozzi, J. C. Cousseins, P. Conflnt, and R. N. Vannier, “Synthesis and characterization of H-LnBO3orthoborates (Ln=La, Nd, Sm, and Eu),” J. Solid State Chem., vol. 148, no. 2, pp. 229‒235, Dec. 1999.
[14] S. Somunkıranoglu, “The synthesis and characterization of oxide and vanadate types of compounds containing some double metals,” MSc thesis, 2014, Balıkesir University, Turkey.
[15] Y. Shi, J. Liang, H. Zhang, J. Yang, W. Zhuang, and G. Rao, “X-Ray powder diffraction and vibrational spectra studies of rare earth borophosphates, Ln7O6(BO3)(PO4)2(Ln=La, Nd, Gd, and Dy),” J. Solid State Chem.,vol. 129, no. 1, pp. 45‒52, Feb. 1997.
[16] M. Yerli, “The synthesis and characterization of some metal containing borate, phosphate and vanadate compounds,” MSc. thesis, 2009, Balıkesir University, Turkey.
[17] S. Sarıkaya Gacanoğlu, “The solid state chemical synthesis and characterization studies of some new type double metal orthoborate compounds,” PhD thesis, 2009, Balıkesir University, Turkey.
[18] Y. Zhang, X. L. Chen, J. K. Liang, and T. Xu, “Synthesis and structural study of new rare earth sodium borates Na3Ln(BO3)2 (Ln=Y, Gd),” J. Alloys and Comp., vol. 333, no. 1‒2, pp. 72‒75, Feb. 2002.
[19] M. Taşdemir, “Some theorical applications of Rietveld analysis via GSAS computer program on powder crystal systems,” MSc. thesis, 2008, Balıkesir University, Turkey.
[20] G. Gözel, A. Baykal, M. Kızılyallı, and R. Kniep, “Optimizing the dispersion on an alumina suspension using commercial polyvalent electrolyte dispersants,” J. Europ. Ceram. Soc., vol. 18, no. 14, pp. 2241‒2247, Dec. 1998.
[21] K. Nakomato, Infrared and Raman Spectra of Inorganic and Coordination Compounds, A Willey-Interscience Publication, John Wiley and Sons, 1986.
[22] A. Baykal, M. Kızılyallı, G. Gözel, and R. Kniep, “Synthesis of strontium borophosphate, SrBPO5 by solid state and hydrothermal methods and characterization,” Crys. Res. Technol., vol. 35, no. 3, pp. 247‒254, March 2000.
[23] A. Baykal, and M. Kızılyallı, “X-ray powder diffraction and IR study of NaMg(H2O)2(BP2O8)·H2O and NH4Mg(H2O)2(BP2O8)·H2O,” J. Mater. Science, vol. 35, no. 18, pp. 4621‒4626, Sep. 2000.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:74620", author = "G. Çelik Gül and F. Kurtuluş", title = "Iron Doped Biomaterial Calcium Borate: Synthesis and Characterization", abstract = "Colemanite is the most common borate mineral, and the main source of the boron required by plants, human, and earth. Transition metals exhibit optical and physical properties such as; non-linear optical character, structural diversity, thermal stability, long cycle life and luminescent radiation. The doping of colemanite with a transition metal, bring it very interesting and attractive properties which make them applicable in industry. Iron doped calcium borate was synthesized by conventional solid state method at 1200 °C for 12 h with a systematic pathway. X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy/energy dispersive analyze (SEM/EDS) were used to characterize structural and morphological properties. Also, thermal properties were recorded by thermogravimetric-differential thermal analysis (TG/DTA).
", keywords = "Colemanite, conventional synthesis, powder x-ray diffraction, borates.", volume = "10", number = "12", pages = "1501-5", }
