Experimental Determination of the Critical Locus of the Acetone + Chloroform Binary System
In this paper, vapour-liquid critical locus for the
binary system acetone + chloroform was determined experimentally
over the whole range of composition. The critical property
measurements were carried out using a dynamic-synthetic apparatus,
employed in the dynamic mode. The critical points are visually
determined by observing the critical opalescence and the
simultaneous disappearance and reappearance of the meniscus in the
middle of a high-pressure view cell which withstands operations up
to 673K and 20MPa. The experimental critical points measured in
this work were compared to those available in literature.
[1] W.L. Luyben, "Control of the maximum-boiling acetone/chloroform
azeotropic distillation System", Ind. Eng. Chem. Res, vol. 47, pp. 6140-
6149, 2008.
[2] R. Gupta, A. Chandra, "Structural, single-particle and pair dynamical
properties of acetone-chloroform mixtures with dissolved solutes",
Chemical Physics, vol. 383, pp.41-49, 2011.
[3] T.S. Perova, D.H. Christensen, O. Faurskov Nielsen, "Low-frequency
Raman and far-infrared spectra of acetone/chloroform mixtures",
Vibrational Spectroscopy, vol. 15, pp.61-67, 1997.
[4] M.R. Jalilian, L. Alibabaei, "Spectra and structure of binary azeotropes,
I. Acetone-chloroform", Spectrochimica Acta, vol. 62, pp.322-325,
2005.
[5] B.H. Carroll, J.H. Mathews, "A calorimeter for heats of mixing at
elevated temperatures", J. Am. Chem. Soc, vol. 46, pp. 30-36, 1924.
[6] A.E. Karr, W.M. Bowest, E.G. Scheibel, "Analysis of binary and ternary
mixtures system acetone-chloroform-methyl isobutyl ketone", Analytical
Chemistry, vol. 23, pp. 459-463, 1951.
[7] A.N. Campbell, E.M. Kartzmark, "The energy of hydrogen bonding in
the system acetone - chloroform", Can. J. Chem., vol. 38, pp. 652-655,
1960.
[8] A.N. Campbell, E.M. Kartzmark, H. Friesen, "The equilibrium diagrams,
heats of mixing, dipoles moments, densities and boiling points of the
system acetone + chloroform + benzene", Can. J. Chem., vol. 39, pp.
735-744, 1961.
[9] Edward R. Kearns, "Thermodynamic studies of the system acetonrchloroform,
II. The relation of excess mixing functions to association
complexes", J of Phys. Chem., vol. 65, pp. 314-316, 1961.
[10] K.W. Morcom, D.N. Travers, "Heat of mixing of the system acetonechloroform;
temperature dependence and deuterium isotope effect",
Tran. Faraday Soc., vol. 61, pp. 230-234, 1965.
[11] J.W. Morris, P.J. Mulvey, M.M. Abbott, H.C. Van Ness, "Excess
thermodynamic functions for ternary systems, 1. Acetone-chloroformmethanol
at 50┬░C", J. of Chem. & Eng. Data, vol. 20, pp. 403-405, 1975.
[12] A. Apelblat, A. Tamir, M. Wagner, "Thermodynamics of acetone +
chloroform mixtures", Fluid Phase Equilibria. vol. 4, pp. 229-255, 1980.
[13] G. Savaro─ƒlu, E. Aral, "Ultrasonic velocity and isentropic
compressibilities of the ternary mixture benzene + acetone + chloroform
and their corresponding binary mixture at 298.15K", J. of mole. Liq.,
vol. 105/1, pp. 79-92, 2003.
[14] M.A. Rosanoff, C.W. Bacon, A ND J. F. W. Schulze, "A method of
finding the partial from the total vapour pressures of binary mixtures and
a theory of fractional distillation", J. Am. Chem. Soc, vol. 36, pp. 1993-
2004, 1914.
[15] F.J. Soday, G.W. Bennett, "Laboratory experiments on the boiling-point
curves of binary mixtures", J. Chem. Educ., vol. 7, pp. 1336-1340, 1930.
[16] C.R. Fordyce, D.R. Simonsen, "Cellulose ester solutions: Evaporation in
binary solvent mixtures", Ind. Eng. Chem., vol. 41, pp. 104-111, 1949.
[17] A. Rose, E.T. Williams, W.W. Sanders, R.L Heiny J.F.Ryan, "Binary
vapor-liquid equilibria trail and error prediction and correlation", Ind.
