Abstract: In the present work, Electrochemical Impedance
Spectrocopy (EIS) is applied to study the transport of different metal
cations through a cation-exchange membrane. This technique enables
the identification of the ionic-transport characteristics and to
distinguish between different transport mechanisms occurring at
different current density ranges. The impedance spectra are
dependent on the applied dc current density, on the type of cation and
on the concentration.
When the applied dc current density increases, the diameter of the
impedance spectra loops increases because all the components of
membrane system resistance increase. The diameter of the impedance
plots decreases in the order of Na(I), Ni(II) and Cr(III) due to the
increased interactions between the negatively charged sulfonic
groups of the membrane and the cations with greater charge. Nyquist
plots are shifted towards lower values of the real impedance, and its
diameter decreases with the increase of concentration due to the
decrease of the solution resistance.
Abstract: The objective of this work is to study the effect of two
key factors - external magnetic field and applied current density
during template-based electrodeposition of nickel nanowires using an
electrode distance of 20 mm. Morphology, length, crystallite size and
crystallographic characterization of the grown nickel nanowires at an
electrode distance of 20mm are presented. For this electrode distance
of 20 mm, these two key electrodeposition factors when coupled was
found to reduce crystallite size with a higher growth length and
preferred orientation of Ni crystals. These observed changes can be
inferred to be due to coupled interaction forces induced by the
intensity of applied electric field (current density) and external
magnetic field known as magnetohydrodynamic (MHD) effect during
the electrodeposition process.
Abstract: In this paper, two options of anodic alumina barrier
layer thinning have been demonstrated. The approaches varied with
the duration of the voltage step. It was found that too long step of the
barrier layer thinning process leads to chemical etching of the
nanopores on their top. At the bottoms pores are not fully opened
what is disadvantageous for further applications in nanofabrication.
On the other hand, while the duration of the voltage step is controlled
by the current density (value of the current density cannot exceed
75% of the value recorded during previous voltage step) the pores are
fully opened. However, pores at the bottom obtained with this
procedure have smaller diameter, nevertheless this procedure
provides electric contact between the bare aluminum (substrate) and
electrolyte, what is suitable for template assisted electrodeposition,
one of the most cost-efficient synthesis method in nanotechnology.
Abstract: This study models the use of transcutaneous electrical
nerve stimulation on skin with a disk electrode in order to simulate
tissue damage. The current density distribution above a disk electrode
is known to be a dynamic and non-uniform quantity that is intensified
at the edges of the disk. The non-uniformity is subject to change
through using various electrode geometries or stimulation methods.
One of these methods known as edge-retarded stimulation has shown
to reduce this edge enhancement. Though progress has been made in
modeling the behavior of a disk electrode, little has been done to test
the validity of these models in simulating the actual heat transfer
from the electrode. This simulation uses finite element software to
couple the injection of current from a disk electrode to heat transfer
described by the Pennesbioheat transfer equation. An example
application of this model is studying an experimental form of
stimulation, known as edge-retarded stimulation. The edge-retarded
stimulation method will reduce the current density at the edges of the
electrode. It is hypothesized that reducing the current density edge
enhancement effect will, in turn, reduce temperature change and
tissue damage at the edges of these electrodes. This study tests this
hypothesis as a demonstration of the capabilities of this model. The
edge-retarded stimulation proved to be safer after this simulation. It is
shown that temperature change and the fraction of tissue necrosis is
much greater in the square wave stimulation. These results bring
implications for changes of procedures in transcutaneous electrical
nerve stimulation and transcutaneous spinal cord stimulation as well.
Abstract: Packaging for vanadium redox flow battery is one of the key elements for successful implementation of flow battery in the electrical energy storage system. Usually the bulky battery size and low energy densities make this technology not available for mobility application. ThereforeRFB with improved packaging size and energy capacity are highly desirable. This paper focuses on the study of packaging improvement for unit cell V-RFB to the application on Series Hybrid Electric Vehicle. Two different designs of 25cm2 and 100cm2 unit cell V-RFB at same current density are used for the sample in this investigation. Further suggestions on packaging improvement are highlighted.
Abstract: This study was focused on polymer electrolytes containing methanesulfonic acid (MSA) and p-toluene sulfonic acid (pTSA) mixed with polyacrylamide (PAAm) respectively. Impedance Spectroscopy technique has been employed to compare the ionic conductivity of these polymer electrolytes. The ionic conductivity of the PAAm hydrogel electrolytes increase upon adding the sulfonic acids. Ionic conductivity of PAAm-pTSA is higher than PAAm-MSA. The electrochemical performance evaluations were done with the tin-air cells discharge at zero current for 30minutes and at constant current density of 2.5, 5, 7.5, 10, 12.5 and 15mA/cm2. The tin-air cell of PAAm-MSA produce higher specific discharge capacity compared to PAAm-pTSA. Open-circuit voltage measurement revealed a higher voltage for tin-air cell of PAAm-MSA which is 1.27V.
