Abstract: Most often the contaminants are not taken seriously into consideration, and this behavior comes out directly from the lack of monitoring and professional reporting about pollution in the printing facilities in Serbia. The goal of planned and systematic ozone measurements in ambient air of the screen printing facilities in Novi Sad is to examine of its impact on the employees health, and to track trends in concentration. In this study, ozone concentrations were determined by using discontinuous and continuous method during the automatic and manual screen printing process. Obtained results indicates that the average concentrations of ozone measured during the automatic process were almost 3 to 28 times higher for discontinuous and 10 times higher for continuous method (1.028 ppm) compared to the values prescribed by OSHA. In the manual process, average concentrations of ozone were within prescribed values for discontinuous and almost 3 times higher for continuous method (0.299 ppm).
Abstract: Mercury is a natural occurring element and present in
various concentrations in the environment. Due to its toxic effects, it
is desirable to research mercury sensitive materials to adsorb
mercury. This paper describes the preparation of Au nanoparticles for
mercury adsorption by using a microwave (MW)-polyol method in
the presence of three different Sodium Chloride (NaCl)
concentrations (10, 20 and 30 mM). Mixtures of spherical, triangular,
octahedral, decahedral particles and 1-D product were obtained using
this rapid method. Sizes and shapes was found strongly depend on the
concentrations of NaCl. Without NaCl concentration, spherical,
triangular plates, octahedral, decahedral nanoparticles and 1D
product were produced. At the lower NaCl concentration (10 mM),
spherical, octahedral and decahedral nanoparticles were present,
while spherical and decahedral nanoparticles were preferentially form
by using 20 mM of NaCl concentration. Spherical, triangular plates,
octahedral and decahedral nanoparticles were obtained at the highest
NaCl concentration (30 mM). The amount of mercury adsorbed using
20 ppm mercury solution is the highest (67.5 %) for NaCl
concentration of 30 mM. The high yield of polygonal particles will
increase the mercury adsorption. In addition, the adsorption of
mercury is also due to the sizes of the particles. The sizes of particles
become smaller with increasing NaCl concentrations (size ranges, 5-
16 nm) than those synthesized without addition of NaCl (size ranges
11-32 nm). It is concluded that NaCl concentrations affects the
formation of sizes and shapes of Au nanoparticles thus affects the
mercury adsorption.
Abstract: An experimental investigation was performed on pulp
liquid flow in straight ducts with a square cross section. Fully
developed steady flow was visualized and the fiber concentration was
obtained using a light-section method developed by the author et al.
The obtained results reveal quantitatively, in a definite form, the
distribution of the fiber concentration. From the results and
measurements of pressure loss, it is found that the flow characteristics
of pulp liquid in ducts can be classified into five patterns. The
relationships among the distributions of mean and fluctuation of fiber
concentration, the pressure loss and the flow velocity are discussed,
and then the features for each pattern are extracted. The degree of
nonuniformity of the fiber concentration, which is indicated by the
standard deviation of its distribution, is decreased from 0.3 to 0.05
with an increase in the velocity of the tested pulp liquid from 0.4 to
0.8%.
Abstract: Fick's second law equations for unsteady state
diffusion of salt into the potato tissues were solved numerically. The
set of equations resulted from implicit modeling were solved using
Thomas method to find the salt concentration profiles in solid phase.
The needed effective diffusivity and equilibrium distribution
coefficient were determined experimentally. Cylindrical samples of
potato were infused with aqueous NaCl solutions of 1-3%
concentrations, and variations in salt concentrations of brine were
determined over time. Solute concentrations profiles of samples were
determined by measuring salt uptake of potato slices. For the studied
conditions, equilibrium distribution coefficients were found to be
dependent on salt concentrations, whereas the effective diffusivity
was slightly affected by brine concentration.
Abstract: Double-diffusive natural convection in an open top
square cavity and heated from the side is studied numerically.