Eng. Chem., vol. 45, pp. 1568-1572, 1953.
[18] J.A. Tallmadge, L.N. Canjar, "Simultaneous measurement of phase
equilibria and integral isobaric - heats of vaporization; systems acetonechloroform
and benzene-acetone", Ind. Eng. Chem., vol. 46, pp. 1279-
1281, 1954.
[19] H. Röck, W Schröder, "Dampf-Fl├╝ssigkeits-Gleichgewichtsmessungen
im system azeton -chloroform", Zeitschrift f├╝r Physikalische Chemie,
vol. 11, pp. 41-55, 1957.
[20] C.R. Mueller, E. Kearn, "Thermodynamic studies of the system acetone
and chloroform", J. Phys. Chem., vol. 62, pp. 1441-1445, 1958.
[21] A.N. Campbell, E.M. Kartzmark, R.M. Chatterjee, "Excess volumes,
vapor pressure and related thermodynamic properties of the system
acetone-chloroform-benzene and its component binary systems", Can. J.
Chem., vol. 44, pp. 1183-1189, 1966.
[22] M.M. Abbott, H.C. Van Ness, "Vapor-liquid equilibrium: Part III. Data
reduction with precise expressions for GE", J. AIChE., vol. 21, pp. 62-76,
1975.
[23] M. G├│ral, G. Kolasińska, P. Oracz, S. Warycha, "Vapour-liquid
equilibria. II. The ternary system methanol-chloroform-acetone at 313.15
and 323.15 K", Fluid Phase Equilibria, vol. 23, pp. 89-116, 1985.
[24] K. Kojlma, K. Tochigl, K. Kurihara, M. Nakamichi, "Isobaric vaporviquid
equilibria for acetone + chloroform + benzene and the three
constituent binary systems", J. Chem. Eng. Data, vol. 34, pp. 343-345,
1991.
[25] J.A. Hopkins, V.R. Bhethanabotla, S.W. Campbell, "Total pressure
measurements for chloroform + acetone + toluene at 303.15 K", J.
Chem. Eng. Data, vol. 39, pp. 488-492, 1994.
[26] P. Oracz, S. Warycha, "Vapour-liquid equilibria. XII. The ternary system
methanol-chloroform-acetone at 303.15 K", Fluid Phase Equilibria, vol.
137, pp. 149-162, 1997.
[27] A.N. Campbell, G. M. Musbally, "Vapor pressures and vapor liquid
equilibria in the systems: (1) acetone - chloroform, (2) acetone - carbon
tetrachloride, (3) benzene - carbon tetrachloride", Can. J. Chem., vol. 48,
pp. 3173-3184, 1970.
[28] G. Kamath, G. Georgiev, J.J. Potoff, "Molecular modeling of phase
behavior and microstructure of acetone-chloroform-methanol binary
mixtures", J. Phys. Chem., vol. 109, pp. 19463-19473, 2005.
[29] J.P. Kuenen, W.G. Robson, "Observations on mixtures with maximum
or minimum vapour-pressure", Philosophical Magazine Series 6, vol. 4,
pp. 116-132, 1902.
[30] A.S. Teja, J. Mendez-Santiago, in: R.D. Weir, Th.W. de Loos (Eds.),
"Measurement of the thermodynamic properties of multiple phases",
Elsevier, Amsterdam, pp. 409-425, 2005.
[31] N. Juntarachat, P.D. Beltran Moreno, S. Bello, R. Privat, J.-N. Jaubert,
"Validation of a new apparatus using the dynamic and static methods for
determining the critical properties of pure components and mixtures", J.
of Supercritical Fluids, vol. 68, pp. 25- 30, 2012.
[32] N. Juntarachat, S. Bello, R. Privat, J.-N. Jaubert, "Validation of a new
apparatus using the dynamic method for determining the critical
properties of binary mixtures containing CO2 and a n-alkane", Fluid
Phase Equilibria, vol. 325, pp. 66-70, 2012.
[33] P.H. van Konynenburg, R.L. Scott, "Critical lines and phase
equilibriums in binary Van der Waals mixtures", Philos. Trans. R. Soc.
London Ser. A, vol. 298, pp. 495-540, 1980.
[1] W.L. Luyben, "Control of the maximum-boiling acetone/chloroform
azeotropic distillation System", Ind. Eng. Chem. Res, vol. 47, pp. 6140-
6149, 2008.
