Abstract: Among the various methods of treatment, advanced oxidation processes (AOP) are the most promising ones. In this study, Peroxi Electrocoagulation Process (PEP) was investigated for the treatment of detergent wastewater. The process was compared with electrooxidation treatment. The results showed that chemical oxygen demand (COD) was high 7584 mgO2.L-1, while the biochemical oxygen demand was low (250 mgO2.L-1). This wastewater was hardly biodegradable. Electrochemical process was carried out for the removal of detergent using a glass reactor with a volume of 1 L and fitted with three electrodes. A direct current (DC) supply was used. Samples were taken at various current density (0.0227 A/cm2 to 0.0378 A/cm2) and reaction time (1-2-3-4 and 5 hour). Finally, the COD was determined. The results indicated that COD removal efficiency of PEP was observed to increase with current intensity and reached to 77% after 5 h. The highest removal efficiency was observed after 5 h of treatment.
Abstract: Various techniques including conventional and advanced have been employed for the boron treatment from water and wastewater. The electrocoagulation involves an electrolytic reactor for coagulation/flotation with aluminium as anode and cathode. There is aluminium as coagulant to be used for removal which may induce secondary pollution in chemical coagulation. The purpose of this study is to investigate and compare the performance between electrocoagulation and chemical coagulation on boron removal from synthetic wastewater. The effect of different parameters, such as pH reaction, coagulant dosage, and initial boron concentration were examined. The results show that the boron removal using chemical coagulation was lower. At the optimum condition (e.g. pH 8 and 0.8 mol coagulant dosage), boron removal efficiencies for chemical coagulation and electrocoagulation were 61% and 91%, respectively. In addition, the electrocoagulation needs no chemical reagents and makes the boron treatment easy for application.
Abstract: A flow column has been innovatively used in the
design of a new electrocoagulation reactor (ECR1) that will reduce
the temperature of water being treated; where the flow columns work
as a radiator for the water being treated. In order to investigate the
performance of ECR1 and compare it to that of traditional reactors;
600 mL water samples with an initial temperature of 350C were
pumped continuously through these reactors for 30 min at current
density of 1 mA/cm2. The temperature of water being treated was
measured at 5 minutes intervals over a 30 minutes period using a
thermometer. Additional experiments were commenced to investigate
the effects of initial temperature (15-350C), water conductivity (0.15
– 1.2 S) and current density (0.5 -3 mA/cm2) on the performance of
ECR1.
The results obtained demonstrated that the ECR1, at a current
density of 1 mA/cm2 and continuous flow model, reduced water
temperature from 350C to the vicinity of 280C during the first 15
minutes and kept the same level till the end of the treatment time.
While, the temperature increased from 28.1 to 29.80C and from 29.8
to 31.90C in the batch and the traditional continuous flow models
respectively. In term of initial temperature, ECR1 maintained the
temperature of water being treated within the range of 22 to 280C
without the need for external cooling system even when the initial
temperatures varied over a wide range (15 to 350C). The influent
water conductivity was found to be a significant variable that affect
the temperature. The desirable value of water conductivity is 0.6 S.
However, it was found that the water temperature increased rapidly
with a higher current density.
Abstract: The goal of this experiment is to evaluate the
effectiveness of different leachate pre-treatment options in terms of
COD and ammonia removal. This research focused on the evaluation
of physical-chemical methods for pre-treatment of leachate that
would be effective and rapid in order to satisfy the requirements of
the sewer discharge by-laws. The four pre-treatment options
evaluated were: air stripping, chemical coagulation, electrocoagulation
and advanced oxidation with sodium ferrate. Chemical
coagulation reported the best COD removal rate at 43%, compared to
18% for both air stripping and electro-coagulation, and 20% for
oxidation with sodium ferrate. On the other hand, air stripping was
far superior to the other treatment options in terms of ammonia
removal with 86%. Oxidation with sodium ferrate reached only 16%,
while chemical coagulation and electro-coagulation removed less
than 10%. When combined, air stripping and chemical coagulation
removed up to 50% COD and 85% ammonia.
