Abstract: The purpose of this work was to synthesize and investigate phase formation, structure and thermophysical properties of the phosphates M0.5+xM'xZr2–x(PO4)3 (M – Cd, Sr, Pb; M' – Mg, Co, Mn). The compounds were synthesized by sol-gel method. The results showed formation of limited solid solutions of NZP/NASICON type. The crystal structures of triple phosphates of the compositions MMg0.5Zr1.5(PO4)3 were refined by the Rietveld method using XRD data. Heat capacity (8–660 K) of the phosphates Pb0.5+xMgxZr2-x(PO4)3 (x = 0, 0.5) was measured, and reversible polymorphic transitions were found at temperatures, close to the room temperature. The results of Rietveld structure refinement showed the polymorphism caused by disordering of lead cations in the cavities of NZP/NASICON structure. Thermal expansion (298−1073 K) of the phosphates MMg0.5Zr1.5(PO4)3 was studied by XRD method, and the compounds were found to belong to middle and low-expanding materials. Thermal diffusivity (298–573 K) of the ceramic samples of phosphates slightly decreased with temperature increasing. As was demonstrated, the studied phosphates are characterized by the better thermophysical characteristics than widespread fire-resistant materials, such as zirconia and etc.
Abstract: The content of omega-3 in soybean oil is important in the development of infants and is an alternative for the omega-3 in fish oils. The investigation of extraction of soybean oil is needed to obtain the bioactive compound in the extract. Supercritical carbon dioxide extraction is modern and green technology to extract herbs and plants to obtain high quality extract due to high diffusivity and solubility of the solvent. The aim of this study was to obtain the optimum condition of soybean oil extraction by modified supercritical carbon dioxide. The soybean oil was extracted by using modified supercritical carbon dioxide (SC-CO2) under the temperatures of 40, 60, 80 °C, pressures of 150, 250, 350 Bar, and constant flow-rate of 10 g/min as the parameters of extraction processes. An experimental design was performed in order to optimize three important parameters of SC-CO2 extraction which are pressure (X1), temperature (X2) to achieve optimum yields of soybean oil. Box Behnken Design was applied for experimental design. From the optimization process, the optimum condition of extraction of soybean oil was obtained at pressure 338 Bar and temperature 80 °C with oil yield of 2.713 g. Effect of pressure is significant on the extraction of soybean oil by modified supercritical carbon dioxide. Increasing of pressure will increase the oil yield of soybean oil.
Abstract: Previously, some materials like solid metals and their alloys have been used as implants in human’s body. In order to amend fixation of these artificial hard human tissues, some porous structures have been introduced. In this way, tissues in vicinity of the porous structure can be attached more easily to the inserted implant. In particular, the porous bone scaffolds are useful since they can deliver important biomolecules like growth factors and proteins. This study focuses on the properties of the degradable porous hard tissues using a three-dimensional numerical Finite Element Method (FEM). The most important studied properties of these structures are diffusivity flux and concentration of different species like glucose, oxygen, and lactate. The process of cells migration into the scaffold is considered as a diffusion process, and related parameters are studied for different values of production/consumption rates.
Abstract: High moisture content in fruits generates post-harvest
problems such as mechanical, biochemical, microbial and physical
losses. Dehydration, which is based on the reduction of water activity
of the fruit, is a common option for overcoming such losses.
However, regular hot air drying could affect negatively the quality
properties of the fruit due to the long residence time at high
temperature. Power ultrasound (US) application during the
convective drying has been used as a novel method able to enhance
drying rate and, consequently, to decrease drying time. In the present
study, a new approach was tested to evaluate the effect of US on the
drying time, the final antioxidant activity (AA) and the total
polyphenol content (TPC) of banana slices (BS), mango slices (MS)
and guava slices (GS). There were also studied the drying kinetics
with nine different models from which water effective diffusivities
(Deff) (with or without shrinkage corrections) were calculated.
Compared with the corresponding control tests, US assisted drying
for fruit slices showed reductions in drying time between 16.23 and
30.19%, 11.34 and 32.73%, and 19.25 and 47.51% for the MS, BS
and GS respectively. Considering shrinkage effects, Deff calculated
values ranged from 1.67*10-10 to 3.18*10-10 m2/s, 3.96*10-10 and
5.57*10-10 m2/s and 4.61*10-10 to 8.16*10-10 m2/s for the BS, MS and
GS samples respectively. Reductions of TPC and AA (as DPPH)
were observed compared with the original content in fresh fruit data
in all kinds of drying assays.
