Abstract: Zinc borates are used as a multi-functional flame
retardant additive for its high dehydration temperature. In this study,
the method of ultrasonic mixing was used in the synthesis of zinc
borates. The reactants of zinc oxide (ZnO) and boric acid (H3BO3)
were used at the constant reaction parameters of 90°C reaction
temperature and 55 min of reaction time. Several molar ratios of
ZnO:H3BO3 (1:1, 1:2, 1:3, 1:4 and 1:5) were conducted for the
determination of the optimum reaction ratio. Prior to synthesis the
characterization of the synthesized zinc borates were made by X-Ray
Diffraction (XRD) and Fourier Transform Infrared Spectroscopy
(FT-IR). From the results Zinc Oxide Borate Hydrate
[Zn3B6O12.3.5H2O], were synthesized optimum at the molar ratio of
1:3, with a reaction efficiency of 95.2%.
Abstract: Zinc borate is an important inorganic hydrate borate
material, which can be used as a flame retardant agent and corrosion
resistance material. This compound can loss its structural water
content at higher than 290°C. Due to thermal stability; Zinc Borate
can be used as flame retardant at high temperature process of plastic
and gum. In this study, the ultrasonic reaction of zinc borates were
studied using hydrozincite (Zn5(CO3)2·(OH)6) and boric acid
(H3BO3) raw materials. Before the synthesis raw materials were
characterized by X-Ray Diffraction (XRD) and Fourier Transform
Infrared Spectroscopy (FT-IR). Ultrasonic method is a new
application on the zinc borate synthesis. The synthesis parameters
were set to 90°C reaction temperature and 55 minutes of reaction
time, with 1:1, 1:2, 1:3, 1:4 and 1:5 molar ratio of starting materials
(Zn5(CO3)2·(OH)6 : H3BO3). After the zinc borate synthesis, the
products were analyzed by XRD and FT-IR. As a result, optimum
molar ratio of 1:5 is determined for the synthesis of zinc borates with
ultrasonic method.
Abstract: Potassium borates, which are widely used in welding
and metal refining industry, as a lubricating oil additive, cement
additive, fiberglass additive and insulation compound, are one of the
important groups of borate minerals. In this study the production of a
potassium borate mineral via hydrothermal method is aimed. The
potassium source of potassium nitrate (KNO3) was used along with a
sodium source of sodium hydroxide (NaOH) and boron source of
boric acid (H3BO3). The constant parameters of reaction temperature
and reaction time were determined as 80°C and 1 h, respectively. The
molar ratios of 1:1:3 (as KNO3:NaOH:H3BO3), 1:1:4, 1:1:5, 1:1:6
and 1:1:7 were used. Following the synthesis the identifications of
the produced products were conducted by X-Ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FT-IR) and Raman
Spectroscopy. The results of the experiments and analysis showed in
the ratio of 1:1:6, the Santite mineral with powder diffraction file
number (pdf no.) of 01-072-1688, which is known as potassium
pentaborate (KB5O8·4H2O) was synthesized as best.
Abstract: Zinc borate is an important boron compound that can be used as multi-functional flame retardant additive due to its high dehydration temperature property. In this study, theraw materials of ZnSO4.7H2O, NaOH and H3BO3werecharacterized by X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) and used in the synthesis of zinc borates.The synthesis parameters were set to 100°C reaction temperature and 120 minutes of reaction time, with different molar ratio of starting materials (ZnSO4.7H2O:NaOH:H3BO3). After the zinc borate synthesis, the identifications of the products were conducted by XRD and FT-IR. As a result,Zinc Oxide Borate Hydrate [Zn3B6O12.3.5H2O], were synthesized at the molar ratios of 1:1:3, 1:1:4, 1:2:5 and 1:2:6. Among these ratios 1:2:6 had the best results.
Abstract: Due to their strong mechanical and thermal properties magnesium borates have a wide usage area such as ceramic industry, detergent production, friction reducing additive and grease production. In this study, microwave synthesis of magnesium borates from MgCl2.6H2O (Magnesium chloride hexahydrate), MgO (Magnesium oxide) and H3BO3 (Boric acid) for different reaction times is researched. X-ray Diffraction (XRD) and Fourier Transform Infrared (FT-IR) Spectroscopy are used to find out how the reaction time sways on the products. The superficial properties are investigated with Scanning Electron Microscopy (SEM). According to XRD analysis, the synthesized compounds are 00-041-1407 pdf coded Shabinite (Mg5(BO3)4Cl2(OH)5.4(H2O)) and 01-073-2158 pdf coded Karlite (Mg7(BO3)3(OH,Cl)5).
Abstract: Magnesium borate(MB) istechnical ceramic for high heat-resisting, corrosion-resisting, super mechanical strength, superinsulation, light weight, high strength, and high coefficient of elasticity. Zinc borate (ZB) can be used as multi-functional synergistic additives with flame retardant additives in polymers. The most important properties are low solubility in water and high dehydration temperature. ZB dehydrates above 290°C and anhydrous ZB has thermal resistance about 400°C. In this study, the raw materials of ZnO, MgO and H3BO3 were used with mole ratio of 1:1:9. With the starting materials hydrothermal method was applied at a temperature of 100oC. The reaction time was determined as 30, 60, 90 and 120 minutes after some preliminary experiments. After the synthesis, the crystal structure and the morphology of the products were examined by X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR). As a result, the forms of Zinc Oxide Borate Hydrate [Zn3B6O12.3.5H2O], Admontite [MgO(B2O3)3.7(H2O)] and Mcallisterite [Mg2(B6O7(OH)6)2.9(H2O)] were synthesized.
