Adsorption Capacity of Chitosan Beads in Toxic Solutions
The efficiency of chitosan beads processed from 4
marine animal shells; white leg shrimp (Litopenaeus vannamei), mud
crab (Scylla sp.), horseshoe crab (Carcinoscorpius rotundicauda),
and cuttlefish bone (Sepia sp.), for the adsorption experiments of
ammonia and formaldehyde were investigated. The porosities of
chitosan from the shells looked like beads were distinctly examined
under SEM. The original pores of those shells on the surface areas
compose of evenly fine pores. The shell beads of cuttlefish bone and
horseshoe crab show the larger probably even porosity, while on
those white leg shrimp and mud crab contain various large and fine
pores. The best adsorption at pH 9 in 18 mg/l ammonia at 2 hours
yield on cuttlefish bone, horseshoe crab, mud crab and white leg
shrimp with the average percent of 59.12, 51.45, 45.66 and 43.52,
respectively. Within 30 minutes the formaldehyde absorbers (at pH 5
in 8 μg/ml) revealed 46.27, 26.56, and 18.04 percent capacities in
cuttlefish bone, mud crab and white leg shrimp beads; while 22.44
percent in the horseshoe crab at pH 7. The adsorption capacities and
the amounts of beads showed a positive correlation. The adsorption
capacity relationship between pH and the gas concentrations were
affected by these qualities of chitosan beads.
[1] H. Minamisawa, H. Iwanami, N. Arai, and T. Okutani, "Adsorption
behavior of cobalt (II) on chitosan and its determination by tungsten
metal furnace atomic adsorption spectrometry," Anal. Chim. Acta., vol.
378, pp. 279-285, Jan. 1999.
[2] H. Li, Y. Du, X. Wu, and H. Zhan, "Effect of molecular weight and
degree of substitution of quaternary chitosan on its adsorption and
flocculation properties for potential retention-aids in alkaline
papermaking," Colloids and Surfaces A: Physicochemical and
Engineering Aspects, vol. 242, pp. 1-8, Aug. 2004.
[3] C. Jeon, and K. H. Park, "Adsorption and desorption characteristics of
mercury (II) ions using aminated chitosan bead," Water Research, vol.
39, pp. 3938-3944, Oct. 2005.
[4] Metallurgy and Materials Science Research Institute, Application of
chitin-chitosan. MMRI Chulalongkorn University, Bangkok, 2005, pp.
17-25.
[5] F. Li, W.G. Liu, and K.D. Yao, "Preparation of oxidized glucosecrosslinked
N-alkylated chitosan membrane and in vitro studies of pHsensitive
drug delivery," Biomaterials, vol. 23, pp. 343-347, Jan. 2002.
[6] E. Selmer-Olsen, H.C. Ratnaweera, and R. Pehrson, "A novel treatment
process for dairy wastewater with chitosan produced from shrimp-shell
waste," Water Science and Technology, vol. 34, pp. 33-40, Feb. 1996.
[7] M.S. Chiou, and H.Y. Li, "Adsorption behavior of reactive dye in
aqueous solution on chemical cross-linked chitosan beads,"
Chemosphere, vol. 50, pp. 1095-1105, Mar. 2003.
[8] N.V. Majeti, and R. Kumar, "A review of chitin and chitosan
applications," Reactive & Functional Polymers, vol. 46, pp. 1-27, Jun.
2000.
[9] S. Budavari, M.J. O'Neil, A. Smith, P.E. Heekelman, and J.F. Kinneary,
Merck Index. N.J., U.S.A., 1996.
[10] K. Toei, and T. Kohara, "A conductometric method for colloid
titrations," Analytica Chimica Acta, vol. 83, pp. 59-65, Jan. 2002.
[11] P. Pradyot, Handbook of environmental analysis: chemical pollutants in
air, water, soil wastes. 2nd ed. CRC, Boca Raton, 2010.
[12] British Pharmacopocia, Formaldehyde Solution Volume I. Her
Majesty-s Stationary Office, London, 1988.
[13] S.L.Y. Ling, C.Y.Yee, and H.S. Eng, "Removal of A Cationic Dye
using Deacetylated Chitin Chitosan," Applied Sciences, vol. 8, pp.