Abstract: These days, the field of tissue engineering is getting
serious attention due to its usefulness. Bone tissue engineering helps
to address and sort-out the critical sized and non-healing orthopedic
problems by the creation of manmade bone tissue. We will design
and validate an efficient numerical model, which will simulate the
effective diffusivity in bone tissue engineering. Our numerical model
will be based on the finite element analysis of the diffusion-reaction
equations. It will have the ability to optimize the diffusivity, even
at multi-scale, with the variation of time. It will also have a special
feature “parametric sweep”, with which we will be able to predict
the oxygen, glucose and cell density dynamics, more accurately. We
will fix these problems by modifying the governing equations, by
selecting appropriate spatio-temporal finite element schemes and by
transient analysis.
Abstract: Drying behavior of blanched sweet potato in a cabinet
dryer using different five air temperatures (40-80°C) and ten sweet
potato varieties sliced to 5mm thickness were investigated. The
drying data were fitted to eight models. The Modified Henderson and
Pabis model gave the best fit to the experimental moisture ratio data
obtained during the drying of all the varieties while Newton (Lewis)
and Wang and Singh models gave the least fit. The values of Deff
obtained for Bophelo variety (1.27 x 10-9 to 1.77 x 10-9 m2/s) was
the least while that of S191 (1.93 x 10-9 to 2.47 x 10-9 m2/s) was the
highest which indicates that moisture diffusivity in sweet potato is
affected by the genetic factor. Activation energy values ranged from
0.27-6.54 kJ/mol. The lower activation energy indicates that drying
of sweet potato slices requires less energy and is hence a cost and
energy saving method. The drying behavior of blanched sweet potato
was investigated in a cabinet dryer. Drying time decreased
considerably with increase in hot air temperature. Out of the eight
models fitted, the Modified Henderson and Pabis model gave the best
fit to the experimental moisture ratio data on all the varieties while
Newton, Wang and Singh models gave the least. The lower activation
energy (0.27 - 6.54 kJ/mol) obtained indicates that drying of sweet
potato slices requires less energy and is hence a cost and energy
saving method.
Abstract: Transient plane source method has been used to
measure the thermal diffusivity and thermal conductivity of a compact
isostatic electroceramics at room temperature. The samples were fired
at temperatures from 100 up to 1320 degrees Celsius in steps of
50. Bulk density and specific heat capacity were also measured with
their corresponding standard uncertainties. The results were compared
with further thermal analysis (dilatometry and thermogravimetry).
Structural processes during firing were discussed.
Abstract: Ground Coupled Heat Pumps (GCHPs) exploit effectively the heat capacity of the ground, with the use of Ground Heat Exchangers (GHE). Depending on the mode of operation of the GCHPs, GHEs dissipate or absorb heat from the ground. For sizing the GHE the thermal properties of the ground need to be known. This paper gives information about the density, thermal conductivity, specific heat and thermal diffusivity of various lithologies encountered in Cyprus with various relations between these properties being examined through comparison and modeling. The results show that the most important correlation is the one encountered between thermal conductivity and thermal diffusivity with both properties showing similar response to the inlet and outlet flow temperature of vertical and horizontal heat exchangers.
Abstract: Pervaporation has the potential to be an alternative to the other traditional separation processes such as distillation,
adsorption, reverse osmosis and extraction. This study investigates the separation of phenol from water using a polyurethane membrane by pervaporation by applying the modified Maxwell-Stephen model. The modified Maxwell-Stefan model takes into account the non-ideal multi-component solubility effect, nonideal diffusivity of all permeating components, concentration dependent density of the membrane and diffusion coupling to predict various fluxes. Four cases has been developed to investigate the process parameters effects on the flux and weight fraction of phenol in the permeate values namely feed concentration, membrane thickness, operating temperature and operating downstream pressure. The model could
describe semi-quantitatively the performance of the pervaporation membrane for the given system as a very good agreement between the observed and theoretical fluxes was observed.
Abstract: In this paper, 3D image based composite unit cell is constructed from high resolution tomographic images. Through-thickness thermal diffusivity and in-plane Young’s modulus are predicted for the composite unit cell. The accuracy of the image based composite unit cell is tested by comparing its results with the experimental results obtained from laser flash and tensile test. The FE predictions are in close agreement with experimental results. Through-thickness thermal diffusivity and in-plane Young’s modulus of a virgin C/C composite are predicted by replacing the properties of air (porosity) with the properties of carbon matrix. The effect of porosity was found to be more profound on thermal diffusivity than young’s modulus.