Abstract: Intercalation imparts interesting features to the host graphite material. Two different types of intercalated compounds called (GIC-bisulphate or Nyex 1000 and GIC-nitrate or Nyex 3000) were tested for their adsorption capacity and ability to undergo electrochemical regeneration. It was found that Nyex 3000 showed comparatively slow kinetics along with reduced adsorption capacity to one half for acid violet 17 as adsorbate. Acid violet 17 was selected as model organic pollutant for evaluating comparative performance of said adsorbents. Both adsorbent materials showed 100% regeneration efficiency as achieved by passing a charge of 36 C g-1 at a current density of 12 mA cm-2 and a treatment time of 60 min.
Abstract: The porous silicon (PS), formed from the anodization
of a p+ type substrate silicon, consists of a network organized in a
pseudo-column as structure of multiple side ramifications. Structural
micro-topology can be interpreted as the fraction of the interconnected
solid phase contributing to thermal transport. The
reduction of dimensions of silicon of each nanocristallite during the
oxidation induced a reduction in thermal conductivity. Integration of
thermal sensors in the Microsystems silicon requires an effective
insulation of the sensor element. Indeed, the low thermal conductivity
of PS consists in a very promising way in the fabrication of integrated
thermal Microsystems.In this work we are interesting in the
measurements of thermal conductivity (on the surface and in depth)
of PS by the micro-Raman spectroscopy. The thermal conductivity is
studied according to the parameters of anodization (initial doping and
current density. We also, determine porosity of samples by
spectroellipsometry.
Abstract: Preparation of size controlled nano-particles of silver catalyst on carbon substrate from e-waste has been investigated. Chemical route was developed by extraction of the metals available in nitric acid followed by treatment with hydrofluoric acid. Silver metal particles deposited with an average size 4-10 nm. A stabilizer concentration of 10- 40 g/l was used. The average size of the prepared silver decreased with increase of the anode current density. Size uniformity of the silver nano-particles was improved distinctly at higher current density no more than 20mA... Grain size increased with EK time whereby aggregation of particles was observed after 6 h of reaction.. The chemical method involves adsorption of silver nitrate on the carbon substrate. Adsorbed silver ions were directly reduced to metal particles using hydrazine hydrate. Another alternative method is by treatment with ammonia followed by heating the carbon loaded-silver hydroxide at 980°C. The product was characterized with the help of XRD, XRF, ICP, SEM and TEM techniques.
Abstract: This study presents an investigation of
electrochemical variables and an application of the optimal
parameters in operating a continuous upflow electrocoagulation
reactor in removing dye. Direct red 23, which is azo-based, was used
as a representative of direct dyes. First, a batch mode was employed
to optimize the design parameters: electrode type, electrode distance,
current density and electrocoagulation time. The optimal parameters
were found to be iron anode, distance between electrodes of 8 mm
and current density of 30 A·m-2 with contact time of 5 min. The
performance of the continuous upflow reactor with these parameters
was satisfactory, with >95% color removal and energy consumption
in the order of 0.6-0.7 kWh·m-3.
Abstract: A simple approach is demonstrated for growing large
scale, nearly vertically aligned ZnO nanowire arrays by thermal
oxidation method. To reveal effect of temperature on growth and
physical properties of the ZnO nanowires, gold coated zinc substrates
were annealed at 300 °C and 400 °C for 4 hours duration in air. Xray
diffraction patterns of annealed samples indicated a set of well
defined diffraction peaks, indexed to the wurtzite hexagonal phase of
ZnO. The scanning electron microscopy studies show formation of
ZnO nanowires having length of several microns and average of
diameter less than 500 nm. It is found that the areal density of wires
is relatively higher, when the annealing is carried out at higher
temperature i.e. at 400°C. From the field emission studies, the values
of the turn-on and threshold field, required to draw emission current
density of 10 μA/cm2 and 100 μA/cm2 are observed to be 1.2 V/μm
and 1.7 V/μm for the samples annealed at 300 °C and 2.9 V/μm and
3.7 V/μm for that annealed at 400 °C, respectively. The field
emission current stability, investigated over duration of more than 2
hours at the preset value of 1 μA, is found to be fairly good in both
cases. The simplicity of the synthesis route coupled with the
promising field emission properties offer unprecedented advantage
for the use of ZnO field emitters for high current density
applications.