Abstract: Research on the boron (B) toxicity problems had recently considerable relation, especially in the dry regions of the world. Development of resistant varieties to B toxicity is a high priority on these regions, where the soils have high levels of B. Thus, this study aimed to assessment the resistance of wheat genotypes to B toxicity using the agronomic and physiologic parameters. For this aim, a pot experiment, based on a completely randomized design with three replications, was conducted using the soil of calcareous usthochrepts. In the study, twenty different wheat genotypes of T. aestivum and T. Durum were used. Boron fertilizer at the levels of 0 (-B), 30 mg B kg-1 (+B) as H3BO3 was applied to the pots. After harvest, plant dry matter yield was recorded, and total B concentrations in tops of wheat plants were determined. The results have revealed the existence of a large genotypic variation among wheat genotypes to their physiologic and agronomic susceptibility to B toxicity.
Abstract: Magnesium wastes are produced by many industrial activities. This waste problem is becoming a future problem for the world. Magnesium borates have many advantages such as; high corrosion resistance, heat resistance, high coefficient of elasticity and can also be used in the production of material against radiation. Addition, magnesium borates have great potential in sectors
including ceramic and detergents industry and superconducting materials.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate
temperature of 70oC. Several mole ratios of waste magnesium to H3BO3 are selected as; 1:2, 1:4, 1:6, 1:8, 1:10. Reaction time was determined as 1 hour. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques are applied to products. As a result the forms of mcallisterite “Mg2(B6O7(OH)6)2.9(H2O)”, admontite “MgO(B2O3)3.7(H2O)” and magnesium boron hydrate (MgO(B2O3)3.6(H2O)” are obtained.
Abstract: There are many kinds of metal borates found not only
in nature but also synthesized in the laboratory such as magnesium
borates. Due to its excellent properties, as remarkable ceramic
materials, they have also application areas in anti-wear and friction
reducing additives as well as electro-conductive treating agents. The
synthesis of magnesium borate powders can be fulfilled simply with
two different methods, hydrothermal and thermal synthesis.
Microwave assisted method, also another way of producing
magnesium borate, can be classified into thermal synthesis because of
using the principles of solid state synthesis. It also contributes
producing particles with small size and high purity in nano-size
material synthesize. In this study the production of magnesium
borates, are aimed using MgCl2.6H2O and H3BO3. The identification
of both starting materials and products were made by the equipments
of, X-Ray Diffraction (XRD) and Fourier Transform Infrared
Spectroscopy (FT-IR). After several synthesis steps magnesium
borates were synthesized and characterized by XRD and FT-IR, as
well.
Abstract: Turkey has 72 % of total world boron reserves on the
basis of B2O3.Borates that is a refined form of boron minerals have a
wide range of applications. Zinc borates can be used as multifunctional
synergistic additives. The most important properties are
low solubility in water and high dehydration temperature. Zinc
borates dehydrate above 290°C and anhydrous zinc borate has
thermal resistance about 400°C. Zinc borates can be synthesized
using several methods such as hydrothermal and solid-state
processes. In this study, the solid-state method was applied between
500 and 800°C using the starting materials of ZnO and H3BO3 with
1:4 mole ratio. The reaction time was determined as 4 hours after
some preliminary experiments. After the synthesis, the crystal
structure and the morphology of the products were examined by XRay
Diffraction (XRD), Fourier Transform Infrared Spectroscopy
(FT-IR) and Raman Spectrometer. As a result the form of ZnB4O7
was synthesized with the highest crystal score at 800°C.
Abstract: Borate minerals have attracted considerable attention in the past years due to their structural chemistry and mechanical properties in several industries. Recently, increasing attention has been paid to the use of; synthetically produced magnesium borates as catalysts reinforcing material for plastics, the conversion of hydrocarbons, electro-conductive treating agent, anti-wear and anti-corrosion materials. Magnesium borates can be synthesized by several methods such as; hydrothermal and solid-state (thermal) processes. In this study the hydrothermal production method was applied at the modest temperature of 80C along with convenient crystal growth. Using MgCl2.6H2O, H3BO3, and NaOH as starting materials, 30, 60, 120, 240 minutes of reaction times were studied. After all, the crystal structure and the morphology of the products were examined by X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR). As a result the forms of Admontite and Mcallisterite minerals were synthesized.
Abstract: Zinc borates can be used as multi-functional
synergistic additives with flame retardant additives in polymers. Zinc
borate is white, non-hygroscopic and powder type product. The most
important properties are low solubility in water and high dehydration
temperature. Zinc borates dehydrate above 290°C and anhydrous zinc
borate has thermal resistance about 400°C. Zinc borates can be
synthesized using several methods such as hydrothermal and solidstate
processes. In this study, the solid-state method was applied at
low temperatures of 600oC and 700oC using the starting materials of
ZnO and H3BO3 with several mole ratios. The reaction time was
determined as 4 hours after some preliminary experiments. After the
synthesis, the crystal structure and the morphology of the products
were examined by X-Ray Diffraction (XRD) and Fourier Transform
Infrared Spectroscopy (FT-IR). As a result the forms of ZnB4O7,
Zn3(BO3)2, ZnB2O4 were synthesized and obtained along with the
unreacted ZnO.