Abstract: The purpose of present work was to study the drying kinetics of whole acorn and its kernel at different drying air temperatures and their effective moisture diffusivity. The results indicated that the drying time of whole acorn was 442, 206 and 188 min at the air temperature of 65, 75 and 85ºC, respectively. At the same temperatures, the drying time of kernel was 131, 56 and 76min. The results showed that the effect of drying air temperature increasing on the drying time reduction could not be significant on acorn drying at all conditions. The effective moisture diffusivity of whole acorn and kernel increased with increasing air temperature from 65 to 75ºC. However more air temperature increasing, led to decreasing this property of acorn kernel. The critical temperature of acorn drying was about 75°C in which acorn kernel had the highest effective moisture diffusivity.
Abstract: Hydrogen is an important chemical in many industries and it is expected to become one of the major fuels for energy generation in the future. Unfortunately, hydrogen does not exist in its elemental form in nature and therefore has to be produced from hydrocarbons, hydrogen-containing compounds or water.
Above its critical point (374.8oC and 22.1MPa), water has lower density and viscosity, and a higher heat capacity than those of ambient water. Mass transfer in supercritical water (SCW) is enhanced due to its increased diffusivity and transport ability. The reduced dielectric constant makes supercritical water a better solvent for organic compounds and gases. Hence, due to the aforementioned desirable properties, there is a growing interest toward studies regarding the gasification of organic matter containing biomass or model biomass solutions in supercritical water.
In this study, hydrogen and biofuel production by the catalytic gasification of 2-Propanol in supercritical conditions of water was investigated. Ru/Al2O3 was the catalyst used in the gasification reactions. All of the experiments were performed under a constant pressure of 25 MPa. The effects of five reaction temperatures (400, 450, 500, 550 and 600oC) and five reaction times (10, 15, 20, 25 and 30 s) on the gasification yield and flammable component content were investigated.
Abstract: Recently, a growing interest has emerged on the development of new and efficient energy sources, due to the inevitable extinction of the nonrenewable energy reserves. One of these alternative sources which have a great potential and sustainability to meet up the energy demand is biomass energy. This significant energy source can be utilized with various energy conversion technologies, one of which is biomass gasification in supercritical water.
Water, being the most important solvent in nature, has very important characteristics as a reaction solvent under supercritical circumstances. At temperatures above its critical point (374.8oC and 22.1MPa), water becomes more acidic and its diffusivity increases. Working with water at high temperatures increases the thermal reaction rate, which in consequence leads to a better dissolving of the organic matters and a fast reaction with oxygen. Hence, supercritical water offers a control mechanism depending on solubility, excellent transport properties based on its high diffusion ability and new reaction possibilities for hydrolysis or oxidation.
In this study the gasification of a real biomass, namely olive mill wastewater (OMW), in supercritical water conditions is investigated with the use of Ru/Al2O3 catalyst. OMW is a by-product obtained during olive oil production, which has a complex nature characterized by a high content of organic compounds and polyphenols. These properties impose OMW a significant pollution potential, but at the same time, the high content of organics makes OMW a desirable biomass candidate for energy production.
The catalytic gasification experiments were made with five different reaction temperatures (400, 450, 500, 550 and 600°C) and five reaction times (30, 60, 90, 120 and 150s), under a constant pressure of 25MPa. Through these experiments, the effects of reaction temperature and time on the gasification yield, gaseous product composition and OMW treatment efficiency were investigated.
Abstract: The Pads have unique values of thermophysical
properties (THP) having important contribution over heat transfer
into the PCB structure.
Materials with high thermal diffusivity (TD) rapidly adjust their
temperature to that of their surroundings, because the HT is quick in
compare to their volumetric heat capacity (VHC).
In the paper is presenting the diffusivity tests (ASTM E1461 flash
method) for PCBs with different core materials. In the experiments,
the multilayer structure of PCBA was taken into consideration, an
equivalent property referring to each of experimental structure be
practically measured.
Concerning to entire structure, the THP emphasize the major
contribution of substrate in establishing of reflow soldering process
(RSP) heat transfer necessities. This conclusion offer practical
solution for heat transfer time constant calculation as function of
thickness and substrate material diffusivity with an acceptable error
estimation.