Constant temperatures and concentration are imposed along the right
and left walls while the heat balance at the surface is assumed to obey
Newton-s law of cooling. The finite difference method is used to
solve the dimensionless governing equations. The numerical results
are reported for the effect of Marangoni number, Biot number and
Prandtl number on the contours of streamlines, temperature and
concentration. The predicted results for the average Nusselt number
and Sherwood number are presented for various parametric
conditions. The parameters involved are as follows; the thermal
Marangoni number, 0 ≤ MaT ≤1000 , the solutal Marangoni number,
0 1000 c ≤ Ma ≤ , the Biot number, 0 ≤ Bi ≤ 6 , Grashof number,
5 Gr = 10 and aspect ratio 1. The study focused on both flows; thermal
dominated, N = 0.8 , and compositional dominated, N = 1.3 .
Abstract: A laboratory set-up was designed to survey the
effectiveness of UV/O3 advanced oxidation process (AOP) for the
removal of Carbaryl from polluted water in batch reactor. The study
was carried out by UV/O3 process for water samples containing 1 to
20 mg/L of Carbaryl in distilled water. Also the range of drinking
water resources adjusted in synthetic water and effects of contact
time, pH and Carbaryl concentration were studied. The residual
pesticide concentration was determined by applying high
performance liquid chromatography (HPLC). The results indicated
that increasing of retention time and pH, enhances pesticide removal
efficiency. The removal efficiency has been affected by pesticide
initial concentration. Samples with low pesticide concentration
showed a remarkable removal efficiency compared to the samples
with high pesticide concentration. AOP method showed the removal
efficiencies of 80% to 100%. Although process showed high
performance for removal of pesticide from water samples, this
process has different disadvantages including complication,
intolerability, difficulty of maintenance and equipmental and
structural requirements.
Abstract: In the present study, Convective heat transfer
coefficient and pressure drop of Al2O3/water nanofluid in laminar
flow regime under constant heat flux conditions inside a circular tube
were experimentally investigated. Al2O3/water nanofluid with 0.5%
and 1% volume concentrations with 15 nm diameter nanoparticles
were used as working fluid. The effect of different volume
concentrations on convective heat transfer coefficient and friction
factor was studied. The results emphasize that increasing of particle
volume concentration leads to enhance convective heat transfer
coefficient. Measurements show the average heat transfer coefficient
enhanced about 11-20% with 0.5% volume concentration and
increased about 16-27% with 1% volume concentration compared to
distilled water. In addition, the convective heat transfer coefficient of
nanofluid enhances with increase in heat flux. From the results, the
average ratio of (fnf/fbf) was about 1.10 for 0.5% volume
concentration. Therefore, there is no significant increase in friction
factor for nanofluids.
Abstract: Methanol-to-olefins coupled with transformation of
coal or natural gas to methanol gives an interesting and promising way
to produce ethylene and propylene. To investigate solid concentration
in gas-solid fluidized bed for methanol-to-olefins process catalyzed by
SAPO-34, a cold model experiment system is established in this paper.
The system comprises a gas distributor in a 300mm internal diameter
and 5000mm height acrylic column, the fiber optic probe system and
series of cyclones. The experiments are carried out at ambient
conditions and under different superficial gas velocity ranging from
0.3930m/s to 0.7860m/s and different initial bed height ranging from
600mm to 1200mm. The effects of radial distance, axial distance,
superficial gas velocity, initial bed height on solid concentration in the
bed are discussed. The effects of distributor shape and porosity on
solid concentration are also discussed. The time-averaged solid
concentration profiles under different conditions are obtained.
Abstract: Anaerobic Digestion has become a promising
technology for biological transformation of organic fraction of the
municipal solid wastes (MSW). In order to represent the kinetic
behavior of such biological process and thereby to design a reactor
system, development of a mathematical model is essential.
Addressing this issue, a simplistic mathematical model has been
developed for anaerobic digestion of MSW in a continuous flow
reactor unit under homogeneous steady state condition. Upon
simulated hydrolysis, the kinetics of biomass growth and substrate
utilization rate are assumed to follow first order reaction kinetics.