Abstract: This work attempts to improve the permselectivity of poly-ortho-phenylenediamine (PPD) coating for glutamate biosensor applications on Pt microelectrode, using constant potential amperometry and cyclic voltammetry. Percentage permeability of the modified PPD microelectrode was carried out towards hydrogen peroxide (H2O2) and ascorbic acid (AA) whereas permselectivity represents the percentage interference by AA in H2O2 detection. The 50-μm diameter Pt disk microelectrode showed a good permeability value toward H2O2 (95%) and selectivity against AA (0.01%) compared to other sizes of electrode studied here. The electrode was further modified with glutamate oxidase (GluOx) that was immobilized and cross linked with glutaraldehyde (GA, 0.125%), resulting in Pt/PPD/GluOx-GA electrode design. The maximum current density Jmax and apparent Michaelis constant, KM, obtained on Pt/PPD/GluOx-GA electrodes were 48 μA cm-2 and 50 μM, respectively. The linear region slope (LRS) was 0.96 μA cm-2 mM-1. The detection limit (LOD) for glutamate was 3.0 ± 0.6 μM. This study shows a promising glutamate microbiosensor for brain glutamate detection.
Abstract: Three similar negative differential resistance (NDR)
profiles with both high peak to valley current density ratio (PVCDR)
value and high peak current density (PCD) value in unity resonant
tunneling electronic circuit (RTEC) element is developed in this paper.
The PCD values and valley current density (VCD) values of the three
NDR curves are all about 3.5 A and 0.8 A, respectively. All PV values
of NDR curves are 0.40 V, 0.82 V, and 1.35 V, respectively. The VV
values are 0.61 V, 1.07 V, and 1.69 V, respectively. All PVCDR
values reach about 4.4 in three NDR curves. The PCD value of 3.5 A
in triple PVCDR RTEC element is better than other resonant
tunneling devices (RTD) elements. The high PVCDR value is
concluded the lower VCD value about 0.8 A. The low VCD value is
achieved by suitable selection of resistors in triple PVCDR RTEC
element. The low PV value less than 1.35 V possesses low power
dispersion in triple PVCDR RTEC element. The designed multiple
value logical level (MVLL) system using triple PVCDR RTEC
element provides equidistant logical level. The logical levels of
MVLL system are about 0.2 V, 0.8 V, 1.5 V, and 2.2 V from low
voltage to high voltage and then 2.2 V, 1.3 V, 0.8 V, and 0.2 V from
high voltage back to low voltage in half cycle of sinusoid wave. The
output level of four levels MVLL system is represented in 0.3 V, 1.1 V,
1.7 V, and 2.6 V, which satisfies the NMP condition of traditional
two-bit system. The remarkable logical characteristic of improved
MVLL system with paralleled capacitor are with four significant
stable logical levels about 220 mV, 223 mV, 228 mV, and 230 mV.
The stability and articulation of logical levels of improved MVLL
system are outstanding. The average holding time of improved MVLL
system is approximately 0.14 μs. The holding time of improved
MVLL system is fourfold than of basic MVLL system. The function of
additional capacitor in the improved MVLL system is successfully
discovered.
Abstract: Vertical Double Gate (DG) Metal Oxide Semiconductor Field Effect Transistor (MOSFET) is believed to suppress various short channel effect problems. The gate to channel coupling in vertical DG-MOSFET are doubled, thus resulting in higher current density. By having two gates, both gates are able to control the channel from both sides and possess better electrostatic control over the channel. In order to ensure that the transistor possess a superb turn-off characteristic, the subs-threshold swing (SS) must be kept at minimum value (60-90mV/dec). By utilizing SILVACO TCAD software, an n-channel vertical DG-MOSFET was successfully designed while keeping the sub-threshold swing (SS) value as minimum as possible. From the observation made, the value of sub-threshold swing (SS) was able to be varied by adjusting the height of the silicon pillar. The minimum value of sub-threshold swing (SS) was found to be 64.7mV/dec with threshold voltage (VTH) of 0.895V. The ideal height of the vertical DG-MOSFET pillar was found to be at 0.265 µm.
Abstract: By the application of an improved back-propagation
neural network (BPNN), a model of current densities for a solid oxide
fuel cell (SOFC) with 10 layers is established in this study. To build
the learning data of BPNN, Taguchi orthogonal array is applied to
arrange the conditions of operating parameters, which totally 7 factors
act as the inputs of BPNN. Also, the average current densities
achieved by numerical method acts as the outputs of BPNN.
Comparing with the direct solution, the learning errors for all learning
data are smaller than 0.117%, and the predicting errors for 27
forecasting cases are less than 0.231%. The results show that the
presented model effectively builds a mathematical algorithm to predict
performance of a SOFC stack immediately in real time.