Abstract: Mechanical and water transport properties of high
performance concrete (HPC) containing natural zeolite as partial
replacement of Portland cement are studied. Experimental results
show that in the investigated mixes the use of natural zeolite leads to
an increase of porosity, decrease of compressive strength and
increase of moisture diffusivity and water vapor diffusion coefficient,
as compared with the reference HPC. However, for the replacement
level up to 20% of the mass of Portland cement the concretes still
maintain their high performance character and exhibit acceptable
water transport properties. Therefore, natural zeolite can be
considered an environmental friendly binder with a potential to
replace a part of Portland cement in concrete in building industry.
Abstract: Many commercial processes are available for the
removal of H2S from gaseous streams. The desulfurization of gas
streams using aqueous ferric sulfate solution as washing liquor is
studied. Apart from sulfur, only H2O is generated in the process, and
consequently, no waste treatment facilities are required. A distinct
advantage of the process is that the reaction of H2S with is so rapid
and complete that there remains no danger of discharging toxic waste
gas. In this study, the reactive absorption of hydrogen sulfide into
aqueous ferric sulfate solution has been studied and design
calculations for equipments have been done and effective operation
parameters on this process considered. Results show that high
temperature and low pressure are suitable for absorption reaction.
Variation of hydrogen sulfide concentration and Fe3+ concentration
with time in absorption reaction shown that the reaction of ferric
sulfate and hydrogen sulfide is first order with respect to the both
reactant. At low Fe2(SO4)3 concentration the absorption rate of H2S
increase with increasing the Fe2(SO4)3 concentration. At higher
concentration a decrease in the absorption rate was found. At higher
concentration of Fe2(SO4)3, the ionic strength and viscosity of
solution increase remarkably resulting in a decrease of solubility,
diffusivity and hence absorption rate.
Abstract: This article is dedicated to development of
mathematical models for determining the dynamics of
concentration of hazardous substances in urban turbulent
atmosphere. Development of the mathematical models implied
taking into account the time-space variability of the fields of
meteorological items and such turbulent atmosphere data as vortex
nature, nonlinear nature, dissipativity and diffusivity. Knowing the
turbulent airflow velocity is not assumed when developing the
model. However, a simplified model implies that the turbulent and
molecular diffusion ratio is a piecewise constant function that
changes depending on vertical distance from the earth surface.
Thereby an important assumption of vertical stratification of urban
air due to atmospheric accumulation of hazardous substances
emitted by motor vehicles is introduced into the mathematical
model. The suggested simplified non-linear mathematical model of
determining the sought exhaust concentration at a priori unknown
turbulent flow velocity through non-degenerate transformation is
reduced to the model which is subsequently solved analytically.
Abstract: Interaction of inorganic water-soluble salts and building stones is studied in the paper. Two types of sandstone and one type of spongillite as representatives of materials used in historical masonry are subjected to experimental testing. Within the performed experiments, measurement of moisture and chloride concentration profiles is done in order to get input data for computational inverse analysis. Using the inverse analysis, moisture diffusivity and chloride diffusion coefficient of investigated materials are accessed. Additionally, the effect of salt presence on water vapor storage is investigated using dynamic vapor sorption device. The obtained data represents valuable information for restoration of historical masonry and give evidence on the performance of studied stones in contact with water soluble salts.
Abstract: In the present work, the effective moisture diffusivity
and activation energy were calculated using an infinite series solution
of Fick-s diffusion equation. The results showed that increasing
drying temperature accelerated the drying process. All drying
experiments had only falling rate period. The average effective
moisture diffusivity values varied from 2.807x10-10 to 6.977x10-10m2
s_1 over the temperature and velocity range. The temperature
dependence of the effective moisture diffusivity for the thin layer
drying of the ginger slices was satisfactorily described by an
Arrhenius-type relationship with activation energy values of 19.313-
22.722 kJ.mol-1 within 40–70 °C and 0.8-3 ms-1 temperature range.
Abstract: Six parameters, the effective diffusivity (De),
activation energy of De, pre-exponential factor of De, amount
(ASOW) of self-organized water species, and amplitude (α) of the
forced oscillation of the molecular mobility (1/tC) derived from the
forced cyclic temperature change operation, were characterized by
using six typical foods, squid, sardines, scallops, salmon, beef, and
pork, as a function of the correlation time (tC) of the water molecule-s
proton retained in the foods. Each of the six parameters was clearly
divided into the water species A1 and A2 at a specified value of tC
=10-8s (=CtC), indicating an anomalous change in the physicochemical
nature of the water species at the CtC. The forced oscillation of 1/tC
clearly demonstrated a characteristic mode depending on the food
shown as a three dimensional map associated with 1/tC, the amount of
self-organized water, and tC.