Simulation of this model has been conducted by studying sensitivity
of various process variables. The model was simulated using typical
kinetic data of anaerobic digestion MSW and typical MSW
characteristics of Kolkata. The hydraulic retention time (HRT) and
solid retention time (SRT) time were mainly estimated by varying
different model parameters like efficiency of reactor, influent
substrate concentration and biomass concentration. Consequently,
design table and charts have also been prepared for ready use in the
actual plant operation.
Abstract: Influence of octane and benzene on plant cell
ultrastructure and enzymes of basic metabolism, such as nitrogen
assimilation and energy generation have been studied. Different
plants: perennial ryegrass (Lolium perenne) and alfalfa (Medicago
sativa); crops- maize (Zea mays L.) and bean (Phaseolus vulgaris);
shrubs – privet (Ligustrum sempervirens) and trifoliate orange
(Poncirus trifoliate); trees - poplar (Populus deltoides) and white
mulberry (Morus alba L.) were exposed to hydrocarbons of different
concentrations (1, 10 and 100 mM). Destructive changes in bean and
maize leaves cells ultrastructure under the influence of benzene
vapour were revealed at the level of photosynthetic and energy
generation subcellular organells. Different deviations at the level of
subcellular organelles structure and distribution were observed in
alfalfa and ryegrass root cells under the influence of benzene and
octane, absorbed through roots. The level of destructive changes is
concentration dependent. Benzene at low 1 and 10 mM concentration
caused the increase in glutamate dehydrogenase (GDH) activity in
maize roots and leaves and in poplar and mulberry shoots, though to
higher extent in case of lower, 1mM concentration. The induction
was more intensive in plant roots. The highest tested 100mM
concentration of benzene was inhibitory to the enzyme in all plants.
Octane caused induction of GDH in all grassy plants at all tested
concentrations; however the rate of induction decreased parallel to
increase of the hydrocarbon concentration. Octane at concentration 1
mM caused induction of GDH in privet, trifoliate and white mulberry
shoots. The highest, 100mM octane was characterized by inhibitory
effect to GDH activity in all plants. Octane had inductive effect on
malate dehydrogenase in almost all plants and tested concentrations,
indicating the intensification of Trycarboxylic Acid Cycle.
The data could be suggested for elaboration of criteria for plant
selection for phytoremediation of oil hydrocarbons contaminated
soils.
Abstract: This paper unifies power optimization approaches in
various energy converters, such as: thermal, solar, chemical, and
electrochemical engines, in particular fuel cells. Thermodynamics
leads to converter-s efficiency and limiting power. Efficiency
equations serve to solve problems of upgrading and downgrading of
resources. While optimization of steady systems applies the
differential calculus and Lagrange multipliers, dynamic optimization
involves variational calculus and dynamic programming. In reacting
systems chemical affinity constitutes a prevailing component of an
overall efficiency, thus the power is analyzed in terms of an active
part of chemical affinity. The main novelty of the present paper in the
energy yield context consists in showing that the generalized heat
flux Q (involving the traditional heat flux q plus the product of
temperature and the sum products of partial entropies and fluxes of
species) plays in complex cases (solar, chemical and electrochemical)
the same role as the traditional heat q in pure heat engines.
The presented methodology is also applied to power limits in fuel
cells as to systems which are electrochemical flow engines propelled
by chemical reactions. The performance of fuel cells is determined by
magnitudes and directions of participating streams and mechanism of
electric current generation. Voltage lowering below the reversible
voltage is a proper measure of cells imperfection. The voltage losses,
called polarization, include the contributions of three main sources:
activation, ohmic and concentration. Examples show power maxima
in fuel cells and prove the relevance of the extension of the thermal
machine theory to chemical and electrochemical systems. The main
novelty of the present paper in the FC context consists in introducing
an effective or reduced Gibbs free energy change between products p
and reactants s which take into account the decrease of voltage and
power caused by the incomplete conversion of the overall reaction.
