Hydrogen Gas Sensing Properties of Multiwalled Carbon Nanotubes Network Partially Coated with SnO2 Nanoparticles at Room Temperature

In the present work, hydrogen gas sensor of modest
sensitivity utilizing functionalized multiwalled carbon nanotubes
partially decorated with tin oxide nanoparticles (F-MWCNTs/SnO2)
has been fabricated. This sensing material was characterized by
scanning electron microscopy (SEM). In addition, a remarkable
finding was that the F-MWCNTs/SnO2 sensor shows good sensitivity
as compared to F-MWCNTs for low concentration (0.05-1% by
volume) of H2 gas. The fabricated sensors show complete resistance
recovery and good repeatability when exposed to H2 gas at the room
temperature conditions.





References:
[1] V.M. Aroutiounian, “Hydrogen detectors,” Int J of Alternative Energy
Ecol., vol. 23, pp 21-31, 2005.
[2] V.M Aroutiounian, “Metal oxide hydrogen, oxygen, and carbon
monoxide sensors for hydrogen setups and cells,” Int J Hydrogen
Energy, vol. 32, pp 1145-58,2007.
[3] S. Dhall, N. Jaggi and R. Nathawat, “Functionalized multiwalled carbon
nanotubes based hydrogen gas sensor,” Sens. and Actu. A, vol. 201,pp
221-227, 2013.
[4] L.D. Luca, A. Donato, S.Santangelo, G. Faggio, G. Messina, N. Donato
and G. Neri, “Hydrogen sensing characteristics of Pt/TiO2/MWCNTs
composites,” Int. J. Hydrogen Energy, vol.37, pp 1842-47, 2012.
[5] C. Wongchoosuk, A. Wisitsoraat, D. Phokharatkul, A. Tuantranont and
T. Kerdcharoen,“Multi-Walled Carbon Nanotube-Doped Tungsten
Oxide Thin Films for Hydrogen Gas Sensing,” Sensors, vol.10, pp 7705-
15, 2010.
[6] S. Trocino, A. Donato, M. Latino, N. Donato, S. G. Lenonardi and G.
Neri Pt-TiO2/MWCNTs “Hybrid composites for monitoring low
hydrogen concentrations in air,” Sensors, vol. 12, pp 12361-73, 2012.
[7] S. Dhall and N. Jaggi, “Hydrogen Sensing of NiO and
Cu2O/Multiwalled Carbon Nanotubes Nanostructures at Room
Temperature,” Sensor Lett., vol. 12, pp 1-6, 2014.
[8] A. Star, V. Joshi, S. Skarupo, D. Thomas and J.C.P. Gabriel, “Gas
Sensor Array Based on Metal-Decorated Carbon Nanotubes,” Phys.
Chem. B, vol.110, pp 21014-20, 2006.
[9] A. Kaniyoor and S. Ramaprabhu, “Hybrid carbon nanostructured
ensembles as chemiresistive hydrogen gas sensors,” Carbon, vol. 49, pp
227-236, 2011.
[10] V. V. Bolotov, V. E. Kan, P. M. Korusenko, S. N. Nesov, S. N.
Povoroznyuk, I. V. Ponomareva, V. E. Roslikov, Yu. A. Sten’kin, R. V.
Shelyagin and E. V. Knyazev, “Formation mechanisms of
nanocomposite layers based on multiwalled carbon nanotubes and nonstoichiometric
tin oxide,” Physics of the Solid State, vol. 54, pp. 166–
173, 2012.
[11] M. Yang, D. H. Kim, W. S. Kim, T. J. Kang, B. Y. Lee, S. Hong, Y. H.
Kim and S. H. Hong, “H2 sensing characteristics of SnO2 coated single
wall carbon nanotube network sensors,” Nanotechnology, vol. 21, pp
215501, 2010.