Also, the calculating algorithms are applied to proceed with the
optimization of the average current density for a SOFC stack. The
operating performance window of a SOFC stack is found to be
between 41137.11 and 53907.89. Furthermore, an inverse predicting
model of operating parameters of a SOFC stack is developed here by
the calculating algorithms of the improved BPNN, which is proved to
effectively predict operating parameters to achieve a desired
performance output of a SOFC stack.
Abstract: Non-uniform current distribution in polymer
electrolyte membrane fuel cells results in local over-heating,
accelerated ageing, and lower power output than expected. This
issue is very critical when fuel cell experiences water flooding. In
this work, the performance of a PEM fuel cell is investigated under
cathode flooding conditions. Two-dimensional partially flooded
GDL models based on the conservation laws and electrochemical
relations are proposed to study local current density distributions
along flow fields over a wide range of cell operating conditions.
The model results show a direct association between cathode inlet
humidity increases and that of average current density but the
system becomes more sensitive to flooding. The anode inlet
relative humidity shows a similar effect. Operating the cell at
higher temperatures would lead to higher average current densities
and the chance of system being flooded is reduced. In addition,
higher cathode stoichiometries prevent system flooding but the
average current density remains almost constant. The higher anode
stoichiometry leads to higher average current density and higher
sensitivity to cathode flooding.
Abstract: Electrochemical-oxidation of Reactive Black-5 (RB- 5) was conducted for degradation using DSA type Ti/RuO2-SnO2- Sb2O5 electrode. In the study, for electro-oxidation, electrode was indigenously fabricated in laboratory using titanium as substrate. This substrate was coated using different metal oxides RuO2, Sb2O5 and SnO2 by thermal decomposition method. Laboratory scale batch reactor was used for degradation and decolorization studies at pH 2, 7 and 11. Current density (50mA/cm2) and distance between electrodes (8mm) were kept constant for all experiments. Under identical conditions, removal of color, COD and TOC at initial pH 2 was 99.40%, 55% and 37% respectively for initial concentration of 100 mg/L RB-5. Surface morphology and composition of the fabricated electrode coatings were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) respectively. Coating microstructure was analyzed by X-ray diffraction (XRD). Results of this study further revealed that almost 90% of oxidation occurred within 5-10 minutes.
Abstract: This study investigates the electrical performance of a
planar solid oxide fuel cell unit with cross-flow configuration when the fuel utilization gets higher and the fuel inlet flow are non-uniform.
A software package in this study solves two-dimensional,
simultaneous, partial differential equations of mass, energy, and
electro-chemistry, without considering stack direction variation. The
results show that the fuel utilization increases with a decrease in the molar flow rate, and the average current density decreases when the
molar flow rate drops. In addition, non-uniform Pattern A will induce more severe happening of non-reaction area in the corner of the fuel
exit and the air inlet. This non-reaction area deteriorates the average
current density and then deteriorates the electrical performance to –7%.
Abstract: The mechanism behind the electromigration and
thermomigration failure in flip-chip solder joints with Cu-pillar bumps
was investigated in this paper through using finite element method.
Hot spot and the current crowding occurrs in the upper corner of
copper column instead of solders of the common solder ball. The
simulation results show that the change in thermal gradient is
noticeable, which might greatly affect the reliability of solder joints
with Cu-pillar bumps under current stressing. When the average
applied current density is increased from 1×104 A/cm2 to 3×104 A/cm2
in solders, the thermal gradient would increase from 74 K/cm to 901
K/cm at an ambient temperature of 25°C. The force from thermal
gradient of 901 K/cm can nearly induce thermomigration by itself.
With the increase in applied current, the thermal gradient is growing. It
is proposed that thermomigration likely causes a serious reliability
issue for Cu column based interconnects.
Abstract: In this study, a nickel film with nano-crystalline grains,
high hardness and smooth surface was electrodeposited using a post
supercritical carbon dioxide (CO2) mixed Watts electrolyte. Although
the hardness was not as high as its Sc-CO2 counterpart, the thin coating
contained significantly less number of nano-sized pinholes. By
measuring the escape concentration of the dissolved CO2 in post
Sc-CO2 mixed electrolyte with the elapsed time, it was believed that
the residue of dissolved CO2 bubbles should closely relate to the
improvement in hardness and surface roughness over its conventional
plating counterpart. Therefore, shortening the duration of
electroplating with the raise of current density up to 0.5 A/cm2 could
effectively retain more post Sc-CO2 mixing effect. This study not only
confirms the roles of dissolved CO2 bubbles in electrolyte but also
provides a potential process to overcome most issues associated with
the cost in building high-pressure chamber for large size products and
continuous plating using supercritical method.