Abstract: In Jordan having deficit atmospheric precipitation, an
increase in water demand occurs during summer months. Jordan can
be regarded with a relatively high potential for wastewater recycling
and reuse. The main purpose of this paper was to investigate the
removal of total suspended solids (TSS) and chemical oxygen
demand (COD) for olive mill wastewater (OMW) by
electrocoagulation (EC) process. In the combination of
electrocoagulation by using coupled iron–aluminum electrodes, the
optimum working pH was found to be around 6. Results indicated
that the electrocoagulation process allowed removal of TSS and COD
of about 82.5% and 47.5%, respectively at 45 mA/cm2 after 70
minutes by using coupled iron–aluminum electrodes. It was
demonstrated that the maximum TSS and COD removals were
obtained at some optimum experimental parameters for current
density, pH, and reaction time.
Abstract: Synthetic oily wastewaters were prepared from metal working fluids (MWF). Electrocoagulation experiments were performed under constant voltage application. The current, conductivity, pH, dissolved oxygen concentration and temperature were recorded on line at every 5 seconds during the experiments. Effects of applied voltage differences, electrode materials and distance between electrodes on removal efficiency have been investigated. According to the experimental results, the treatment of MWF wastewaters by iron electrodes rather than aluminum and stainless steel was much quicker; and the distance between electrodes should be less than 1cm. The electrocoagulation process was modeled by using block oriented approach and found out that it can be modeled as a single input and multiple output system. Modeling studies indicates that the electrocoagulation process has a nonlinear model structure.
Abstract: The objective of this study is to investigate the performance of the electrocoagulation process for color and COD removal in palm oil wastewater using a 10 L batch reactor. Iron was used as electrodes and the distance between electrodes was 2 cm. The effects of operating parameters: current voltage (6, 12 and 18 volt), reaction time (5, 15, 30, 45 and 60 min) and initial pH (4 and 9) of treatment efficiency were examine. The result showed that decolorization and COD removal efficiency increased with the increase in current voltage and reaction time. The proper condition for decolorization achieved at initial pH 4 and 9 were current voltage of 12 volt, reaction time 30 min. The decolorization efficiency reached 90.4% and 88.9%, respectively. COD removal was achiveved at current voltage 12 volt, reaction time 15 min. COD removal efficiency was 89.2 % and 83.0%, respectively. From the results, to show electrocoagulation process can treat palm oil mill wastewater in both acidic and basic condition at high efficiency for color and COD removal. Consequently, electrocoagulation process can be used or applied as a post-treatment step to improve the quality of the final discharge in term of color and residual COD removal.
Abstract: This study presents an investigation of
electrochemical variables and an application of the optimal
parameters in operating a continuous upflow electrocoagulation
reactor in removing dye. Direct red 23, which is azo-based, was used
as a representative of direct dyes. First, a batch mode was employed
to optimize the design parameters: electrode type, electrode distance,
current density and electrocoagulation time. The optimal parameters
were found to be iron anode, distance between electrodes of 8 mm
and current density of 30 A·m-2 with contact time of 5 min. The
performance of the continuous upflow reactor with these parameters
was satisfactory, with >95% color removal and energy consumption
in the order of 0.6-0.7 kWh·m-3.
Abstract: The electrochemical coagulation of a kaolin
suspension was investigated at the currents of 0.06, 0.12, 0.22, 0.44,
0.85 A (corresponding to 0.68, 1.36, 2.50, 5.00, 9.66 mA·cm-2,
respectively) for the contact time of 5, 10, 20, 30, and 50 min. The
TSS removal efficiency at currents of 0.06 A, 0.12 A and 0.22 A
increased with the amount of iron generated by the sacrificial anode,
while the removal efficiencies did not increase proportionally with
the amount of iron generated at the currents of 0.44 and 0.85 A,
where electroflotation was clearly observed. Zeta potential
measurement illustrated the presence of the highly positive charged
particles created by sorption of highly charged polymeric metal
hydroxyl species onto the negative surface charged kaolin particles at
both low and high applied currents. The disappearance of the
individual peaks after certain contact times indicated the attraction
between these positive and negative charged particles causing
agglomeration. It was concluded that charge neutralization of the
individual species was not the only mechanism operating in the
electrocoagulation process at any current level, but electrostatic
attraction was likely to co-operate or mainly operate.
Abstract: Following the research in the Department of environmental engineering in Faculty of mechanical engineering on Technical University of Kosice and experiences with electrocoagulation style of disposal waste water, there were designed and partly examining the equipment of two stage revitalization on the standing and little fusible water of tenet electrolysis on the little tarns. With the cooperation with vet experts was that manners prove and it is innocuous for animals, during which time cyanobacteria are totally paralyzed. For the implementation of science and research results have been obtained by means EU funds for structural development.