Investigation of Oil inside the Wells in REY Area in Tehran Oil Refining Company in Iran

REY area has been located in Tehran Province and several archaeological ruins of this area indicate that the settlement in this area has been started since several thousand years ago. In this paper, the main investigation items consist of analysis of oil components and groundwater quality inside the wells. By finding the contents of oil in the well, it is possible to find out the pollution source by comparing the oil contents of well with other oil products that are used inside and outside of the oil farm. Investigation items consist of analysis of BTEX (Benzene, Toluene, Ethyl-benzene, Xylene), Gas chromatographic distillation characteristics, Water content, Density, Sulfur content, Lead content, Atmospheric distillation, MTBE(Methyl tertiary butyl ether). Analysis of polluting oil components showed that except MW(Monitoring Well)10 and MW 15 that oil with slightly heavy components was detected in them; with a high possibility the polluting oil is light oil.





References:
[1] Wang, Z., Fingas, M., Page, D.S., "Oil spill identification. J.
Chromatogr." 1999, A 843, 369e411.
[2] B. Mrayyan, M.N. Batikhi, "Biodegradation of total organic carbon"
(TOC in Jordanian petroleum sludge, J. Hazard. Mater. B120 ,2005, 127-
134.
[3] Zhou, E., Crawford, R., "Effects of oxygen, nitrogen, and temperature on
gasoline biodegradation in soil." 1995,Biodegradation 6, 127e140.
[4] Liebeg, E.W., Cutright, T.J., "The investigation of enhanced
bioremediation through the addition of macro and micronutrients in a
PAH contaminated soil." 1999, International Biodeterioration and
Biodegradation 44, 55e64.
[5] Ting, Y.P., Hu, H.L., Tan, H.M., "Bioremediation of petroleum
hydrocarbons in soil microcosms." 1999,Resource and Environmental
Biotechnology 2, 197e218.
[6] Vasudevan, N., Rajaram, P., Bioremediation of oil sludgecontaminated
soil. Environment International 26, 409e411.
[7] Xie, G., Barcelona, M.J., "Efficient Quantification of TPH and
Applications at Two Contaminated Sites." 2001,Ground Water
Monitoring and Remediation, 64-70.
[8] Einhorn, I.N., Sears, S.F., Hickey, J.C., Viellenave, J.H., Moore, G.S.,
"Characterization of Petroleum Contaminants in Groundwater and Soils."
In Hydrocarbon Contaminated Soils, Vol. 2, P.T. Kostecki and E.J.
Calabrese (Eds). Amherst, Massachusetts, USA, 1992, pp. 89-143.
[9] American Society for Testing and Materials, ASTM D6563 - 05e1
Standard Test Method for Benzene, Toluene, Xylene (BTX) Concentrates
Analysis by Gas Chromatography.
[10] American Society for Testing and Materials, ASTM D2887-04a Standard
Test Method for Boiling Range Distribution of Petroleum Fractions by
Gas Chromatography.
[11] American Society for Testing and Materials, ASTM D1533 - 00(2005)
Standard Test Method for Water in Insulating Liquids by Coulometric
Karl Fischer Titration.
[12] American Society for Testing and Materials, ASTM D4052- 96(2002)e1
Standard Test Method for Density and Relative Density of Liquids by
Digital Density Meter.
[13] American Society for Testing and Materials, ASTM D4294-03-Standard
Test Method for Sulfur in Petroleum and Petroleum Products by Energy-
Dispersive X-Ray Fluorescence Spectrometry .
[14] American Society for Testing and Materials, ASTM D3237-02-Standard
Test Method for Lead In Gasoline By Atomic Absorption Spectroscopy.
[15] American Society for Testing and Materials, ASTM D86-04b Standard
Test Method for Distillation of Petroleum Products at Atmospheric
Pressure.
[16] American Society for Testing and Materials, ASTM D4815- American
Society for Testing and Materials Standard, D4815-04 Standard Test
Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-
Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas
Chromatography.
[17] Cheremisinoff, P.N. "A guide to underground storage tanks,
evaluation, site assessment and remediation." 1992, Published by
Prentice- Hall Inc. Englewood Cliffs, New Jersey.
[18] Dragun, J., and Hellings, C. S., "Physicochemical and structureal
relationships of organic chemicals undergoing soil and clay catalyzed
free radical oxidation." Soil Science., 1985, 139, 100-111.