Abstract: A comparison of activity and stability of the as-formed
Pt/C, Pt-Co and Pt-Pd/C electrocatalysts, prepared by a combined
approach of impregnation and seeding, was performed. According to
the activity test in a single Proton Exchange Membrane (PEM) fuel
cell, the Oxygen Reduction Reaction (ORR) activity of the Pt-M/C
electrocatalyst was slightly lower than that of Pt/C. The j0.9 V and
E10 mA/cm2 of the as-prepared electrocatalysts increased in the order of
Pt/C > Pt-Co/C > Pt-Pd/C. However, in the medium-to-high current
density region, Pt-Pd/C exhibited the best performance. With regard to
their stability in a 0.5 M H2SO4 electrolyte solution, the
electrochemical surface area decreased as the number of rounds of
repetitive potential cycling increased due to the dissolution of the
metals within the catalyst structure. For long-term measurement, Pt-
Pd/C was the most stable than the other three electrocatalysts.
Abstract: This paper presents a synthetic jet air blower actuated
by PZT for air blowing for air-breathing micro PEM fuel cell. The
several factors to affect the performance of air-breathing PEM fuel cell
such as air flow rate, opening ratio and cathode open type in the
cathode side were studied. Especially, an air flow rate is critical
condition to improve its performance. In this paper, we developed a
synthetic jet air blower to supply a high stoichiometric air flow. The
synthetic jet mechanism is a zero mass flux device that converts
electrical energy into the momentum. The synthetic jet actuation is
usually generated by a traditional PZT actuator, which consists of a
small cylindrical cavity, in/outlet channel and PZT diaphragms. The
flow rate of the fabricated synthetic jet air blower was 400cc/min at
550Hz and its power consumption was very low under 0.3W. The
proposed air-breathing PEM fuel cell which installed synthetic jet air
blower was higher performance and stability during continuous
operation than the air-breathing fuel cell without auxiliary device to
supply the air. The results showed that the maximum power density
was 188mW/cm2 at 400mA/cm2. This maximum power density and
durability were improved more than 40% and 20%, respectively.
Abstract: Non-uniform current distribution in polymer
electrolyte membrane fuel cells results in local over-heating,
accelerated ageing, and lower power output than expected. This
issue is very critical when fuel cell experiences water flooding. In
this work, the performance of a PEM fuel cell is investigated under
cathode flooding conditions. Two-dimensional partially flooded
GDL models based on the conservation laws and electrochemical
relations are proposed to study local current density distributions
along flow fields over a wide range of cell operating conditions.
The model results show a direct association between cathode inlet
humidity increases and that of average current density but the
system becomes more sensitive to flooding. The anode inlet
relative humidity shows a similar effect. Operating the cell at
higher temperatures would lead to higher average current densities
and the chance of system being flooded is reduced. In addition,
higher cathode stoichiometries prevent system flooding but the
average current density remains almost constant. The higher anode
stoichiometry leads to higher average current density and higher
sensitivity to cathode flooding.