Generation of Highly Ordered Porous Antimony-Doped Tin Oxide Film by A Simple Coating Method with Colloidal Template
An ordered porous antimony-doped tin oxide (ATO) film was successfully prepared using a simple coating process with colloidal templates. The facile production was effective when a combination of 16-nm ATO (as a model of an inorganic nanoparticle) and polystyrene (PS) spheres (as a model of the template) weresimply coated to produce a composite ATO/PS film. Heat treatment was then used to remove the PS and produce the porous film. The porous film with a spherical pore shape and a highly ordered porous structure could be obtained. A potential way for the control of pore size could be also achieved by changing initial template size. The theoretical explanation and mechanism of porous formation were also added, which would be important for the scaling-up prediction and estimation.
[1] A.L. Onaogu, C.E. Okeke, "Characterization of antimony-doped tin
oxide films prepared by spray pyrolysis", Solar Energy Mater., vol. 20,pp. 26-36, 1990.
[2] T. Tsuchiya, A. Koizumi, "Preparation and electric properties of transparent electrically conductive tin antimonide (SnO2/Sb2O5) thin films by dip coating", J. Ceram. Soc. Jpn., vol. 98, pp. 1011-1016, 1990.
[3] K. Ravichandran, G.Muruganantham, B.Sakthivel, "Highly
conductingandcrystallinedoublydopedtinoxidefilmsfabricatedusing alow-costand simplified spray technique", Physica B, vol. 404, pp. 4299-4302, 2009.
[4] A.B.D. Nandiyanto, T. Ogi, F. Iskandar, K. Okuyama, "Highly ordered
porous monolayer generation by dual-speed spin-coating with colloidal
templates, Chem. Eng. J., vol. 167, pp. 409-415, 2010.
[5] K. Tsukuma, T. Akiyama, H. Imai, "Hydrolysis deposition of thin films
of antimony-doped tin oxide", J. Am. Ceram. Soc., vol. 84, pp. 869-871,
2001.
[6] V. Müller, M. Rasp, G. Stefanic, S. Günther, J. Rathousky, M.
Niederberger, D. Fattakhova-Rohlfing, "Antimony doped tin oxide
nanoparticles and their assembly in mesostructured film", Phys. Status
Solidi C, vol. 8, pp. 1759-1763, 2010.
[7] A.B.D. Nandiyanto, N. Hagura, F. Iskandar, K. Okuyama, "Design of a
highly ordered and uniform porous structure with multisized pores in film
and particle forms using a template-driven self-assembly technique",
Acta Mater., vol. 58, pp. 282-289, 2010.
[8] A.B.D. Nandiyanto, K. Okuyama, "Progress in developing spray-drying
methods for the production of controlled morphology particles: From the
nanometer to submicrometer size ranges", Adv. Powder Technol., vol. 22,
pp. 1-19, 2010.
[9] A.B.D. Nandiyanto, F. Iskandar, K. Okuyama, "Macroporous anatase
titania particle: Aerosol self-assembly fabrication with photocatalytic
performance", Chem. Eng. J., vol. 152, pp. 293-296, 2009.
[10] A.B.D. Nandiyanto, S.G. Kim, F. Iskandar, K. Okuyama, "Synthesis of
spherical mesoporous silica nanoparticles with nanometer-size
controllable pores and outer diameters", Micropor. Mesopor. Mater., vol.
120, pp. 447-453, 2009.
[11] A.B.N. Nandiyanto, M. Abdullah, F. Iskandar, K. Okuyama, "Fabrication
of ordered macroporous titania film using self-assembly an organic
template and asimple dip-coating technique, J. Nanosains
Nanoteknologi, vol. 2, pp. 56-59, 2009.
[12] F. Iskandar, A.B.D. Nandiyanto, K.M. Yun, C.J. Hogan, K. Okuyama, P.
Biswas, Enhanced photocatalytic performance of brookite TiO2
macroporous particles prepared by spray drying with colloidal
templating, Adv. Mater., vol. 19,pp. 1408-1412, 2007.