1445-1448, Mar. 2011.
[14] J. LI, Z. LI, B. LIU, Q. XIA, and H. XI, "Effect of Relative Humidity on
Adsorption of Formaldehyde on Modified Activated Carbons,"
Chinese Journal of Chemical Engineering, vol. 16, pp. 871-875, Aug.
2008.
[15] Z. Bekci, C. Ozveri, Y.Seki, and K.Yurdakoc, "Sorption of malachite
green on chitosan bead," Journal of Hazardous Materials, vol. 154, pp.
254-261,Jan. 2008.
[16] P. M. Claesson, and B. W. Ninham, "pH-Dependent Interaction between
Adsorbed Chitosan Layers," Langmuir, vol. 8, pp. 1406-1412, Feb.
1992.
[17] C. Xin, L. Wenjun, Z. Wei, L. Yuhua, and Y. Tongyin, "pH Sensitivity
and Ion Sensitivity of Hydrogels Based on Complex-Forming
Chitosan/Silk Fibroin Interpenetrating Polymer Network." Applied
Polymer Science, vol. 65, pp. 2257-2262, Mar. 1997.
[18] J. Choong and H. P. Kwang, "Adsorption and desorption characteristics
of mercury(II) ions using aminated chitosan bead," Water Research, vol.
39, pp. 3938-3944, Oct. 2005.
[19] V. Boonamnuayvitaya, S. Sae-ung, and W. Tanthapanichakoon,
"Preparation of activated carbons from coffee residue for the adsorption
of formaldehyde," Separation and Purification Technology, vol. 42, pp.
159-168, Jul. 2005.
[20] C. Ausa, S. Narongsak, F. Damrongsak, and S. Prasart, "Preparation
and physico-chemical characterization of chitin and chitosan from the
pens of the squid species Loligo lessoniana and Loligo formosana,"
Carbohydrate Polymers, vol. 58, pp. 467-474, Aug. 2004.
[1] H. Minamisawa, H. Iwanami, N. Arai, and T. Okutani, "Adsorption
behavior of cobalt (II) on chitosan and its determination by tungsten
metal furnace atomic adsorption spectrometry," Anal. Chim. Acta., vol.
378, pp. 279-285, Jan. 1999.
[2] H. Li, Y. Du, X. Wu, and H. Zhan, "Effect of molecular weight and
degree of substitution of quaternary chitosan on its adsorption and
flocculation properties for potential retention-aids in alkaline
papermaking," Colloids and Surfaces A: Physicochemical and
Engineering Aspects, vol. 242, pp. 1-8, Aug. 2004.
[3] C. Jeon, and K. H. Park, "Adsorption and desorption characteristics of
mercury (II) ions using aminated chitosan bead," Water Research, vol.
39, pp. 3938-3944, Oct. 2005.
[4] Metallurgy and Materials Science Research Institute, Application of
chitin-chitosan. MMRI Chulalongkorn University, Bangkok, 2005, pp.
17-25.
[5] F. Li, W.G. Liu, and K.D. Yao, "Preparation of oxidized glucosecrosslinked
N-alkylated chitosan membrane and in vitro studies of pHsensitive
drug delivery," Biomaterials, vol. 23, pp. 343-347, Jan. 2002.
[6] E. Selmer-Olsen, H.C. Ratnaweera, and R. Pehrson, "A novel treatment
process for dairy wastewater with chitosan produced from shrimp-shell
waste," Water Science and Technology, vol. 34, pp. 33-40, Feb. 1996.
[7] M.S. Chiou, and H.Y. Li, "Adsorption behavior of reactive dye in
aqueous solution on chemical cross-linked chitosan beads,"
Chemosphere, vol. 50, pp. 1095-1105, Mar. 2003.
[8] N.V. Majeti, and R. Kumar, "A review of chitin and chitosan
applications," Reactive & Functional Polymers, vol. 46, pp. 1-27, Jun.
2000.
[9] S. Budavari, M.J. O'Neil, A. Smith, P.E. Heekelman, and J.F. Kinneary,
Merck Index. N.J., U.S.A., 1996.