[2] R. Gupta, A. Chandra, "Structural, single-particle and pair dynamical
properties of acetone-chloroform mixtures with dissolved solutes",
Chemical Physics, vol. 383, pp.41-49, 2011.
[3] T.S. Perova, D.H. Christensen, O. Faurskov Nielsen, "Low-frequency
Raman and far-infrared spectra of acetone/chloroform mixtures",
Vibrational Spectroscopy, vol. 15, pp.61-67, 1997.
[4] M.R. Jalilian, L. Alibabaei, "Spectra and structure of binary azeotropes,
I. Acetone-chloroform", Spectrochimica Acta, vol. 62, pp.322-325,
2005.
[5] B.H. Carroll, J.H. Mathews, "A calorimeter for heats of mixing at
elevated temperatures", J. Am. Chem. Soc, vol. 46, pp. 30-36, 1924.
[6] A.E. Karr, W.M. Bowest, E.G. Scheibel, "Analysis of binary and ternary
mixtures system acetone-chloroform-methyl isobutyl ketone", Analytical
Chemistry, vol. 23, pp. 459-463, 1951.
[7] A.N. Campbell, E.M. Kartzmark, "The energy of hydrogen bonding in
the system acetone - chloroform", Can. J. Chem., vol. 38, pp. 652-655,
1960.
[8] A.N. Campbell, E.M. Kartzmark, H. Friesen, "The equilibrium diagrams,
heats of mixing, dipoles moments, densities and boiling points of the
system acetone + chloroform + benzene", Can. J. Chem., vol. 39, pp.
735-744, 1961.
[9] Edward R. Kearns, "Thermodynamic studies of the system acetonrchloroform,
II. The relation of excess mixing functions to association
complexes", J of Phys. Chem., vol. 65, pp. 314-316, 1961.
[10] K.W. Morcom, D.N. Travers, "Heat of mixing of the system acetonechloroform;
temperature dependence and deuterium isotope effect",
Tran. Faraday Soc., vol. 61, pp. 230-234, 1965.
[11] J.W. Morris, P.J. Mulvey, M.M. Abbott, H.C. Van Ness, "Excess
thermodynamic functions for ternary systems, 1. Acetone-chloroformmethanol
at 50┬░C", J. of Chem. & Eng. Data, vol. 20, pp. 403-405, 1975.
[12] A. Apelblat, A. Tamir, M. Wagner, "Thermodynamics of acetone +
chloroform mixtures", Fluid Phase Equilibria. vol. 4, pp. 229-255, 1980.
[13] G. Savaro─ƒlu, E. Aral, "Ultrasonic velocity and isentropic
compressibilities of the ternary mixture benzene + acetone + chloroform
and their corresponding binary mixture at 298.15K", J. of mole. Liq.,
vol. 105/1, pp. 79-92, 2003.
[14] M.A. Rosanoff, C.W. Bacon, A ND J. F. W. Schulze, "A method of
finding the partial from the total vapour pressures of binary mixtures and
a theory of fractional distillation", J. Am. Chem. Soc, vol. 36, pp. 1993-
2004, 1914.
[15] F.J. Soday, G.W. Bennett, "Laboratory experiments on the boiling-point
curves of binary mixtures", J. Chem. Educ., vol. 7, pp. 1336-1340, 1930.
[16] C.R. Fordyce, D.R. Simonsen, "Cellulose ester solutions: Evaporation in
binary solvent mixtures", Ind. Eng. Chem., vol. 41, pp. 104-111, 1949.
[17] A. Rose, E.T. Williams, W.W. Sanders, R.L Heiny J.F.Ryan, "Binary
vapor-liquid equilibria trail and error prediction and correlation", Ind.
Eng. Chem., vol. 45, pp. 1568-1572, 1953.
[18] J.A. Tallmadge, L.N. Canjar, "Simultaneous measurement of phase
equilibria and integral isobaric - heats of vaporization; systems acetonechloroform
and benzene-acetone", Ind. Eng. Chem., vol. 46, pp. 1279-
1281, 1954.
[19] H. Röck, W Schröder, "Dampf-Fl├╝ssigkeits-Gleichgewichtsmessungen
im system azeton -chloroform", Zeitschrift f├╝r Physikalische Chemie,
vol. 11, pp. 41-55, 1957.
