Abstract: Non-uniform current distribution in polymer
electrolyte membrane fuel cells results in local over-heating,
accelerated ageing, and lower power output than expected. This
issue is very critical when fuel cell experiences water flooding. In
this work, the performance of a PEM fuel cell is investigated under
cathode flooding conditions. Two-dimensional partially flooded
GDL models based on the conservation laws and electrochemical
relations are proposed to study local current density distributions
along flow fields over a wide range of cell operating conditions.
The model results show a direct association between cathode inlet
humidity increases and that of average current density but the
system becomes more sensitive to flooding. The anode inlet
relative humidity shows a similar effect. Operating the cell at
higher temperatures would lead to higher average current densities
and the chance of system being flooded is reduced. In addition,
higher cathode stoichiometries prevent system flooding but the
average current density remains almost constant. The higher anode
stoichiometry leads to higher average current density and higher
sensitivity to cathode flooding.
Abstract: In this paper, the solubility of CO2 in AMP solution
have been measured at temperature range of ( 293, 303 ,313,323)
K.The amine concentration ranges studied are (2.0, 2.8, and 3.4) M.
A solubility apparatus was used to measure the solubility of CO2 in
AMP solution on samples of flue gases from Thermal and Central
Power Plants of Esfahan Steel Company. The modified Kent
Eisenberg model was used to correlate and predict the vapor-liquid
equilibria of the (CO2 + AMP + H2O) system. The model predicted
results are in good agreement with the experimental vapor-liquid
equilibrium measurements.
Abstract: Direct conversion of methane to methanol by partial oxidation in a thermal reactor has a poor yield of about 2% which is less than the expected economical yield of about 10%. Conventional thermal catalytic reactors have been proposed to be superseded by plasma reactors as a promising approach, due to strength of the electrical energy which can break C-H bonds of methane. Among the plasma techniques, non-thermal dielectric barrier discharge (DBD) plasma chemical process is one of the most future promising technologies in synthesizing methanol. The purpose of this paper is presenting a brief review of CH4 oxidation with O2 in DBD plasma reactors based on the recent investigations. For this reason, the effect of various parameters of reactor configuration, feed ratio, applied voltage, residence time (gas flow rate), type of applied catalyst, pressure and reactor wall temperature on methane conversion and methanol selectivity are discussed.