Contaminated Soil Remediation with Hydrogen Peroxide Oxidation
The hydrogen peroxide treatment was able to
remediate chlorophenols, polycyclic aromatic hydrocarbons, diesel
and transformer oil contaminated soil. Chemical treatment of
contaminants adsorbed in peat resulted in lower contaminants-
removal and required higher addition of chemicals than the treatment
of contaminants in sand. The hydrogen peroxide treatment was found
to be feasible for soil remediation at natural soil pH. Contaminants in
soil could degrade with the addition of hydrogen peroxide only
indicating the ability of transition metals ions and minerals of these
metals presented in soil to catalyse the reaction of hydrogen peroxide
decomposition.
[1] European Commission - Environment - Policies - Soil - A Strategy to
Keep Europe-s Soils Robust and Healthy. Available:
[http://ec.europa.eu/environment/soil/index_en.htm]
[2] R.J. Watts, P.C. Stanton, J. Howsawkeng, and A.L. Teel,
"Mineralization of a sorbed polycyclic aromatic hydrocarbon in two
soils using catalyzed hydrogen peroxide", Water Res., vol. 36, pp. 4283-
4292, 2002.
[3] "Technical and Regulatory Guidance for In Situ Chemical Oxidation of
Contaminated Soil and Groundwater", Technical/Regulatory Guidelines,
prepared by Interstate Technology and Regulatory Cooperation Work
Group, In Situ Chemical Oxidation Work Team, 2001, 25 p.
[4] R.J. Watts, M.D. Udell, S.W. Leung, "Treatment of contaminated soils
using catalysed hydrogen peroxide", Chemical Oxidation Technologies
for the Nineties, W.W. Eckenfeld, A.R. Bowers, J.A. Roth (eds.),
Lancaster, USA: A Technomic Publishing Company, INC, 1992, pp. 37-
50.
[5] R.J. Watts, B.C. Bottenberg, T.F. Hess, M.D. Jensen, and A.L. Teel,
"Role of reductants in the enhanced desorption and transformation of
chloraliphatic compounds by modified Fenton-s reactions", Environ. Sci.
Technol., vol. 33, pp. 3432-3437, 1999.
[6] S.-H. Kong, R.J. Watts, and J.-H. Choi, "Treatment of petroleumcontaminated
soils using iron mineral catalyzed hydrogen peroxide",
Chemosphere, vol. 37, no. 8, pp. 1473-1482, 1998.
[7] "In Situ Oxidation", Technology Status Review, performed by
ThermoRetec Consulting Corporation with assistance from
HydroGeoLogic, Inc. and Coleman Research Corporation - Energy &
Environmental Group, Environmental Security Certification Program,
USA, November 1999, 42 p.
[8] A.L. Teel, C.R. Warberg, D.A. Atkinson, and R.J. Watts, "Comparison
of mineral and soluble iron Fenton-s catalysts for the treatment of
trichloroethylene", Water Res., vol. 35, pp. 977-984, 2001.
[9] C. Walling, "Fenton-s reagent revisited", Acc. Chem. Res., vol. 8, p.
125, 1975.
[10] B.R. Petigara, N.V. Blough, and A.C. Mignerey, "Mechanisms of
hydrogen peroxide decomposition in soils", Environ. Sci. Technol., vol.
36, pp. 639-645, 2002.
[11] C.P. Huang, C. Dong, and Z. Tang, "Advanced chemical oxidation: its
present role and potential future in hazardous waste treatment", Waste
Manage., vol. 13, pp. 361-377, 1993.
[1] European Commission - Environment - Policies - Soil - A Strategy to
Keep Europe-s Soils Robust and Healthy. Available:
[http://ec.europa.eu/environment/soil/index_en.htm]
[2] R.J. Watts, P.C. Stanton, J. Howsawkeng, and A.L. Teel,
"Mineralization of a sorbed polycyclic aromatic hydrocarbon in two
soils using catalyzed hydrogen peroxide", Water Res., vol. 36, pp. 4283-
4292, 2002.
[3] "Technical and Regulatory Guidance for In Situ Chemical Oxidation of
Contaminated Soil and Groundwater", Technical/Regulatory Guidelines,
prepared by Interstate Technology and Regulatory Cooperation Work
Group, In Situ Chemical Oxidation Work Team, 2001, 25 p.
[4] R.J. Watts, M.D. Udell, S.W. Leung, "Treatment of contaminated soils
using catalysed hydrogen peroxide", Chemical Oxidation Technologies
for the Nineties, W.W. Eckenfeld, A.R. Bowers, J.A. Roth (eds.),
Lancaster, USA: A Technomic Publishing Company, INC, 1992, pp. 37-
50.
[5] R.J. Watts, B.C. Bottenberg, T.F. Hess, M.D. Jensen, and A.L. Teel,
"Role of reductants in the enhanced desorption and transformation of
chloraliphatic compounds by modified Fenton-s reactions", Environ. Sci.
Technol., vol. 33, pp. 3432-3437, 1999.
[6] S.-H. Kong, R.J. Watts, and J.-H. Choi, "Treatment of petroleumcontaminated
soils using iron mineral catalyzed hydrogen peroxide",
Chemosphere, vol. 37, no. 8, pp. 1473-1482, 1998.
[7] "In Situ Oxidation", Technology Status Review, performed by
ThermoRetec Consulting Corporation with assistance from
HydroGeoLogic, Inc. and Coleman Research Corporation - Energy &
Environmental Group, Environmental Security Certification Program,
USA, November 1999, 42 p.
[8] A.L. Teel, C.R. Warberg, D.A. Atkinson, and R.J. Watts, "Comparison
of mineral and soluble iron Fenton-s catalysts for the treatment of
trichloroethylene", Water Res., vol. 35, pp. 977-984, 2001.
[9] C. Walling, "Fenton-s reagent revisited", Acc. Chem. Res., vol. 8, p.
125, 1975.
[10] B.R. Petigara, N.V. Blough, and A.C. Mignerey, "Mechanisms of
hydrogen peroxide decomposition in soils", Environ. Sci. Technol., vol.
36, pp. 639-645, 2002.
[11] C.P. Huang, C. Dong, and Z. Tang, "Advanced chemical oxidation: its
present role and potential future in hazardous waste treatment", Waste
Manage., vol. 13, pp. 361-377, 1993.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56065", author = "A. Goi and M. Trapido and N. Kulik", title = "Contaminated Soil Remediation with Hydrogen Peroxide Oxidation", abstract = "The hydrogen peroxide treatment was able to
remediate chlorophenols, polycyclic aromatic hydrocarbons, diesel
and transformer oil contaminated soil. Chemical treatment of
contaminants adsorbed in peat resulted in lower contaminants-
removal and required higher addition of chemicals than the treatment
of contaminants in sand. The hydrogen peroxide treatment was found
to be feasible for soil remediation at natural soil pH. Contaminants in
soil could degrade with the addition of hydrogen peroxide only
indicating the ability of transition metals ions and minerals of these
metals presented in soil to catalyse the reaction of hydrogen peroxide
decomposition.", keywords = "Hydrogen peroxide, oxidation, soil treatment,decontamination.", volume = "3", number = "4", pages = "209-5", }