Abstract: High-density polyethylene reinforced with carbon nanofibers (HDPE/CNF) have been prepared via melt processing using dialkylimidazolium tetrafluoroborate (ionic liquid) as a dispersion agent. The prepared samples were characterized by thermogravimetric (TGA) and differential scanning calorimetric (DSC) analyses. The samples blended with imidazolium ionic liquid exhibit higher thermal stability. DSC analysis showed clear miscibility of ionic liquid in the HDPE matrix and showed single endothermic peak. The melt rheological analysis of HDPE/CNF composites was performed using an oscillatory rheometer. The influence of CNF and ionic liquid concentration (ranging from 0, 0.5, and 1 wt%) on the viscoelastic parameters was investigated at 200 °C with an angular frequency range of 0.1 to 100 rad/s. The rheological analysis shows the shear-thinning behavior for the composites. An improvement in the viscoelastic properties was observed as the nanofiber concentration increases. The progress in the modulus values was attributed to the structural rigidity imparted by the high aspect ratio CNF. The modulus values and complex viscosity of the composites increased significantly at low frequencies. Composites blended with ionic liquid exhibit slightly lower values of complex viscosity and modulus over the corresponding HDPE/CNF compositions. Therefore, reduction in melt viscosity is an additional benefit for polymer composite processing as a result of wetting effect by polymer-ionic liquid combinations.
Abstract: The flow of suspensions of wood pulp fibers in circular pipes has been investigated experimentally. The flow characteristics of pulp suspensions are discussed with regard to five flow regimes designated by the author. In particular, the effects of the shear stress at the pipe wall on the disruption and dispersion of networks of pulp fibers are examined. The values of the disruptive and dispersive shear stresses are formulated as simple expressions depending on only the fiber concentration. Furthermore, the flow properties of the suspensions are described using the yield shear stress.
Abstract: An experimental investigation was performed on pulp
liquid flow in straight ducts with a square cross section. Fully
developed steady flow was visualized and the fiber concentration was
obtained using a light-section method developed by the author et al.
The obtained results reveal quantitatively, in a definite form, the
distribution of the fiber concentration. From the results and
measurements of pressure loss, it is found that the flow characteristics
of pulp liquid in ducts can be classified into five patterns. The
relationships among the distributions of mean and fluctuation of fiber
concentration, the pressure loss and the flow velocity are discussed,
and then the features for each pattern are extracted. The degree of
nonuniformity of the fiber concentration, which is indicated by the
standard deviation of its distribution, is decreased from 0.3 to 0.05
with an increase in the velocity of the tested pulp liquid from 0.4 to
0.8%.