Abstract: A method and apparatus for noninvasive measurement
of blood glucose concentration based on transilluminated laser beam
via the Index Finger has been reported in this paper. This method
depends on atomic gas (He-Ne) laser operating at 632.8nm
wavelength. During measurement, the index finger is inserted into the
glucose sensing unit, the transilluminated optical signal is converted
into an electrical signal, compared with the reference electrical
signal, and the obtained difference signal is processed by signal
processing unit which presents the results in the form of blood
glucose concentration. This method would enable the monitoring
blood glucose level of the diabetic patient continuously, safely and
noninvasively.
Abstract: Biochemical Oxygen Demand (BOD) is a measure of
the oxygen used in bacteria mediated oxidation of organic substances
in water and wastewater. Theoretically an infinite time is required for
complete biochemical oxidation of organic matter, but the
measurement is made over 5-days at 20 0C or 3-days at 27 0C test
period with or without dilution. Researchers have worked to further
reduce the time of measurement.
The objective of this paper is to review advancement made in
BOD measurement primarily to minimize the time and negate the
measurement difficulties. Survey of literature review in four such
techniques namely BOD-BARTTM, Biosensors, Ferricyanidemediated
approach, luminous bacterial immobilized chip method.
Basic principle, method of determination, data validation and their
advantage and disadvantages have been incorporated of each of the
methods.
In the BOD-BARTTM method the time lag is calculated for the
system to change from oxidative to reductive state. BIOSENSORS
are the biological sensing element with a transducer which produces
a signal proportional to the analyte concentration. Microbial species
has its metabolic deficiencies. Co-immobilization of bacteria using
sol-gel biosensor increases the range of substrate. In ferricyanidemediated
approach, ferricyanide has been used as e-acceptor instead
of oxygen. In Luminous bacterial cells-immobilized chip method,
bacterial bioluminescence which is caused by lux genes was
observed. Physiological responses is measured and correlated to
BOD due to reduction or emission.
There is a scope to further probe into the rapid estimation of BOD.
Abstract: Newcastle Disease Virus (NDV), an avian
paramyxovirus, is a highly contagious, generalised virus disease of
domestic poultry and wild birds characterized by gastro-intestinal,
respiratory and nervous signs. In this study, it was shown that NDV
strain AF2240 and V4-UPM are cytolytic to Human Promyelocytic
Leukemia, HL60 and Human T-lymphoblastic Leukemia, CEM-SS
cells. Results from MTT cytolytic assay showed that CD50 for NDV
AF2240 against HL60 was 130 HAU and NDV V4-UPM against
HL60 and CEM-SS were 110.6 and 150.9 HAU respectively.
Besides, both strains were found to inhibit the proliferation of cells in
a dose dependent manner. The mode of cell death either by apoptosis
or necrosis was further analyzed using acridine orange and propidium
iodide (AO/PI) staining. Our results showed that both NDV strains
induced primarily apoptosis in treated cells at CD50 concentration. In
conclusion, both NDV strains caused cytolytic effects primarily via
apoptosis in leukemia cells.
Abstract: In this study, the dispersed model is used to predict
gas phase concentration, liquid drop concentration. The venturi
scrubber efficiency is calculated by gas phase concentration. The
modified model has been validated with available experimental data
of Johnstone, Field and Tasler for a range of throat gas velocities,
liquid to gas ratios and particle diameters and is used to study the
effect of some design parameters on collection efficiency.
Abstract: Methanol-to-olefins (MTO) coupled with
transformation of coal or natural gas to methanol gives an interesting
and promising way to produce ethylene and propylene. To investigate
solid concentration in gas-solid fluidized bed for methanol-to-olefins
process catalyzed by SAPO-34, a cold model experiment system is
established in this paper. The system comprises a gas distributor in a
300mm internal diameter and 5000mm height acrylic column, the
fiber optic probe system and series of cyclones. The experiments are
carried out at ambient conditions and under different superficial gas
velocity ranging from 0.3930m/s to 0.7860m/s and different initial bed
height ranging from 600mm to 1200mm. The effects of radial
distance, axial distance, superficial gas velocity, initial bed height on
solid concentration in the bed are discussed. The effects of distributor
shape and porosity on solid concentration are also discussed. The
time-averaged solid concentration profiles under different conditions
are obtained.