[13] A.B.D. Nandiyanto, F. Iskandar, K. Okuyama, "Nanosized polymer
particle-facilitated preparation of mesoporous silica particles using a
spray method", Chem. Lett., vol. 37, pp. 1040-1041, 2008.
[14] A.B.D. Nandiyanto, Y. Kaihatsu, F. Iskandar, K. Okuyama, "Rapid
synthesis of a BN/CNT composite particle via spray routes using
ferrocene/ethanol as a catalyst/carbon source", Mater. Lett., vol. 63, pp.
1847-1850, 2009.
[15] F. Iskandar, A.B.D. Nandiyanto, W. Widiyastuti, L.S. Young, K.
Okuyama, L. Gradon, "Production of morphology-controllable porous
hyaluronic acid particles using a spray-drying method", Acta Biomater.,
vol. 5, pp. 1027-1034, 2009.
[16] F. Iskandar, S.G. Kim, A. Bayu, D. Nandiyanto, Y. Kaihatsu, T. Ogi, K.
Okuyama, "Direct synthesis of hBN/MWCNT composite particles using
spray pyrolysis", J. Alloy. Compd., vol. 471, pp. 166-171, 2009.
[17] A.B.D. Nandiyanto, F. Iskandar, T. Ogi, K. Okuyama, "Nanometer to
Submicrometer Magnesium Fluoride Particles with Controllable
Morphology", Langmuir, vol. 26, pp. 12260-12266, 2010.
[18] A.B.D. Nandiyanto, A. Suhendi, T. Ogi, T. Iwaki, K. Okuyama,
"Synthesis of Additive-free Cationic Polystyrene Particles with
Controllable Size for Hollow Template Applications", Colloid Surf A,
submitted
[1] A.L. Onaogu, C.E. Okeke, "Characterization of antimony-doped tin
oxide films prepared by spray pyrolysis", Solar Energy Mater., vol. 20,pp. 26-36, 1990.
[2] T. Tsuchiya, A. Koizumi, "Preparation and electric properties of transparent electrically conductive tin antimonide (SnO2/Sb2O5) thin films by dip coating", J. Ceram. Soc. Jpn., vol. 98, pp. 1011-1016, 1990.
[3] K. Ravichandran, G.Muruganantham, B.Sakthivel, "Highly
conductingandcrystallinedoublydopedtinoxidefilmsfabricatedusing alow-costand simplified spray technique", Physica B, vol. 404, pp. 4299-4302, 2009.
[4] A.B.D. Nandiyanto, T. Ogi, F. Iskandar, K. Okuyama, "Highly ordered
porous monolayer generation by dual-speed spin-coating with colloidal
templates, Chem. Eng. J., vol. 167, pp. 409-415, 2010.
[5] K. Tsukuma, T. Akiyama, H. Imai, "Hydrolysis deposition of thin films
of antimony-doped tin oxide", J. Am. Ceram. Soc., vol. 84, pp. 869-871,
2001.
[6] V. Müller, M. Rasp, G. Stefanic, S. Günther, J. Rathousky, M.
Niederberger, D. Fattakhova-Rohlfing, "Antimony doped tin oxide
nanoparticles and their assembly in mesostructured film", Phys. Status
Solidi C, vol. 8, pp. 1759-1763, 2010.
[7] A.B.D. Nandiyanto, N. Hagura, F. Iskandar, K. Okuyama, "Design of a
highly ordered and uniform porous structure with multisized pores in film
and particle forms using a template-driven self-assembly technique",
Acta Mater., vol. 58, pp. 282-289, 2010.
[8] A.B.D. Nandiyanto, K. Okuyama, "Progress in developing spray-drying
methods for the production of controlled morphology particles: From the
nanometer to submicrometer size ranges", Adv. Powder Technol., vol. 22,
pp. 1-19, 2010.