[20] C.R. Mueller, E. Kearn, "Thermodynamic studies of the system acetone
and chloroform", J. Phys. Chem., vol. 62, pp. 1441-1445, 1958.
[21] A.N. Campbell, E.M. Kartzmark, R.M. Chatterjee, "Excess volumes,
vapor pressure and related thermodynamic properties of the system
acetone-chloroform-benzene and its component binary systems", Can. J.
Chem., vol. 44, pp. 1183-1189, 1966.
[22] M.M. Abbott, H.C. Van Ness, "Vapor-liquid equilibrium: Part III. Data
reduction with precise expressions for GE", J. AIChE., vol. 21, pp. 62-76,
1975.
[23] M. G├│ral, G. Kolasińska, P. Oracz, S. Warycha, "Vapour-liquid
equilibria. II. The ternary system methanol-chloroform-acetone at 313.15
and 323.15 K", Fluid Phase Equilibria, vol. 23, pp. 89-116, 1985.
[24] K. Kojlma, K. Tochigl, K. Kurihara, M. Nakamichi, "Isobaric vaporviquid
equilibria for acetone + chloroform + benzene and the three
constituent binary systems", J. Chem. Eng. Data, vol. 34, pp. 343-345,
1991.
[25] J.A. Hopkins, V.R. Bhethanabotla, S.W. Campbell, "Total pressure
measurements for chloroform + acetone + toluene at 303.15 K", J.
Chem. Eng. Data, vol. 39, pp. 488-492, 1994.
[26] P. Oracz, S. Warycha, "Vapour-liquid equilibria. XII. The ternary system
methanol-chloroform-acetone at 303.15 K", Fluid Phase Equilibria, vol.
137, pp. 149-162, 1997.
[27] A.N. Campbell, G. M. Musbally, "Vapor pressures and vapor liquid
equilibria in the systems: (1) acetone - chloroform, (2) acetone - carbon
tetrachloride, (3) benzene - carbon tetrachloride", Can. J. Chem., vol. 48,
pp. 3173-3184, 1970.
[28] G. Kamath, G. Georgiev, J.J. Potoff, "Molecular modeling of phase
behavior and microstructure of acetone-chloroform-methanol binary
mixtures", J. Phys. Chem., vol. 109, pp. 19463-19473, 2005.
[29] J.P. Kuenen, W.G. Robson, "Observations on mixtures with maximum
or minimum vapour-pressure", Philosophical Magazine Series 6, vol. 4,
pp. 116-132, 1902.
[30] A.S. Teja, J. Mendez-Santiago, in: R.D. Weir, Th.W. de Loos (Eds.),
"Measurement of the thermodynamic properties of multiple phases",
Elsevier, Amsterdam, pp. 409-425, 2005.
[31] N. Juntarachat, P.D. Beltran Moreno, S. Bello, R. Privat, J.-N. Jaubert,
"Validation of a new apparatus using the dynamic and static methods for
determining the critical properties of pure components and mixtures", J.
of Supercritical Fluids, vol. 68, pp. 25- 30, 2012.
[32] N. Juntarachat, S. Bello, R. Privat, J.-N. Jaubert, "Validation of a new
apparatus using the dynamic method for determining the critical
properties of binary mixtures containing CO2 and a n-alkane", Fluid
Phase Equilibria, vol. 325, pp. 66-70, 2012.
[33] P.H. van Konynenburg, R.L. Scott, "Critical lines and phase
equilibriums in binary Van der Waals mixtures", Philos. Trans. R. Soc.
London Ser. A, vol. 298, pp. 495-540, 1980.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56947", author = "Niramol Juntarachat and Romain Privat and Jean-Noël Jaubert", title = "Experimental Determination of the Critical Locus of the Acetone + Chloroform Binary System", abstract = "In this paper, vapour-liquid critical locus for the
binary system acetone + chloroform was determined experimentally
over the whole range of composition. The critical property
measurements were carried out using a dynamic-synthetic apparatus,
employed in the dynamic mode. The critical points are visually
determined by observing the critical opalescence and the
simultaneous disappearance and reappearance of the meniscus in the
middle of a high-pressure view cell which withstands operations up
to 673K and 20MPa. The experimental critical points measured in
this work were compared to those available in literature.", keywords = "Experimental measurement, critical point, critical
locus, negative azeotrope.", volume = "6", number = "12", pages = "1145-4", }