Abstract: In this paper we propose a novel RF LDMOS structure which employs a thin strained silicon layer at the top of the channel and the N-Drift region. The strain is induced by a relaxed Si0.8 Ge0.2 layer which is on top of a compositionally graded SiGe buffer. We explain the underlying physics of the device and compare the proposed device with a conventional LDMOS in terms of energy band diagram and carrier concentration. Numerical simulations of the proposed strained silicon laterally diffused MOS using a 2 dimensional device simulator indicate improvements in saturation and linear transconductance, current drivability, cut off frequency and on resistance. These improvements are however accompanied with a suppression in the break down voltage.
Abstract: Five lignin samples were fractionated with
Acetone/Water mixtures and the obtained fractions were subjected to
extensive structural characterization, including Fourier Transform
Infrared (FT-IR), Gel permeation Chromatography (GPC) and
Phosphorus-31 NMR spectroscopy (31P-NMR). The results showed
that for all studied lignins the solubility increases with the increment
of the acetone concentration. Wheat straw lignin has the highest
solubility in 90/10 (v/v) Acetone/Water mixture, 400 mg lignin being
dissolved in 1 mL mixture. The weight average molecular weight of
the obtained fractions increased with the increment of acetone
concentration and thus with solubility. 31P-NMR analysis based on
lignin modification by reactive phospholane into phosphitylated
compounds was used to differentiate and quantify the different types
of OH groups (aromatic, aliphatic, and carboxylic) found in the
fractions obtained with 70/30 (v/v) Acetone/Water mixture.
Abstract: In this paper, removal of chromium(VI) from aqueous
solution has been researched using reverse osmosis. The influence of
transmembrane pressure and feed concentration on permeate flux,
water recovery, permeate concentration, and salt rejection was
studied. The results showed that according to the variation of
transmembrane pressure and feed concentration, the permeate flux
and salt rejection were in the range 19.17 to 58.75 l/m2.min and
99.51 to 99.8 %, respectively. The highest permeate flux, 58.75
l/m2.min, and water recovery, 42.47 %, were obtained in the highest
pressure and the lowest feed concentration. On the other hand, the
lowest permeate concentration, 0.01 mg/l, and the highest salt
rejection, 99.8 %, were obtained in the highest pressure and the
lowest feed concentration.
Abstract: Noise has adverse effect on human health and
comfort. Noise not only cause hearing impairment, but it also acts as
a causal factor for stress and raising systolic pressure. Additionally it
can be a causal factor in work accidents, both by marking hazards
and warning signals and by impeding concentration. Industry
workers also suffer psychological and physical stress as well as
hearing loss due to industrial noise. This paper proposes an approach
to enable engineers to point out quantitatively the noisiest source for
modification, while multiple machines are operating simultaneously.
The model with the point source and spherical radiation in a free field
was adopted to formulate the problem. The procedure works very
well in ideal cases (point source and free field). However, most of the
industrial noise problems are complicated by the fact that the noise is
confined in a room. Reflections from the walls, floor, ceiling, and
equipment in a room create a reverberant sound field that alters the
sound wave characteristics from those for the free field. So the model
was validated for relatively low absorption room at NIT Kurukshetra
Central Workshop. The results of validation pointed out that the
estimated sound power of noise sources under simultaneous
conditions were on lower side, within the error limits 3.56 - 6.35 %.
Thus suggesting the use of this methodology for practical
implementation in industry. To demonstrate the application of the
above analytical procedure for estimating the sound power of noise
sources under simultaneous operating conditions, a manufacturing
facility (Railway Workshop at Yamunanagar, India) having five
sound sources (machines) on its workshop floor is considered in this
study. The findings of the case study had identified the two most
effective candidates (noise sources) for noise control in the Railway
Workshop Yamunanagar, India. The study suggests that the
modification in the design and/or replacement of these two identified
noisiest sources (machine) would be necessary so as to achieve an
effective reduction in noise levels. Further, the estimated data allows
engineers to better understand the noise situations of the workplace
and to revise the map when changes occur in noise level due to a
workplace re-layout.