[10] K. Toei, and T. Kohara, "A conductometric method for colloid
titrations," Analytica Chimica Acta, vol. 83, pp. 59-65, Jan. 2002.
[11] P. Pradyot, Handbook of environmental analysis: chemical pollutants in
air, water, soil wastes. 2nd ed. CRC, Boca Raton, 2010.
[12] British Pharmacopocia, Formaldehyde Solution Volume I. Her
Majesty-s Stationary Office, London, 1988.
[13] S.L.Y. Ling, C.Y.Yee, and H.S. Eng, "Removal of A Cationic Dye
using Deacetylated Chitin Chitosan," Applied Sciences, vol. 8, pp.
1445-1448, Mar. 2011.
[14] J. LI, Z. LI, B. LIU, Q. XIA, and H. XI, "Effect of Relative Humidity on
Adsorption of Formaldehyde on Modified Activated Carbons,"
Chinese Journal of Chemical Engineering, vol. 16, pp. 871-875, Aug.
2008.
[15] Z. Bekci, C. Ozveri, Y.Seki, and K.Yurdakoc, "Sorption of malachite
green on chitosan bead," Journal of Hazardous Materials, vol. 154, pp.
254-261,Jan. 2008.
[16] P. M. Claesson, and B. W. Ninham, "pH-Dependent Interaction between
Adsorbed Chitosan Layers," Langmuir, vol. 8, pp. 1406-1412, Feb.
1992.
[17] C. Xin, L. Wenjun, Z. Wei, L. Yuhua, and Y. Tongyin, "pH Sensitivity
and Ion Sensitivity of Hydrogels Based on Complex-Forming
Chitosan/Silk Fibroin Interpenetrating Polymer Network." Applied
Polymer Science, vol. 65, pp. 2257-2262, Mar. 1997.
[18] J. Choong and H. P. Kwang, "Adsorption and desorption characteristics
of mercury(II) ions using aminated chitosan bead," Water Research, vol.
39, pp. 3938-3944, Oct. 2005.
[19] V. Boonamnuayvitaya, S. Sae-ung, and W. Tanthapanichakoon,
"Preparation of activated carbons from coffee residue for the adsorption
of formaldehyde," Separation and Purification Technology, vol. 42, pp.
159-168, Jul. 2005.
[20] C. Ausa, S. Narongsak, F. Damrongsak, and S. Prasart, "Preparation
and physico-chemical characterization of chitin and chitosan from the
pens of the squid species Loligo lessoniana and Loligo formosana,"
Carbohydrate Polymers, vol. 58, pp. 467-474, Aug. 2004.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:53754", author = "P. Setthamongkol and J. Salaenoi", title = "Adsorption Capacity of Chitosan Beads in Toxic Solutions", abstract = "The efficiency of chitosan beads processed from 4
marine animal shells; white leg shrimp (Litopenaeus vannamei), mud
crab (Scylla sp.), horseshoe crab (Carcinoscorpius rotundicauda),
and cuttlefish bone (Sepia sp.), for the adsorption experiments of
ammonia and formaldehyde were investigated. The porosities of
chitosan from the shells looked like beads were distinctly examined
under SEM. The original pores of those shells on the surface areas
compose of evenly fine pores. The shell beads of cuttlefish bone and
horseshoe crab show the larger probably even porosity, while on
those white leg shrimp and mud crab contain various large and fine
pores. The best adsorption at pH 9 in 18 mg/l ammonia at 2 hours
yield on cuttlefish bone, horseshoe crab, mud crab and white leg
shrimp with the average percent of 59.12, 51.45, 45.66 and 43.52,
respectively. Within 30 minutes the formaldehyde absorbers (at pH 5
in 8 μg/ml) revealed 46.27, 26.56, and 18.04 percent capacities in
cuttlefish bone, mud crab and white leg shrimp beads; while 22.44
percent in the horseshoe crab at pH 7. The adsorption capacities and
the amounts of beads showed a positive correlation. The adsorption
capacity relationship between pH and the gas concentrations were
affected by these qualities of chitosan beads.", keywords = "chitosan, adsorption, ammonia, formaldehyde", volume = "6", number = "9", pages = "870-6", }