[9] A.B.D. Nandiyanto, F. Iskandar, K. Okuyama, "Macroporous anatase
titania particle: Aerosol self-assembly fabrication with photocatalytic
performance", Chem. Eng. J., vol. 152, pp. 293-296, 2009.
[10] A.B.D. Nandiyanto, S.G. Kim, F. Iskandar, K. Okuyama, "Synthesis of
spherical mesoporous silica nanoparticles with nanometer-size
controllable pores and outer diameters", Micropor. Mesopor. Mater., vol.
120, pp. 447-453, 2009.
[11] A.B.N. Nandiyanto, M. Abdullah, F. Iskandar, K. Okuyama, "Fabrication
of ordered macroporous titania film using self-assembly an organic
template and asimple dip-coating technique, J. Nanosains
Nanoteknologi, vol. 2, pp. 56-59, 2009.
[12] F. Iskandar, A.B.D. Nandiyanto, K.M. Yun, C.J. Hogan, K. Okuyama, P.
Biswas, Enhanced photocatalytic performance of brookite TiO2
macroporous particles prepared by spray drying with colloidal
templating, Adv. Mater., vol. 19,pp. 1408-1412, 2007.
[13] A.B.D. Nandiyanto, F. Iskandar, K. Okuyama, "Nanosized polymer
particle-facilitated preparation of mesoporous silica particles using a
spray method", Chem. Lett., vol. 37, pp. 1040-1041, 2008.
[14] A.B.D. Nandiyanto, Y. Kaihatsu, F. Iskandar, K. Okuyama, "Rapid
synthesis of a BN/CNT composite particle via spray routes using
ferrocene/ethanol as a catalyst/carbon source", Mater. Lett., vol. 63, pp.
1847-1850, 2009.
[15] F. Iskandar, A.B.D. Nandiyanto, W. Widiyastuti, L.S. Young, K.
Okuyama, L. Gradon, "Production of morphology-controllable porous
hyaluronic acid particles using a spray-drying method", Acta Biomater.,
vol. 5, pp. 1027-1034, 2009.
[16] F. Iskandar, S.G. Kim, A. Bayu, D. Nandiyanto, Y. Kaihatsu, T. Ogi, K.
Okuyama, "Direct synthesis of hBN/MWCNT composite particles using
spray pyrolysis", J. Alloy. Compd., vol. 471, pp. 166-171, 2009.
[17] A.B.D. Nandiyanto, F. Iskandar, T. Ogi, K. Okuyama, "Nanometer to
Submicrometer Magnesium Fluoride Particles with Controllable
Morphology", Langmuir, vol. 26, pp. 12260-12266, 2010.
[18] A.B.D. Nandiyanto, A. Suhendi, T. Ogi, T. Iwaki, K. Okuyama,
"Synthesis of Additive-free Cationic Polystyrene Particles with
Controllable Size for Hollow Template Applications", Colloid Surf A,
submitted
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:61037", author = "Asep Bayu Dani Nandiyanto and Asep Suhendi and Yutaka Kisakibaru and Takashi Ogi and Kikuo Okuyama", title = "Generation of Highly Ordered Porous Antimony-Doped Tin Oxide Film by A Simple Coating Method with Colloidal Template", abstract = "An ordered porous antimony-doped tin oxide (ATO) film was successfully prepared using a simple coating process with colloidal templates. The facile production was effective when a combination of 16-nm ATO (as a model of an inorganic nanoparticle) and polystyrene (PS) spheres (as a model of the template) weresimply coated to produce a composite ATO/PS film. Heat treatment was then used to remove the PS and produce the porous film. The porous film with a spherical pore shape and a highly ordered porous structure could be obtained. A potential way for the control of pore size could be also achieved by changing initial template size. The theoretical explanation and mechanism of porous formation were also added, which would be important for the scaling-up prediction and estimation.
", keywords = "Porous structure film; ATO particle; Ultra-low refractive index; vertical drop method; Low-density material;", volume = "6", number = "1", pages = "101-4", }
